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A\nrecent detailed study employing 18-O isotope labeling shows that the\nmajority reaction pathway (> 85%) for deformylation of 4\u03b1-CHO\ndihydrolanosterol by P450 51A1 occurs via nucleophilic attack by a\nheme-peroxo (\u201cCompound 0\u201d) species. See the next citation."},{"key":"ref40\/cit40b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202317711"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202406542"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0804348105"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1126\/science.adk5097"},{"key":"ref44\/cit44","unstructured":"Molecular Mechanisms of Oxygen Activation; Hayaishi, O., Ed. 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P. Chapter Four - Five Decades of Metalloenzymology\n                      The Enzymes\n                      Kaguni, L. S.; Kaguni, L. S.; Kaguni, L. S.; Kaguni, L. S.; Tamanoi, F., Eds. 2023, Vol 54, pp 71\u2013105."},{"key":"ref62\/cit62b","doi-asserted-by":"publisher","DOI":"10.1039\/C7NP00067G"},{"key":"ref62\/cit62c","unstructured":"(c) One of the two O-atoms from O\n                      2(g)\n                      inserts into the substrate via the key hydroxylating Fe(IV)=O\nactive species, while the other inserts into the 2-OG sacrificial\nco-substrate with loss of CO\n                      2\n                      giving succinate. Examples\nare Prolyl hydroxylase and Taurine hydroxylase (TauD); enzyme relatives\nare SyrB2 (a Halogenase) and Histone demethylases (e.g., AlkB or related\nTET enzymes, demethylating DNA or RNA methylated bases)."},{"key":"ref62\/cit62d","doi-asserted-by":"publisher","DOI":"10.1021\/cr020628n"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1021\/ic991450z"},{"key":"ref64\/cit64","doi-asserted-by":"publisher","DOI":"10.1021\/ja00014a027"},{"key":"ref65\/cit65a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00319a036"},{"key":"ref65\/cit65b","doi-asserted-by":"publisher","DOI":"10.1021\/ja4078717"},{"key":"ref66\/cit66a","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00202j"},{"key":"ref66\/cit66b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201301249"},{"key":"ref66\/cit66c","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2016.07.009"},{"key":"ref67\/cit67a","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2018.09.087"},{"key":"ref67\/cit67b","doi-asserted-by":"publisher","DOI":"10.1002\/ijch.202000045"},{"key":"ref67\/cit67c","doi-asserted-by":"publisher","DOI":"10.1039\/D3DT03747A"},{"key":"ref68\/cit68a","doi-asserted-by":"publisher","DOI":"10.1021\/ic970639c"},{"key":"ref68\/cit68b","doi-asserted-by":"publisher","DOI":"10.1021\/ja00083a018"},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201809634"},{"key":"ref70\/cit70","unstructured":"We must note that effective\noccupancy factors for the coordinated formate anion are about 0.95\n(for Cu1-Cu2 complex) and 0.85 (for Cu3-Cu4); see details in the CIF\nfile (see the SI). Since the formate anions\nare found to be only partially occupied, it is likely there is some\nsmall amount of dicopper(I) complex that co-crystallized along with\nthe targeted mixed-valent Cu\n                      I\n                      \u2212Cu\n                      II\n                      complex."},{"key":"ref71\/cit71a","doi-asserted-by":"publisher","DOI":"10.1039\/DT9840001349"},{"key":"ref71\/cit71b","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201200075"},{"key":"ref72\/cit72a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00243a019"},{"key":"ref72\/cit72b","doi-asserted-by":"publisher","DOI":"10.1021\/ja00228a027"},{"key":"ref73\/cit73a","doi-asserted-by":"publisher","DOI":"10.1021\/cr030011l"},{"key":"ref73\/cit73b","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.12.162"},{"key":"ref74\/cit74a","doi-asserted-by":"publisher","DOI":"10.1007\/s00775-002-0430-7"},{"key":"ref74\/cit74b","doi-asserted-by":"publisher","DOI":"10.1021\/ja0641251"},{"key":"ref74\/cit74c","doi-asserted-by":"publisher","DOI":"10.1038\/nchembio.71"},{"key":"ref74\/cit74d","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c04770"},{"key":"ref75\/cit75a","doi-asserted-by":"publisher","DOI":"10.1007\/s00775-008-0380-9"},{"key":"ref75\/cit75b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b02978"},{"key":"ref76\/cit76a","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt01036g"},{"key":"ref76\/cit76b","doi-asserted-by":"publisher","DOI":"10.1021\/ja800443s"},{"key":"ref77\/cit77a","doi-asserted-by":"publisher","DOI":"10.1021\/ja503629r"},{"key":"ref77\/cit77b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00338"},{"key":"ref77\/cit77c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b02127"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.4c06243","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.4c06243","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,8,28]],"date-time":"2024-08-28T05:58:06Z","timestamp":1724824686000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.4c06243"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,8,14]]},"references-count":179,"journal-issue":{"issue":"34","published-print":{"date-parts":[[2024,8,28]]}},"alternative-id":["10.1021\/jacs.4c06243"],"URL":"https:\/\/doi.org\/10.1021\/jacs.4c06243","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,8,14]]}}}