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Of particular interest is the interplay between A and B cations as exemplified by intersite charge transfer (ICT), which causes novel phenomena including negative thermal expansion and metal\u2013insulator transition. However, the ICT properties were achieved and optimized by cationic substitution or ordering. Here we demonstrate an anionic approach to induce ICT using an oxyhydride perovskite, EuVO2H, which has alternating layers of EuH and VO2. A bulk EuVO2H behaves as a ferromagnetic insulator with a relatively high transition temperature (TC) of 10 K. However, the application of external pressure to the EuIIVIIIO2H bulk or compressive strain from the substrate in the thin films induces ICT from the EuIIH layer to the VIIIO2 layer due to the extended empty V dxy orbital. The ICT phenomenon causes the VO2 layer to become conductive, leading to an increase in TC that is dependent on the number of carriers in the dxy orbitals (up to a factor of 4 for 10 nm thin films). In addition, a large perpendicular magnetic anisotropy appears with the ICT for the films of &amp;lt;100 nm, which is unprecedented in materials with orbital-free Eu2+, opening new perspectives for applications. The present results provide opportunities for the acquisition of novel functions by alternating transition metal\/rare earth layers with heteroanions.<\/jats:p>","DOI":"10.1021\/jacs.3c04521","type":"journal-article","created":{"date-parts":[[2023,9,28]],"date-time":"2023-09-28T20:01:26Z","timestamp":1695931286000},"page":"21807-21816","source":"Crossref","is-referenced-by-count":16,"title":["Large\nPerpendicular Magnetic Anisotropy Induced by\nan Intersite Charge Transfer in Strained EuVO2H Films"],"prefix":"10.1021","volume":"145","author":[{"given":"Morito","family":"Namba","sequence":"first","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5792-0113","authenticated-orcid":true,"given":"Hiroshi","family":"Takatsu","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Riho","family":"Mikita","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Sijia","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0993-0215","authenticated-orcid":true,"given":"Kantaro","family":"Murayama","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0277-0848","authenticated-orcid":true,"given":"Hao-Bo","family":"Li","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-0616-458X","authenticated-orcid":true,"given":"Ryo","family":"Terada","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8867-4813","authenticated-orcid":true,"given":"Ce\u0301dric","family":"Tassel","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3602-312X","authenticated-orcid":true,"given":"Hiroki","family":"Ubukata","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masayuki","family":"Ochi","sequence":"additional","affiliation":[{"name":"Osaka University , , Machikaneyama-cho, , ,","place":["Toyonaka, Osaka, Japan, 560-0043"]},{"name":"Osaka University , , Machikaneyama-cho, ,","place":["Toyonaka,, Osaka, Japan, 560-0043"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Regino","family":"Saez-Puche","sequence":"additional","affiliation":[{"name":"Universidad Complutense de Madrid, Ciudad Universitaria , , , ,","place":["Madrid, Spain, 28040"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elias Palacios","family":"Latasa","sequence":"additional","affiliation":[{"name":"INMA, CSIC-Universidad de Zaragoza , , ,","place":["Zaragoza, Spain, 50009"]},{"name":"Universidad de Zaragoza , , , ,","place":["Zaragoza, Spain, 50018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Naoki","family":"Ishimatsu","sequence":"additional","affiliation":[{"name":"Hiroshima University , , , ,","place":["Higashihiroshima, Hiroshima, Japan, 739-8526"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4500-6214","authenticated-orcid":true,"given":"Daisuke","family":"Shiga","sequence":"additional","affiliation":[{"name":"Tohoku University , , ,","place":["Sendai, Japan, 980-8578"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4668-2695","authenticated-orcid":true,"given":"Hiroshi","family":"Kumigashira","sequence":"additional","affiliation":[{"name":"Tohoku University , , ,","place":["Sendai, Japan, 980-8578"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katsuki","family":"Kinjo","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 606-8502"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shunsaku","family":"Kitagawa","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 606-8502"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kenji","family":"Ishida","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 606-8502"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takahito","family":"Terashima","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 606-8502"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1700-0889","authenticated-orcid":true,"given":"Koji","family":"Fujita","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takeaki","family":"Mashiko","sequence":"additional","affiliation":[{"name":"National Institute for Materials Science , ,","place":["Ibaraki, Japan, 305-0044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keiichi","family":"Yanagisawa","sequence":"additional","affiliation":[{"name":"National Institute for Materials Science , ,","place":["Ibaraki, Japan, 305-0044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3927-0492","authenticated-orcid":true,"given":"Koji","family":"Kimoto","sequence":"additional","affiliation":[{"name":"National Institute for Materials Science , ,","place":["Ibaraki, Japan, 305-0044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3911-9864","authenticated-orcid":true,"given":"Hiroshi","family":"Kageyama","sequence":"additional","affiliation":[{"name":"Kyoto University , , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2023,9,28]]},"reference":[{"key":"2026081707182190200_cit1","doi-asserted-by":"crossref","DOI":"10.1002\/9781118935651","volume-title":"Perovskites: Structure-Property\nRelationships","author":"Tilley","year":"2016"},{"issue":"7","key":"2026081707182190200_cit2","doi-asserted-by":"publisher","first-page":"076501","DOI":"10.1088\/0034-4885\/77\/7\/076501","article-title":"Multiferroics of spin\norigin","volume":"77","author":"Tokura","year":"2014","journal-title":"Rep. Prog. Phys."},{"key":"2026081707182190200_cit3","doi-asserted-by":"publisher","first-page":"814","DOI":"10.1038\/332814a0","article-title":"Superconductivity\nnear 30 K without copper: the Ba0.6K0.4BiO3 perovskite","volume":"332","author":"Cava","year":"1988","journal-title":"Nature"},{"key":"2026081707182190200_cit4","doi-asserted-by":"publisher","first-page":"S573","DOI":"10.1088\/0953-8984\/16\/11\/002","article-title":"Novel structures and\nelectromagnetic properties of\nthe A-siteordered\/disordered manganites RBaMn2O6\/R0.5Ba0.5MnO3 (R = Y and rare earth\nelements)","volume":"16","author":"Ueda","year":"2004","journal-title":"J. Phys.: Condens. Matter"},{"key":"2026081707182190200_cit5","doi-asserted-by":"publisher","first-page":"693","DOI":"10.1016\/S0921-4526(02)01997-X","article-title":"Magnetic\norder and superconductivity in La2\u2011xSrxCuO4: a review","volume":"329\u2013333","author":"Julien","year":"2003","journal-title":"Physica B"},{"key":"2026081707182190200_cit6","doi-asserted-by":"publisher","first-page":"423","DOI":"10.1038\/nature02308","article-title":"A high-mobility electron gas at the\nLaAlO3\/SrTiO3 heterointerface","volume":"427","author":"Ohtomo","year":"2004","journal-title":"Nature"},{"key":"2026081707182190200_cit7","doi-asserted-by":"publisher","first-page":"772","DOI":"10.1038\/s41467-018-02838-4","article-title":"Expanding frontiers in materials\nchemistry and physics with multiple anions","volume":"9","author":"Kageyama","year":"2018","journal-title":"Nat. Commun."},{"key":"2026081707182190200_cit8","doi-asserted-by":"publisher","first-page":"980","DOI":"10.1038\/35010082","article-title":"Inorganic\nyellow-red pigments without toxic metals","volume":"404","author":"Jansen","year":"2000","journal-title":"Nature"},{"key":"2026081707182190200_cit9","doi-asserted-by":"publisher","first-page":"174519","DOI":"10.1103\/PhysRevB.84.174519","article-title":"Superconductivity in WO2.6F0.4 synthesized by reaction of WO3 with Teflon","volume":"84","author":"Hirai","year":"2011","journal-title":"Phys. Rev. B"},{"key":"2026081707182190200_cit10","doi-asserted-by":"publisher","first-page":"18240","DOI":"10.1021\/jacs.7b08891","article-title":"Titanium-Based Hydrides\nas Heterogeneous Catalysts for Ammonia Synthesis","volume":"139","author":"Kobayashi","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"2026081707182190200_cit11","doi-asserted-by":"publisher","first-page":"47","DOI":"10.1038\/nchem.908","article-title":"Anion order in perovskite oxynitrides","volume":"3","author":"Minghui","year":"2011","journal-title":"Nat. Chem."},{"key":"2026081707182190200_cit12","doi-asserted-by":"publisher","first-page":"6762","DOI":"10.1021\/ja300847m","article-title":"Subextensive Entropies and Open Order\nin Perovskite Oxynitrides","volume":"134","author":"Camp","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"2026081707182190200_cit13","doi-asserted-by":"publisher","first-page":"303","DOI":"10.1038\/nature14453","article-title":"The crystallography\nof correlated disorder","volume":"521","author":"Keen","year":"2015","journal-title":"Nature"},{"key":"2026081707182190200_cit14","doi-asserted-by":"publisher","first-page":"2680","DOI":"10.1021\/ja01315a102","article-title":"The Structure\nand Entropy of Ice and of Other Crystals with Some Randomness of Atomic\nArrangement","volume":"57","author":"Pauling","year":"1935","journal-title":"J. Am. Chem. Soc."},{"key":"2026081707182190200_cit15","doi-asserted-by":"publisher","first-page":"7686","DOI":"10.1002\/ange.201403536","article-title":"Strontium Vanadium\nOxide-Hydrides: \u201cSquare-Planar\u201d\nTwo-Electron Phases","volume":"126","author":"Romero","year":"2014","journal-title":"Angew. Chem."},{"key":"2026081707182190200_cit16","doi-asserted-by":"publisher","first-page":"1217","DOI":"10.1038\/s41467-017-01301-0","article-title":"The role of p-blocking\nhydride ligands\nin a pressure-induced insulator-to-metal phase transition in SrVO2H","volume":"8","author":"Yamamoto","year":"2017","journal-title":"Nat. Commun."},{"key":"2026081707182190200_cit17","doi-asserted-by":"publisher","first-page":"751","DOI":"10.1107\/S0567739476001551","article-title":"Revised\neffective ionic radii and systematic studies of interatomic distances\nin halides and chalcogenides","volume":"A32","author":"Shannon","year":"1976","journal-title":"Acta Crystallogr."},{"key":"2026081707182190200_cit18","doi-asserted-by":"publisher","first-page":"051401","DOI":"10.1103\/PhysRevMaterials.3.051401","article-title":"Charge transport in oxygen-deficient\nEuTiO3: The emerging picture of dilute metallicity in quantum-paraelectric\nperovskite oxides","volume":"3","author":"Engelmayer","year":"2019","journal-title":"Phys. Rev. Materials"},{"key":"2026081707182190200_cit19","doi-asserted-by":"publisher","first-page":"67","DOI":"10.1107\/S0365110X53000156","article-title":"Rare earth titanates with a perovskite\nstructure","volume":"6","author":"Brous","year":"1953","journal-title":"Acta Crystallogr."},{"key":"2026081707182190200_cit20","doi-asserted-by":"publisher","first-page":"3913","DOI":"10.1103\/PhysRevB.10.3913","article-title":"Magnetic properties of EuTiO3, Eu2TiO4 and Eu3Ti2O7","volume":"10","author":"Chien","year":"1974","journal-title":"Phys. Rev. B"},{"key":"2026081707182190200_cit21","doi-asserted-by":"publisher","first-page":"14433","DOI":"10.1021\/ja074880u","article-title":"Pressure-Induced Intermetallic Valence\nTransition in BiNiO3","volume":"129","author":"Azuma","year":"2007","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026081707182190200_cit22","doi-asserted-by":"publisher","first-page":"061909","DOI":"10.1063\/1.4817976","article-title":"Tuning negative thermal expansion\nin Bi1\u2011xLnxNiO3 (Ln = La,\nNd, Eu, Dy)","volume":"103","author":"Oka","year":"2013","journal-title":"Appl. Phys. Lett."},{"key":"2026081707182190200_cit23","doi-asserted-by":"publisher","first-page":"045104","DOI":"10.1103\/PhysRevB.84.045104","article-title":"Valence transition\nin (Pr,Ca)\u00adCoO3 cobaltites: Charge migration at the metal-insulator\ntransition","volume":"84","author":"Garci\u0301a-Mun\u0303oz","year":"2011","journal-title":"Phys. Rev. B"},{"key":"2026081707182190200_cit24","doi-asserted-by":"publisher","first-page":"7774","DOI":"10.1038\/s41467-022-35024-8","article-title":"Room-temperature valence\ntransition in a strain-tuned perovskite oxide","volume":"13","author":"Chaturvedi","year":"2022","journal-title":"Nat. Commun."},{"key":"2026081707182190200_cit25","doi-asserted-by":"publisher","first-page":"5731","DOI":"10.1021\/jacs.9b13508","article-title":"Sequential\nSpin State Transition and Intermetallic Charge Transfer in PbCoO3","volume":"142","author":"Liu","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"2026081707182190200_cit26","doi-asserted-by":"publisher","first-page":"60","DOI":"10.1038\/nature07816","article-title":"Temperature-induced\nA-B intersite charge transfer in\nan A-site-ordered LaCu3Fe4O12 perovskite","volume":"458","author":"Long","year":"2009","journal-title":"Nature"},{"key":"2026081707182190200_cit27","doi-asserted-by":"publisher","first-page":"13751","DOI":"10.1021\/ic402344m","article-title":"Control of Bond-Strain-Induced\nElectronic Phase Transitions in Iron Perovskites","volume":"52","author":"Yamada","year":"2013","journal-title":"Inorg. Chem."},{"key":"2026081707182190200_cit28","doi-asserted-by":"publisher","first-page":"063901","DOI":"10.1063\/1.1841463","article-title":"Preparation,\nheat capacity, magnetic properties, and the magnetocaloric effect\nof EuO","volume":"97","author":"Ahn","year":"2005","journal-title":"J. Appl. Phys."},{"key":"2026081707182190200_cit29","doi-asserted-by":"publisher","first-page":"064424","DOI":"10.1103\/PhysRevB.76.064424","article-title":"Heat capacity\nand magnetic properties of a EuVO3 single crystal","volume":"76","author":"Tung","year":"2007","journal-title":"Phys. Rev. B"},{"key":"2026081707182190200_cit30","doi-asserted-by":"publisher","first-page":"174418","DOI":"10.1103\/PhysRevB.97.174418","article-title":"Anisotropic magnetocaloric\neffect in single crystals\nof CrI3","volume":"97","author":"Liu","year":"2018","journal-title":"Phys. Rev. B"},{"key":"2026081707182190200_cit31","doi-asserted-by":"publisher","first-page":"35\/1","DOI":"10.1038\/s41427-020-0214-y","article-title":"Machine-learning-guided\ndiscovery of the gigantic magnetocaloric effect in HoB2 near the hydrogen liquefaction temperature","volume":"12","author":"de\nCastro","year":"2020","journal-title":"NPG Asia Materials"},{"key":"2026081707182190200_cit32","doi-asserted-by":"publisher","first-page":"772","DOI":"10.1021\/ic50146a014","article-title":"Complex oxides containing\ndivalent europium. I. Guidelines\nfor the prediction of new phases. Application to phases of the type\neuropium metal oxide (EuMO3)","volume":"14","author":"McCarthy","year":"1975","journal-title":"Inorg. 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Bull."},{"key":"2026081707182190200_cit41","doi-asserted-by":"publisher","first-page":"24","DOI":"10.1016\/0925-8388(95)01597-3","article-title":"Synthesis and structural,\nmagnetic and electrical characterisation of the reduced oxoniobates\nBaNb8O14, EuNb8O14, Eu2Nb5O9 and EuxNbO3 (x = 0.7, 1.0)","volume":"226","author":"Zubkov","year":"1995","journal-title":"J. Alloys Comp."},{"key":"2026081707182190200_cit42","doi-asserted-by":"publisher","first-page":"385","DOI":"10.1103\/PhysRev.143.385","article-title":"Magnetic and Structural\nProperties\nof Europium Metal and Europium Monooxide at High Pressure","volume":"148","author":"Mcwhan","year":"1966","journal-title":"Phys. Rev."},{"key":"2026081707182190200_cit43","doi-asserted-by":"publisher","first-page":"134108","DOI":"10.1103\/PhysRevB.102.134108","article-title":"Quantifying the stability of the anion ordering in\nSrVO2H","volume":"102","author":"Ochi","year":"2020","journal-title":"Phys. Rev. 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Phys."},{"key":"2026081707182190200_cit47","doi-asserted-by":"publisher","first-page":"26","DOI":"10.3390\/inorganics8040026","article-title":"A Partial Anion Disorder in SrVO2H Induced\nby Biaxial Tensile Strain","volume":"8","author":"Namba","year":"2020","journal-title":"Inorganics"},{"key":"2026081707182190200_cit48","doi-asserted-by":"publisher","first-page":"3779","DOI":"10.1021\/acs.cgd.1c00098","article-title":"Strain-Assisted\nTopochemical\nSynthesis of La-Doped SrVO2H Films","volume":"21","author":"Takatsu","year":"2021","journal-title":"Cryst. Growth Des."},{"key":"2026081707182190200_cit49","volume-title":"Thin Film Materials:\nStress, Defect Formation and Surface Evolution","author":"Freund","year":"2003"},{"key":"2026081707182190200_cit50","doi-asserted-by":"publisher","first-page":"65","DOI":"10.1146\/annurev-matsci-070813-113447","article-title":"Magnetic Oxide Heterostructures","volume":"44","author":"Bhattacharya","year":"2014","journal-title":"Annu. Rev. Mater. 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Lett."},{"key":"2026081707182190200_cit61","doi-asserted-by":"publisher","first-page":"157201","DOI":"10.1103\/PhysRevLett.91.157201","article-title":"Origin of Magnetic Anisotropy of Gd Metal","volume":"91","author":"Colarienti-Tosti","year":"2003","journal-title":"Phys. Rev. Lett."},{"key":"2026081707182190200_cit62","doi-asserted-by":"publisher","first-page":"114707","DOI":"10.7566\/JPSJ.84.114707","article-title":"Effect of\nSpin-Orbit Coupling on Kondo Phenomena in f7-Electron Systems","volume":"84","author":"Hotta","year":"2015","journal-title":"J. Phys. Soc. Jpn."},{"key":"2026081707182190200_cit63","doi-asserted-by":"publisher","first-page":"2707","DOI":"10.1088\/0953-8984\/16\/15\/021","article-title":"Pressure induced\nFe2+ + Ti4+ \u2192\nFe3+ + Ti3+ intervalence charge transfer and\nthe Fe3+\/Fe2+ ratio in natural ilmenite (FeTiO3) minerals","volume":"16","author":"Seda","year":"2004","journal-title":"J. Phys. Cond. Matter."},{"key":"2026081707182190200_cit64","doi-asserted-by":"publisher","first-page":"934","DOI":"10.31635\/ccschem.022.202201989","article-title":"Pressure-Induced\nIntermetallic Charge Transfer and SemiconductorMetal Transition in\nTwo-Dimensional AgRuO3","volume":"5","author":"Zhu","year":"2023","journal-title":"CCS Chem."},{"key":"2026081707182190200_cit65","doi-asserted-by":"publisher","first-page":"2388","DOI":"10.1143\/JJAP.29.2388","article-title":"New Classification\nMethod for Layered Copper Oxide Compounds and\nIts Applicatoin to Design of New High Tc Superconductors","volume":"29","author":"Tokura","year":"1990","journal-title":"J. J. Appl. Phys."},{"key":"2026081707182190200_cit66","doi-asserted-by":"publisher","first-page":"126752","DOI":"10.1016\/j.jcrysgro.2022.126752","article-title":"Single-crystal thin\nfilm growth of the Mott insulator EuVO3 under biaxial substrate\nstrain","volume":"593","author":"Takatsu","year":"2022","journal-title":"J. Cryst. 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