{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T21:25:38Z","timestamp":1792013138874,"version":"4.4.0"},"reference-count":130,"publisher":"American Chemical Society (ACS)","issue":"1","license":[{"start":{"date-parts":[[2024,12,27]],"date-time":"2024-12-27T00:00:00Z","timestamp":1735257600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2024,12,27]],"date-time":"2024-12-27T00:00:00Z","timestamp":1735257600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2024,12,27]],"date-time":"2024-12-27T00:00:00Z","timestamp":1735257600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["24-13-00310"],"award-info":[{"award-number":["24-13-00310"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007251","name":"National Research University Higher School of Economics","doi-asserted-by":"publisher","award":["23-00-013"],"award-info":[{"award-number":["23-00-013"]}],"id":[{"id":"10.13039\/501100007251","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2025,1,8]]},"DOI":"10.1021\/jacs.4c14062","type":"journal-article","created":{"date-parts":[[2024,12,27]],"date-time":"2024-12-27T12:52:01Z","timestamp":1735303921000},"page":"965-977","source":"Crossref","is-referenced-by-count":7,"title":["FeCl<sub>2<\/sub>-Mediated Rearrangement of Aminoperoxides into Functionalized Tetrahydrofurans: Dynamic Non-innocence of O-Ligands at an Fe Center Coordinates a Radical Cascade"],"prefix":"10.1021","volume":"147","author":[{"given":"Yulia Yu.","family":"Belyakova","sequence":"first","affiliation":[{"name":"N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow 119991, Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2653-0395","authenticated-orcid":true,"given":"Peter S.","family":"Radulov","sequence":"additional","affiliation":[{"name":"N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow 119991, Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3740-7424","authenticated-orcid":true,"given":"Roman A.","family":"Novikov","sequence":"additional","affiliation":[{"name":"N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow 119991, Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ilya V.","family":"Prolomov","sequence":"additional","affiliation":[{"name":"N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow 119991, Russian Federation"},{"name":"Mendeleev University of Chemical Technology, Miusskaya Sq. 9, Moscow 125047, Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nikolai V.","family":"Krivoshchapov","sequence":"additional","affiliation":[{"name":"N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow 119991, Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7070-4052","authenticated-orcid":true,"given":"Michael G.","family":"Medvedev","sequence":"additional","affiliation":[{"name":"N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow 119991, Russian Federation"},{"name":"National Research University Higher School of Economics","place":["Moscow, Russian Federation"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1068-9051","authenticated-orcid":true,"given":"Ivan A.","family":"Yaremenko","sequence":"additional","affiliation":[{"name":"N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow 119991, Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9289-3819","authenticated-orcid":true,"given":"Igor V.","family":"Alabugin","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry","place":["Tallahassee, United States"]},{"name":"Florida State University","place":["Tallahassee, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8018-031X","authenticated-orcid":true,"given":"Alexander O.","family":"Terent\u2019ev","sequence":"additional","affiliation":[{"name":"N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow 119991, Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2024,12,27]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.189903203151"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.190003301153"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0690(199904)1999:4<737::AID-EJOC737>3.0.CO;2-B"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1002\/0471264180.or043.03"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.12.162"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201712651"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.09.014"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201901178"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC01563A"},{"key":"ref10\/cit10","unstructured":"Sergeyev, P. G.; Udris, R. J.; Kruzhalov, B. D.; Nyemtsov, B. D. Sposob odnovremennogo polucheniya fenola i acetona. USSR Patent 106992, 1947."},{"key":"ref11\/cit11","unstructured":"Udris, R. J.; Sergeyev, P. G.; Kruzhalov, B. D. Sposob polucheniya gidroperekisejj alkilirovannykh-proizvodnykh benzola ili alicikloaromaticheskikh uglevodorodov. USSR Patent 106666, 1947."},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19440770321"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.3390\/catal12010091"},{"key":"ref14\/cit14","unstructured":"Wang, Z. Hock Rearrangement. In  Comprehensive Organic Name Reactions and Reagents; John Wiley & Sons, Inc.: 2010."},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201703775"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.0c00837"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-04983-2"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/ja804162d"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2010.08.068"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c02640"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b00155"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1016\/j.pt.2019.05.002"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2021.128522"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.3390\/molecules25030465"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2015.02.010"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/acschembio.5b00900"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.3390\/molecules25081954"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2020.112044"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1002\/cmdc.202200328"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201904555"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1016\/j.antiviral.2011.07.018"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2015.07.048"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1016\/j.biotechadv.2018.01.001"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1016\/j.trechm.2023.01.001"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1023\/A:1015009603719"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC06157K"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1055\/s-1994-25596"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1007\/BF00948868"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1021\/jo01053a037"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(02)01522-3"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC03013B"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2016.04.054"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1055\/a-2044-4571"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.4c02999"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1126\/science.adi4758"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c00885"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2010.01.098"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b00173"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c02663"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1055\/s-0030-1260006"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/ja990807v"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(02)00166-1"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202300881"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.59761\/RCR5125"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1016\/j.phytochem.2022.113326"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1007\/s11101-021-09758-0"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1021\/cr3004778"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.3390\/md20100642"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsb.2022.05.020"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c03182"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c05040"},{"key":"ref62\/cit62","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c01411"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b01253"},{"key":"ref64\/cit64","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.8b02828"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1039\/D0QO01312A"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaq0445"},{"key":"ref67\/cit67","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-020-0439-8"},{"key":"ref68\/cit68","doi-asserted-by":"publisher","DOI":"10.1021\/jo982104m"},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702925"},{"key":"ref70\/cit70","doi-asserted-by":"publisher","DOI":"10.1021\/ja5029155"},{"key":"ref71\/cit71","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2015.09.016"},{"key":"ref72\/cit72","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b03510"},{"key":"ref73\/cit73","doi-asserted-by":"publisher","DOI":"10.1021\/ja809873u"},{"key":"ref74\/cit74","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2016.06.076"},{"key":"ref75\/cit75","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c02249"},{"key":"ref76\/cit76","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c00406"},{"key":"ref77\/cit77","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201610699"},{"key":"ref78\/cit78","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0690(199903)1999:3<617::AID-EJOC617>3.0.CO;2-R"},{"key":"ref79\/cit79","doi-asserted-by":"publisher","DOI":"10.1039\/C3NJ01454A"},{"key":"ref80\/cit80","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806312"},{"key":"ref81\/cit81","doi-asserted-by":"publisher","DOI":"10.2174\/1570193X15666180608084557"},{"key":"ref82\/cit82","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201310985"},{"key":"ref83\/cit83","doi-asserted-by":"publisher","DOI":"10.1006\/jmrb.1995.1028"},{"key":"ref84\/cit84","volume-title":"eMagRes.","author":"Muhandiram R.","year":"2007"},{"key":"ref85\/cit85","doi-asserted-by":"publisher","DOI":"10.1039\/C9FD00008A"},{"key":"ref86\/cit86","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-51237-5"},{"key":"ref87\/cit87","doi-asserted-by":"publisher","DOI":"10.1039\/b403435j"},{"key":"ref88\/cit88","doi-asserted-by":"publisher","DOI":"10.1063\/5.0004608"},{"key":"ref89\/cit89","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.81"},{"key":"ref90\/cit90","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.1606"},{"key":"ref91\/cit91","doi-asserted-by":"publisher","DOI":"10.1039\/b810189b"},{"key":"ref92\/cit92","doi-asserted-by":"publisher","DOI":"10.1063\/1.5090222"},{"key":"ref93\/cit93","doi-asserted-by":"publisher","DOI":"10.1039\/D0CP00502A"},{"key":"ref94\/cit94","doi-asserted-by":"publisher","DOI":"10.1063\/1.4993215"},{"key":"ref95\/cit95","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"ref96\/cit96","doi-asserted-by":"publisher","DOI":"10.1039\/b515623h"},{"key":"ref97\/cit97","doi-asserted-by":"publisher","DOI":"10.1063\/1.4939030"},{"key":"ref98\/cit98","doi-asserted-by":"publisher","DOI":"10.1007\/s00214-007-0250-5"},{"key":"ref99\/cit99","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jctc.2c00265"},{"key":"ref100\/cit100","doi-asserted-by":"publisher","DOI":"10.3390\/i3040360"},{"key":"ref101\/cit101","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202205735"},{"key":"ref102\/cit102","doi-asserted-by":"publisher","DOI":"10.1002\/qua.560360824"},{"key":"ref103\/cit103","doi-asserted-by":"publisher","DOI":"10.1021\/jp9716997"},{"key":"ref104\/cit104","doi-asserted-by":"publisher","DOI":"10.1002\/andp.201300720"},{"key":"ref105\/cit105","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b01537"},{"key":"ref106\/cit106","unstructured":"https:\/\/www.faccts.de\/docs\/orca\/5.0\/tutorials\/prop\/cpcm.html (accessed 05 oct 2024)."},{"key":"ref107\/cit107","volume-title":"Essentials of Computational Chemistry: Theories and Models","author":"Cramer C. J.","year":"2005"},{"key":"ref108\/cit108","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.25873"},{"key":"ref109\/cit109","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410637"},{"key":"ref110\/cit110","doi-asserted-by":"publisher","DOI":"10.1039\/C9CP06869D"},{"key":"ref111\/cit111","doi-asserted-by":"publisher","DOI":"10.1063\/5.0197592"},{"key":"ref112\/cit112","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c04568"},{"key":"ref113\/cit113","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.4c02515"},{"key":"ref114\/cit114","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c01356"},{"key":"ref115\/cit115","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.2c00663"},{"key":"ref116\/cit116","doi-asserted-by":"publisher","DOI":"10.1021\/ct400687b"},{"key":"ref117\/cit117","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.8b00184"},{"key":"ref118\/cit118","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c01634"},{"key":"ref119\/cit119","doi-asserted-by":"publisher","DOI":"10.1002\/poc.4202"},{"key":"ref120\/cit120","doi-asserted-by":"publisher","DOI":"10.1146\/annurev.physchem.56.092503.141240"},{"key":"ref121\/cit121","doi-asserted-by":"publisher","DOI":"10.1098\/rsta.2016.0204"},{"key":"ref122\/cit122","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.3c03540"},{"key":"ref123\/cit123","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00386K"},{"key":"ref124\/cit124","doi-asserted-by":"publisher","DOI":"10.1021\/jo102467j"},{"key":"ref125\/cit125","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.3c00161"},{"key":"ref126\/cit126","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.4c00233"},{"key":"ref127\/cit127","doi-asserted-by":"publisher","DOI":"10.1186\/s12951-022-01661-w"},{"key":"ref128\/cit128","doi-asserted-by":"publisher","DOI":"10.3389\/fphar.2020.529881"},{"key":"ref129\/cit129","doi-asserted-by":"publisher","DOI":"10.3390\/pharmaceutics14020395"},{"key":"ref130\/cit130","doi-asserted-by":"publisher","DOI":"10.1016\/j.tips.2020.11.003"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.4c14062","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.4c14062","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,2,25]],"date-time":"2025-02-25T16:09:42Z","timestamp":1740499782000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.4c14062"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,12,27]]},"references-count":130,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2025,1,8]]}},"alternative-id":["10.1021\/jacs.4c14062"],"URL":"https:\/\/doi.org\/10.1021\/jacs.4c14062","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,12,27]]}}}