{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T21:55:18Z","timestamp":1791842118713,"version":"4.3.4"},"reference-count":90,"publisher":"American Chemical Society (ACS)","issue":"46","license":[{"start":{"date-parts":[[2023,11,13]],"date-time":"2023-11-13T00:00:00Z","timestamp":1699833600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2023,11,13]],"date-time":"2023-11-13T00:00:00Z","timestamp":1699833600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2023,11,13]],"date-time":"2023-11-13T00:00:00Z","timestamp":1699833600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22121001"],"award-info":[{"award-number":["22121001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22122305"],"award-info":[{"award-number":["22122305"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22073077"],"award-info":[{"award-number":["22073077"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["E3520802"],"award-info":[{"award-number":["E3520802"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["522023000062"],"award-info":[{"award-number":["522023000062"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2023,11,22]]},"DOI":"10.1021\/jacs.3c08834","type":"journal-article","created":{"date-parts":[[2023,11,13]],"date-time":"2023-11-13T14:58:41Z","timestamp":1699887521000},"page":"25304-25317","source":"Crossref","is-referenced-by-count":31,"title":["Unraveling the Valence State and Reactivity of Copper Centers in Membrane-Bound Particulate Methane Monooxygenase"],"prefix":"10.1021","volume":"145","author":[{"given":"Wei","family":"Peng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces and Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, College of Chemistry and Chemical Engineering and Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen University, Xiamen 361005, P. R. China"},{"name":"Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess and Quaternary Geology (SKLLQG), Institute of Earth Environment, Chinese Academy of Sciences, Xi\u2019an 710061, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4540-8734","authenticated-orcid":true,"given":"Zikuan","family":"Wang","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm-Platz 1, M\u00fclheim an der Ruhr 45470, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiaoyu","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces and Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, College of Chemistry and Chemical Engineering and Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen University, Xiamen 361005, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengheng","family":"Yan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces and Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, College of Chemistry and Chemical Engineering and Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen University, Xiamen 361005, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Binju","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces and Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, College of Chemistry and Chemical Engineering and Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen University, Xiamen 361005, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2023,11,13]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32752-9"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1007\/s00775-016-1419-y"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1146\/annurev.biochem.76.061505.175355"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biochem.5b00198"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0255-1"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00624"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2021.111602"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1038\/s41564-022-01252-3"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c00463"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1146\/annurev-biochem-013118-111529"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/ar1001473"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c05436"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biochem.1c00293"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c01180"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS01291B"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1126\/science.abm3282"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1038\/nature03311"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/acssynbio.2c00366"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav2572"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04568"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.273.14.7957"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c04082"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.3109\/10409238.2012.697865"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/bi200801z"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M114.581363"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.RA118.003348"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-10590-6"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/ic060739v"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/ja5053126"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1038\/nature08992"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1002\/9781119951438.eibc2740"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1099\/mic.0.078584-0"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/ar700004s"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201708977"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1038\/s41589-019-0438-8"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1038\/s41589-019-0437-9"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00591-4"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2019.04.005"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1021\/ja302195p"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c01169"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201103075"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1021\/ar700277n"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC00676B"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c07018"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1007\/s002030000158"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1038\/nature11541"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0536703100"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1128\/JB.185.19.5755-5764.2003"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.47.3037"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1021\/ct200133y"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jctc.5b00255"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jcim.5b00674"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00440"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jcim.1c00203"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21334"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20035"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1021\/j100142a004"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1063\/5.0007045"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1016\/j.cpc.2004.12.014"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1021\/ct050123f"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1063\/1.1462041"},{"key":"ref62\/cit62","doi-asserted-by":"publisher","DOI":"10.1063\/1.2770708"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.1703"},{"key":"ref64\/cit64","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.58.3641"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.100.020603"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.81"},{"key":"ref67\/cit67","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.1327"},{"key":"ref68\/cit68","doi-asserted-by":"publisher","DOI":"10.1063\/5.0004608"},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.1606"},{"key":"ref70\/cit70","doi-asserted-by":"publisher","DOI":"10.1111\/j.1758-2229.2010.00192.x"},{"key":"ref71\/cit71","doi-asserted-by":"publisher","DOI":"10.1515\/hsz-2020-0200"},{"key":"ref72\/cit72","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b00778"},{"key":"ref73\/cit73","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c02914"},{"key":"ref74\/cit74","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10252"},{"key":"ref75\/cit75","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.2c00304"},{"key":"ref76\/cit76","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02273"},{"key":"ref77\/cit77","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c04048"},{"key":"ref78\/cit78","doi-asserted-by":"publisher","DOI":"10.1016\/j.jbc.2023.105094"},{"key":"ref79\/cit79","doi-asserted-by":"publisher","DOI":"10.1042\/EBC20220250"},{"key":"ref80\/cit80","doi-asserted-by":"publisher","DOI":"10.1002\/1873-3468.14629"},{"key":"ref81\/cit81","doi-asserted-by":"publisher","DOI":"10.1006\/abbi.2001.2628"},{"key":"ref82\/cit82","doi-asserted-by":"publisher","DOI":"10.1021\/ja048528h"},{"key":"ref83\/cit83","doi-asserted-by":"publisher","DOI":"10.1021\/ja8019615"},{"key":"ref84\/cit84","doi-asserted-by":"publisher","DOI":"10.1021\/bi051815t"},{"key":"ref85\/cit85","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2012.02.002"},{"key":"ref86\/cit86","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2012.07.008"},{"key":"ref87\/cit87","doi-asserted-by":"publisher","DOI":"10.1021\/ja0558140"},{"key":"ref88\/cit88","doi-asserted-by":"publisher","DOI":"10.1007\/s13361-017-1778-9"},{"key":"ref89\/cit89","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.TM117.000185"},{"key":"ref90\/cit90","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2010.08.002"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.3c08834","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.3c08834","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,11,22]],"date-time":"2023-11-22T10:15:07Z","timestamp":1700648107000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.3c08834"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,11,13]]},"references-count":90,"journal-issue":{"issue":"46","published-print":{"date-parts":[[2023,11,22]]}},"alternative-id":["10.1021\/jacs.3c08834"],"URL":"https:\/\/doi.org\/10.1021\/jacs.3c08834","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,11,13]]}}}