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H(sebenzimMe) also reacts with methylmercury halides, but the reaction is accompanied by elimination of methane resulting from protolytic cleavage of the Hg\u2013C bond, an observation that is of relevance to the report that selenoneine demethylates CysHgMe, thereby providing a mechanism for mercury detoxification. Interestingly, the structures of [H(sebenzimMe)]xHgX2 exhibit a variety of different hydrogen bonding patterns resulting from the ability of the N\u2013H groups to form hydrogen bonds with chlorine, iodine, and selenium.<\/jats:p>","DOI":"10.1021\/jacs.5b00840","type":"journal-article","created":{"date-parts":[[2015,3,30]],"date-time":"2015-03-30T14:02:50Z","timestamp":1427724170000},"page":"4503-4516","source":"Crossref","is-referenced-by-count":40,"title":["Protolytic Cleavage of Hg\u2013C Bonds Induced by\n1-Methyl-1,3-dihydro-2\n                    <i>H<\/i>\n                    -benzimidazole-2-selone:\nSynthesis and Structural Characterization of Mercury Complexes"],"prefix":"10.1021","volume":"137","author":[{"given":"Joshua H.","family":"Palmer","sequence":"first","affiliation":[{"name":"Columbia University , , , ,","place":["New York, New York, United States, 10027"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gerard","family":"Parkin","sequence":"additional","affiliation":[{"name":"Columbia University , , , ,","place":["New York, New York, United States, 10027"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2015,3,30]]},"reference":[{"key":"2026090108032410600_cit1a","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1016\/j.jtemb.2012.02.004","volume":"26","author":"Syversen","year":"2012","journal-title":"J. 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