{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T01:17:11Z","timestamp":1767835031620,"version":"3.49.0"},"reference-count":51,"publisher":"American Chemical Society (ACS)","issue":"8","license":[{"start":{"date-parts":[[2025,2,17]],"date-time":"2025-02-17T00:00:00Z","timestamp":1739750400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,2,17]],"date-time":"2025-02-17T00:00:00Z","timestamp":1739750400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,2,17]],"date-time":"2025-02-17T00:00:00Z","timestamp":1739750400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100004541","name":"Ministry of Education, India","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004541","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Anusandhan National Research Foundation, India","award":["CRG\/2023\/002353"],"award-info":[{"award-number":["CRG\/2023\/002353"]}]},{"name":"Anusandhan National Research Foundation, India","award":["SR\/ FST\/CSII-027\/2014"],"award-info":[{"award-number":["SR\/ FST\/CSII-027\/2014"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2025,2,26]]},"DOI":"10.1021\/jacs.4c17319","type":"journal-article","created":{"date-parts":[[2025,2,17]],"date-time":"2025-02-17T13:57:57Z","timestamp":1739800677000},"page":"6905-6913","source":"Crossref","is-referenced-by-count":10,"title":["Cyclic (Alkenyl)(Amino)Carbene (<sup><i>SMe<\/i><\/sup>CA<sub>en<\/sub>AC): Introducing a Member to the Cyclic (Alkyl)(Amino)Carbenes Family Featuring a Narrow Energy Gap"],"prefix":"10.1021","volume":"147","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-9716-5177","authenticated-orcid":true,"given":"Chinmoy","family":"Majumder","sequence":"first","affiliation":[{"name":"Department of Chemistry","place":["New Delhi, India"]},{"name":"Indian Institute of Technology Delhi","place":["New Delhi, India"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-8846-2368","authenticated-orcid":true,"given":"Ankita","family":"Sharma","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["New Delhi, India"]},{"name":"Indian Institute of Technology Delhi","place":["New Delhi, India"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5723-1529","authenticated-orcid":true,"given":"Bindusagar","family":"Das","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["New Delhi, India"]},{"name":"Indian Institute of Technology Delhi","place":["New Delhi, India"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0145-5213","authenticated-orcid":true,"given":"Ritu","family":"Yadav","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["New Delhi, India"]},{"name":"Indian Institute of Technology Delhi","place":["New Delhi, India"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2308-5452","authenticated-orcid":true,"given":"Subrata","family":"Kundu","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["New Delhi, India"]},{"name":"Indian Institute of Technology Delhi","place":["New Delhi, India"]}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2025,2,17]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00227a028"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00001a054"},{"key":"ref2\/cit2b","volume-title":"N-Heterocyclic Carbenes, from Laboratory Curiosities to Efficient Synthetic Tools","author":"Royal Society of Chemistry","year":"2011"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1021\/ja908253u"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00079"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1055\/s-0033-1339192"},{"key":"ref3\/cit3d","doi-asserted-by":"publisher","DOI":"10.1038\/nature13384"},{"key":"ref3\/cit3e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703883"},{"key":"ref3\/cit3f","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201105415"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00067"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00791"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200501841"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaq1684"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1021\/ar5003494"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC01351B"},{"key":"ref6\/cit6d","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202101301"},{"key":"ref6\/cit6e","doi-asserted-by":"publisher","DOI":"10.1002\/ciuz.201800826"},{"key":"ref6\/cit6f","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702148"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c05508"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC05613E"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04640"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b05518"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507844"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1021\/ja907481w"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201202137"},{"key":"ref11\/cit11c","doi-asserted-by":"publisher","DOI":"10.1021\/om1007665"},{"key":"ref11\/cit11d","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.202200334"},{"key":"ref11\/cit11e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201108813"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05221"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202312858"},{"key":"ref12\/cit12c","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC03871D"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00043"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2012.08.008"},{"key":"ref15\/cit15a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202401020"},{"key":"ref15\/cit15b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202637"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt51309b"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201601406"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201601254"},{"key":"ref19\/cit19a","doi-asserted-by":"publisher","DOI":"10.1021\/om061133h"},{"key":"ref19\/cit19b","doi-asserted-by":"publisher","DOI":"10.1039\/C8RA09065C"},{"key":"ref19\/cit19c","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201901647"},{"key":"ref19\/cit19d","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC03269J"},{"key":"ref19\/cit19e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201309755"},{"key":"ref19\/cit19f","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c03182"},{"key":"ref19\/cit19g","volume-title":"Comprehensive Organic Synthesis","author":"Mauduit M.","year":"2014"},{"key":"ref20\/cit20a","doi-asserted-by":"publisher","DOI":"10.1055\/s-0040-1706092"},{"key":"ref20\/cit20b","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC06962D"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC01216F"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c01723"},{"key":"ref23\/cit23a","doi-asserted-by":"publisher","DOI":"10.1126\/science.1141474"},{"key":"ref23\/cit23b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b04957"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.4c17319","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.4c17319","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,2,26]],"date-time":"2025-02-26T09:23:24Z","timestamp":1740561804000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.4c17319"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,2,17]]},"references-count":51,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2025,2,26]]}},"alternative-id":["10.1021\/jacs.4c17319"],"URL":"https:\/\/doi.org\/10.1021\/jacs.4c17319","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,2,17]]}}}