{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,18]],"date-time":"2026-10-18T04:19:11Z","timestamp":1792297151952,"version":"4.4.0"},"reference-count":98,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2023,8,28]],"date-time":"2023-08-28T00:00:00Z","timestamp":1693180800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2023,8,28]],"date-time":"2023-08-28T00:00:00Z","timestamp":1693180800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2023,8,28]],"date-time":"2023-08-28T00:00:00Z","timestamp":1693180800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["CHE-2042353"],"award-info":[{"award-number":["CHE-2042353"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["R35 GM147523-01"],"award-info":[{"award-number":["R35 GM147523-01"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2023,9,13]]},"DOI":"10.1021\/jacs.3c02595","type":"journal-article","created":{"date-parts":[[2023,8,28]],"date-time":"2023-08-28T13:10:45Z","timestamp":1693228245000},"page":"19542-19553","source":"Crossref","is-referenced-by-count":34,"title":["Asymmetric Syntheses of (\n                    <i>Z<\/i>\n                    )- or (\n                    <i>E<\/i>\n                    )-\u03b2,\u03b3-Unsaturated Ketones via Silane-Controlled Enantiodivergent Catalysis"],"prefix":"10.1021","volume":"145","author":[{"given":"Jiaming","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry, Auburn University, Auburn, Alabama 36849, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8166-5503","authenticated-orcid":true,"given":"Shang","family":"Gao","sequence":"additional","affiliation":[{"name":"Department of Medicinal Chemistry, School of Pharmacy, China Pharmaceutical University, Nanjing 210009, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Evangelos","family":"Miliordos","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, Auburn University, Auburn, Alabama 36849, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9841-8274","authenticated-orcid":true,"given":"Ming","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, Auburn University, Auburn, Alabama 36849, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2023,8,28]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1021\/ar700155p"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1039\/b821200g"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00727"},{"key":"ref1\/cit1d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00821"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1039\/a815477y"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20000818)39:16<2847::AID-ANIE2847>3.0.CO;2-0"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02019"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.7164\/antibiotics.45.1433"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1021\/ol702249g"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2014.12.030"},{"key":"ref3\/cit3d","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b02071"},{"key":"ref3\/cit3e","doi-asserted-by":"publisher","DOI":"10.1039\/D0OB00617C"},{"key":"ref3\/cit3f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jnatprod.0c00767"},{"key":"ref3\/cit3g","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jnatprod.0c01010"},{"key":"ref3\/cit3h","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jnatprod.1c00783"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00338E"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC01254C"},{"key":"ref4\/cit4c","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c02496"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201703079"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)82420-0"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(02)00080-7"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800848"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1021\/ja202267k"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1021\/ol0159470"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1021\/ja903880q"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1021\/ja8009428"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1021\/ja1017046"},{"key":"ref9\/cit9c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c01686"},{"key":"ref9\/cit9d","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c11526"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1021\/ja077212h"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1021\/ja303116v"},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1021\/ja406356c"},{"key":"ref10\/cit10d","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaw4029"},{"key":"ref10\/cit10e","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC03531A"},{"key":"ref10\/cit10f","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903174"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b01399"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201801080"},{"key":"ref11\/cit11c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b02653"},{"key":"ref11\/cit11d","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC00226J"},{"key":"ref11\/cit11e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b00461"},{"key":"ref11\/cit11f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b01535"},{"key":"ref11\/cit11g","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b03819"},{"key":"ref11\/cit11h","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b04089"},{"key":"ref11\/cit11i","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c02657"},{"key":"ref11\/cit11j","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c03366"},{"key":"ref11\/cit11k","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202000039"},{"key":"ref11\/cit11l","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c04107"},{"key":"ref11\/cit11m","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202107004"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1021\/ol902039q"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-018-0628-7"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC02905B"},{"key":"ref14\/cit14a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00783a034"},{"key":"ref14\/cit14b","doi-asserted-by":"publisher","DOI":"10.1021\/ja00011a006"},{"key":"ref14\/cit14c","doi-asserted-by":"publisher","DOI":"10.1038\/nprot.2007.354"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198500013"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(19981102)4:11<2154::AID-CHEM2154>3.0.CO;2-O"},{"key":"ref17\/cit17a","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20000717)6:14<2590::AID-CHEM2590>3.0.CO;2-X"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201707323"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b03768"},{"key":"ref19\/cit19a","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)94399-5"},{"key":"ref19\/cit19b","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)97250-2"},{"key":"ref19\/cit19c","doi-asserted-by":"publisher","DOI":"10.1021\/ar960223n"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/ja100949e"},{"key":"ref21\/cit21a","doi-asserted-by":"publisher","DOI":"10.1021\/jo8002826"},{"key":"ref21\/cit21b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201606046"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/ja305448w"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1971"},{"key":"ref24\/cit24a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00990a061"},{"key":"ref24\/cit24b","doi-asserted-by":"publisher","DOI":"10.1055\/s-0036-1589046"},{"key":"ref25\/cit25a","doi-asserted-by":"publisher","DOI":"10.1021\/ja029225v"},{"key":"ref25\/cit25b","doi-asserted-by":"publisher","DOI":"10.1021\/ol800341z"},{"key":"ref25\/cit25c","doi-asserted-by":"publisher","DOI":"10.1021\/ol2020187"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/ja00237a029"},{"key":"ref27\/cit27a","doi-asserted-by":"publisher","DOI":"10.7164\/antibiotics.34.1075"},{"key":"ref27\/cit27b","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1987.113"},{"key":"ref27\/cit27c","doi-asserted-by":"publisher","DOI":"10.1021\/ol302539s"},{"key":"ref27\/cit27d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jnatprod.6b00200"},{"key":"ref28\/cit28a","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15071e"},{"key":"ref28\/cit28b","doi-asserted-by":"publisher","DOI":"10.1021\/ol030010f"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/cr00098a009"},{"key":"ref30\/cit30a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00316a077"},{"key":"ref30\/cit30b","doi-asserted-by":"publisher","DOI":"10.1021\/ja00158a056"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/ol301563g"},{"key":"ref32\/cit32a","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b04767"},{"key":"ref32\/cit32b","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c02758"},{"key":"ref33\/cit33a","doi-asserted-by":"publisher","DOI":"10.1021\/ja909640b"},{"key":"ref33\/cit33b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201300443"},{"key":"ref33\/cit33c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b03483"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1021\/cr078340r"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202006420"},{"key":"ref36\/cit36a","doi-asserted-by":"crossref","first-page":"1920","DOI":"10.1021\/ja01565a041","volume":"79","author":"Zimmerman H. E.","year":"1957","journal-title":"J. Am. Chem. Soc."},{"key":"ref36\/cit36b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198205553"},{"key":"ref39\/cit39a","doi-asserted-by":"publisher","DOI":"10.1021\/cr00054a001"},{"key":"ref39\/cit39b","doi-asserted-by":"publisher","DOI":"10.1126\/science.217.4558.401"},{"key":"ref39\/cit39c","doi-asserted-by":"publisher","DOI":"10.1021\/ja00240a025"},{"key":"ref40\/cit40a","doi-asserted-by":"publisher","DOI":"10.1021\/ja311208a"},{"key":"ref40\/cit40b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b01784"},{"key":"ref40\/cit40c","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC04787E"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.3c02595","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.3c02595","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,13]],"date-time":"2023-09-13T06:10:38Z","timestamp":1694585438000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.3c02595"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,8,28]]},"references-count":98,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2023,9,13]]}},"alternative-id":["10.1021\/jacs.3c02595"],"URL":"https:\/\/doi.org\/10.1021\/jacs.3c02595","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,8,28]]}}}