{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T04:18:38Z","timestamp":1793074718316,"version":"4.5.0"},"reference-count":49,"publisher":"American Chemical Society (ACS)","issue":"5","license":[{"start":{"date-parts":[[2024,1,25]],"date-time":"2024-01-25T00:00:00Z","timestamp":1706140800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2024,1,25]],"date-time":"2024-01-25T00:00:00Z","timestamp":1706140800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2024,1,25]],"date-time":"2024-01-25T00:00:00Z","timestamp":1706140800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100005237","name":"Helen Hay Whitney Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100005237","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000183","name":"Army Research Office","doi-asserted-by":"publisher","award":["W911NF-19-0026"],"award-info":[{"award-number":["W911NF-19-0026"]}],"id":[{"id":"10.13039\/100000183","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100001229","name":"G. Harold and Leila Y. Mathers Charitable Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100001229","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100005156","name":"Alexander von Humboldt-Stiftung","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100005156","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-2153972"],"award-info":[{"award-number":["CHE-2153972"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2024,2,7]]},"DOI":"10.1021\/jacs.3c06030","type":"journal-article","created":{"date-parts":[[2024,1,25]],"date-time":"2024-01-25T15:48:47Z","timestamp":1706197727000},"page":"2959-2966","source":"Crossref","is-referenced-by-count":35,"title":["Iron Heme Enzyme-Catalyzed Cyclopropanations with Diazirines as Carbene Precursors: Computational Explorations of Diazirine Activation and Cyclopropanation Mechanism"],"prefix":"10.1021","volume":"146","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4519-4596","authenticated-orcid":true,"given":"Torben","family":"Rogge","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingyang","family":"Zhou","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nicholas J.","family":"Porter","sequence":"additional","affiliation":[{"name":"Division of Chemistry and Chemical Engineering, Division of Biology and Bioengineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4027-364X","authenticated-orcid":true,"given":"Frances H.","family":"Arnold","sequence":"additional","affiliation":[{"name":"Division of Chemistry and Chemical Engineering, Division of Biology and Bioengineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8387-5261","authenticated-orcid":true,"given":"K. N.","family":"Houk","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2024,1,25]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217713"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c00224"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00100K"},{"key":"ref1\/cit1d","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202006648"},{"key":"ref1\/cit1e","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c01496"},{"key":"ref1\/cit1f","doi-asserted-by":"publisher","DOI":"10.1038\/s43586-021-00044-z"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1002\/cbic.202200049"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00260"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1038\/s41589-020-0532-y"},{"key":"ref2\/cit2d","doi-asserted-by":"publisher","DOI":"10.1146\/annurev-biochem-062917-012034"},{"key":"ref2\/cit2e","doi-asserted-by":"publisher","DOI":"10.1038\/nrg3927"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1016\/j.cogsc.2021.100494"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00591"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201708408"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202103437"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c02146"},{"key":"ref4\/cit4c","doi-asserted-by":"publisher","DOI":"10.1038\/nature24996"},{"key":"ref4\/cit4d","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201608680"},{"key":"ref4\/cit4e","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah6219"},{"key":"ref4\/cit4f","doi-asserted-by":"publisher","DOI":"10.1002\/cbic.201500624"},{"key":"ref4\/cit4g","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC00080G"},{"key":"ref4\/cit4h","doi-asserted-by":"publisher","DOI":"10.1126\/science.1231434"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/acs.oprd.9b00422"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02723"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21759"},{"key":"ref7\/cit7d","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344"},{"key":"ref7\/cit7e","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"ref7\/cit7f","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.10189"},{"key":"ref7\/cit7g","doi-asserted-by":"publisher","DOI":"10.1063\/1.448799"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201901984"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208936"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.21203\/rs.3.rs-1639676\/v1"},{"key":"ref9\/cit9c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c00912"},{"key":"ref9\/cit9d","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1807027115"},{"key":"ref9\/cit9e","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b09171"},{"key":"ref9\/cit9f","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b01492"},{"key":"ref9\/cit9g","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b01875"},{"key":"ref9\/cit9h","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04636"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1039\/C7CP01263B"},{"key":"ref11\/cit11","doi-asserted-by":"crossref","first-page":"631","DOI":"10.1002\/9781119129301.ch14","volume-title":"Fundamentals of Porphyrin Chemistry","author":"Nakamura M.","year":"2022"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00321"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1007\/s11224-016-0824-8"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1021\/jp1012939"},{"key":"ref13\/cit13c","doi-asserted-by":"publisher","DOI":"10.1021\/jo034949q"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b02272"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c12004"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06823"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.3c06030","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.3c06030","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,2,7]],"date-time":"2024-02-07T14:26:20Z","timestamp":1707315980000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.3c06030"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,1,25]]},"references-count":49,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2024,2,7]]}},"alternative-id":["10.1021\/jacs.3c06030"],"URL":"https:\/\/doi.org\/10.1021\/jacs.3c06030","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,1,25]]}}}