{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T11:10:59Z","timestamp":1791544259867,"version":"4.3.4"},"reference-count":52,"publisher":"American Chemical Society (ACS)","issue":"45","license":[{"start":{"date-parts":[[2022,11,3]],"date-time":"2022-11-03T00:00:00Z","timestamp":1667433600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2022,11,3]],"date-time":"2022-11-03T00:00:00Z","timestamp":1667433600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2022,11,3]],"date-time":"2022-11-03T00:00:00Z","timestamp":1667433600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-SC0022920"],"award-info":[{"award-number":["DE-SC0022920"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000082","name":"Division of Graduate Education","doi-asserted-by":"publisher","award":["DGE-1745301"],"award-info":[{"award-number":["DGE-1745301"]}],"id":[{"id":"10.13039\/100000082","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100004341","name":"Dow Chemical Company","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100004341","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100005883","name":"Hertz Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100005883","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006961","name":"California Institute of Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006961","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2022,11,16]]},"DOI":"10.1021\/jacs.2c08729","type":"journal-article","created":{"date-parts":[[2022,11,3]],"date-time":"2022-11-03T14:16:45Z","timestamp":1667485005000},"page":"20804-20814","source":"Crossref","is-referenced-by-count":48,"title":["Illuminating Ligand Field Contributions to Molecular Qubit Spin Relaxation via\n                    <i>T<\/i>\n                    <sub>1<\/sub>\n                    Anisotropy"],"prefix":"10.1021","volume":"144","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7822-6769","authenticated-orcid":true,"given":"Nathanael P.","family":"Kazmierczak","sequence":"first","affiliation":[{"name":"Division of Chemistry and Chemical Engineering, Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6026-1358","authenticated-orcid":true,"given":"Ryan G.","family":"Hadt","sequence":"additional","affiliation":[{"name":"Division of Chemistry and Chemical Engineering, Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2022,11,3]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-020-0200-5"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00984"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202100845"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c00737"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b13408"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC00074G"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC06130E"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms6304"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05574"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10145"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06909"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c08986"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4899-6539-4"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c04605"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC05464E"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c02573"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.103.014401"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1039\/D0CP00852D"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.7b00479"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aax7163"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.0c01681"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c01410"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1006\/jmra.1995.9971"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmr.2005.08.013"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)92495-2"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1039\/dt9880000309"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.0c07860"},{"key":"ref28\/cit28","doi-asserted-by":"crossref","unstructured":"Yen, T. F.\n                      Electron Spin Resonance of Metal Complexes: Proceedings of the Symposium on ESR of Metal Chelates\n                      ; Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, Cleveland, OH, March 4\u20138, 1968; Springer US: Boston, MA, 1969.","DOI":"10.1007\/978-1-4684-8323-9"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1002\/9780470034590.emrstm1507"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1016\/bs.mie.2015.06.028"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1002\/ijch.199200041"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2019.137034"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1006\/jmra.1995.1172"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1006\/jmra.1995.1169"},{"key":"ref35\/cit35","volume-title":"The Physical Principles of Electron Paramagnetic Resonance","author":"Pake G. E.","year":"1973","edition":"2"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1103\/RevModPhys.76.323"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRev.96.266"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2010.04.022"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1007\/BF00526531"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.46.636"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.47.732"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1021\/ja0665949"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1021\/ja00431a016"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/ja01037a046"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1021\/ic50015a013"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1021\/ic50120a029"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1002\/0471471933.ch3"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1021\/ja00953a009"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1021\/ja01011a014"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1021\/ja029806k"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-575301-2.50008-0"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmr.2005.11.011"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.2c08729","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.2c08729","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,27]],"date-time":"2023-04-27T18:05:14Z","timestamp":1682618714000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.2c08729"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11,3]]},"references-count":52,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2022,11,16]]}},"alternative-id":["10.1021\/jacs.2c08729"],"URL":"https:\/\/doi.org\/10.1021\/jacs.2c08729","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,11,3]]}}}