{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T02:47:08Z","timestamp":1791946028365,"version":"4.3.4"},"reference-count":130,"publisher":"American Chemical Society (ACS)","issue":"44","funder":[{"DOI":"10.13039\/100001082","name":"Camille and Henry Dreyfus Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100001082","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006961","name":"California Institute of Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006961","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["R01-GM102687A"],"award-info":[{"award-number":["R01-GM102687A"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2015,11,11]]},"DOI":"10.1021\/jacs.5b07397","type":"journal-article","created":{"date-parts":[[2015,9,21]],"date-time":"2015-09-21T17:47:44Z","timestamp":1442857664000},"page":"14094-14106","source":"Crossref","is-referenced-by-count":39,"title":["Nitric Oxide Activation by Distal Redox Modulation in Tetranuclear Iron Nitrosyl Complexes"],"prefix":"10.1021","volume":"137","author":[{"given":"Graham","family":"de Ruiter","sequence":"first","affiliation":[{"name":"Division\rof Chemistry and\rChemical Engineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Niklas B.","family":"Thompson","sequence":"additional","affiliation":[{"name":"Division\rof Chemistry and\rChemical Engineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Davide","family":"Lionetti","sequence":"additional","affiliation":[{"name":"Division\rof Chemistry and\rChemical Engineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Theodor","family":"Agapie","sequence":"additional","affiliation":[{"name":"Division\rof Chemistry and\rChemical Engineering, California Institute of Technology, Pasadena, California 91125, United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2015,11,2]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1021\/cr400641x"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1021\/cr4005814"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1021\/cr400327t"},{"key":"ref1\/cit1d","doi-asserted-by":"publisher","DOI":"10.1021\/cr4004874"},{"key":"ref1\/cit1e","doi-asserted-by":"publisher","DOI":"10.1038\/nature08299"},{"key":"ref1\/cit1f","doi-asserted-by":"publisher","DOI":"10.1021\/cr0503153"},{"key":"ref1\/cit1g","doi-asserted-by":"publisher","DOI":"10.1021\/cr9500390"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0204294"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1038\/nature13991"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1038\/nature09913"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1126\/science.1093087"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1970.tb06017.x"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1016\/S0969-2126(99)80005-7"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1038\/373580a0"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1126\/science.1061500"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1038\/nsb823"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1038\/nsb912"},{"key":"ref9\/cit9a","doi-asserted-by":"publisher","DOI":"10.1021\/cr950051s"},{"key":"ref9\/cit9b","doi-asserted-by":"publisher","DOI":"10.1126\/science.7652554"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1021\/ar300267m"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1126\/science.1214025"},{"key":"ref10\/cit10d","doi-asserted-by":"publisher","DOI":"10.1007\/s11244-006-0002-0"},{"key":"ref10\/cit10e","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(02)00248-5"},{"key":"ref10\/cit10f","doi-asserted-by":"publisher","DOI":"10.1126\/science.1073877"},{"key":"ref10\/cit10g","doi-asserted-by":"publisher","DOI":"10.1021\/cr9500545"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1021\/cr950057h"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1302677110"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1021\/ja4104974"},{"key":"ref12\/cit12c","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1578"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1021\/ja5115198"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1021\/ja508630d"},{"key":"ref13\/cit13c","doi-asserted-by":"publisher","DOI":"10.1021\/ja508160x"},{"key":"ref13\/cit13d","doi-asserted-by":"publisher","DOI":"10.1039\/c4sc00453a"},{"key":"ref13\/cit13e","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1571"},{"key":"ref13\/cit13q","doi-asserted-by":"publisher","DOI":"10.1021\/ja309782m"},{"key":"ref13\/cit13f","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1180"},{"key":"ref13\/cit13g","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1284"},{"key":"ref13\/cit13h","doi-asserted-by":"publisher","DOI":"10.1021\/ja3083818"},{"key":"ref13\/cit13i","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201203602"},{"key":"ref13\/cit13j","doi-asserted-by":"publisher","DOI":"10.1126\/science.1206036"},{"key":"ref13\/cit13k","doi-asserted-by":"publisher","DOI":"10.1039\/c1sc00062d"},{"key":"ref13\/cit13l","doi-asserted-by":"publisher","DOI":"10.1021\/ja2052655"},{"key":"ref13\/cit13m","doi-asserted-by":"publisher","DOI":"10.1021\/ja909718f"},{"key":"ref13\/cit13n","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.586"},{"key":"ref13\/cit13o","doi-asserted-by":"publisher","DOI":"10.1021\/ja903394s"},{"key":"ref13\/cit13p","doi-asserted-by":"publisher","DOI":"10.1021\/ja906137y"},{"key":"ref13\/cit13r","doi-asserted-by":"publisher","DOI":"10.1126\/science.1135844"},{"key":"ref13\/cit13s","doi-asserted-by":"publisher","DOI":"10.1126\/science.271.5254.1397"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/ic402236f"},{"key":"ref15\/cit15a","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc05608a"},{"key":"ref15\/cit15b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201005232"},{"key":"ref16\/cit16a","doi-asserted-by":"publisher","DOI":"10.1021\/ja510615p"},{"key":"ref16\/cit16b","doi-asserted-by":"publisher","DOI":"10.1126\/science.1198315"},{"key":"ref16\/cit16c","doi-asserted-by":"publisher","DOI":"10.1038\/nature12435"},{"key":"ref16\/cit16d","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201305291"},{"key":"ref16\/cit16e","doi-asserted-by":"publisher","DOI":"10.1021\/ja207048h"},{"key":"ref16\/cit16f","doi-asserted-by":"publisher","DOI":"10.1021\/ja110798w"},{"key":"ref16\/cit16g","doi-asserted-by":"publisher","DOI":"10.1021\/ja1008213"},{"key":"ref16\/cit16h","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.660"},{"key":"ref16\/cit16i","doi-asserted-by":"publisher","DOI":"10.1126\/science.289.5481.938"},{"key":"ref16\/cit16j","doi-asserted-by":"publisher","DOI":"10.1021\/ic990070a"},{"key":"ref16\/cit16k","doi-asserted-by":"publisher","DOI":"10.1021\/ja960036k"},{"key":"ref16\/cit16l","doi-asserted-by":"publisher","DOI":"10.1021\/ja00089a028"},{"key":"ref17\/cit17a","volume-title":"Advanced Inorganic Chemistry","author":"Cotton F. A.","year":"1999","edition":"6"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.1021\/ic9814468"},{"key":"ref17\/cit17c","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(97)05538-2"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/ic902360x"},{"key":"ref19\/cit19a","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2013.02.035"},{"key":"ref19\/cit19b","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201200396"},{"key":"ref19\/cit19c","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201001166"},{"key":"ref19\/cit19d","doi-asserted-by":"publisher","DOI":"10.1039\/b607731e"},{"key":"ref19\/cit19e","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(99)00252-2"},{"key":"ref20\/cit20a","doi-asserted-by":"publisher","DOI":"10.1021\/cr4004067"},{"key":"ref20\/cit20b","doi-asserted-by":"publisher","DOI":"10.1021\/cr020615+"},{"key":"ref21\/cit21a","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201326"},{"key":"ref21\/cit21b","doi-asserted-by":"publisher","DOI":"10.1021\/ic960052i"},{"key":"ref21\/cit21c","doi-asserted-by":"publisher","DOI":"10.1039\/dt9870000831"},{"key":"ref21\/cit21d","doi-asserted-by":"publisher","DOI":"10.1021\/ja00444a017"},{"key":"ref22\/cit22a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b06453"},{"key":"ref22\/cit22b","doi-asserted-by":"publisher","DOI":"10.1021\/ja2015845"},{"key":"ref22\/cit22c","doi-asserted-by":"publisher","DOI":"10.1021\/ja035962v"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/ja406506m"},{"key":"ref24\/cit24a","doi-asserted-by":"publisher","DOI":"10.1021\/ic201123x"},{"key":"ref24\/cit24b","doi-asserted-by":"publisher","DOI":"10.1021\/ic1009972"},{"key":"ref25\/cit25","doi-asserted-by":"crossref","DOI":"10.1007\/978-3-540-88428-6","volume-title":"M\u00f6ssbauer Spectroscopy and Transition Metal Chemistry","author":"Gutlich P.","year":"2011"},{"key":"ref26\/cit26a","doi-asserted-by":"publisher","DOI":"10.1021\/ic501793v"},{"key":"ref26\/cit26b","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200900292"},{"key":"ref26\/cit26c","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200800032"},{"key":"ref26\/cit26d","doi-asserted-by":"publisher","DOI":"10.1021\/ic030192+"},{"key":"ref26\/cit26e","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3749(200211)628:11<2443::AID-ZAAC2443>3.0.CO;2-1"},{"key":"ref26\/cit26f","doi-asserted-by":"publisher","DOI":"10.1021\/ic971081b"},{"key":"ref27\/cit27","doi-asserted-by":"crossref","unstructured":"Reiff, W. M.; Long, G. J.InMossbauer Spectroscopy Applied to Inorganic Chemistry;Long, G. J., Ed.Plenum Press:New York, 1984; Vol.1, p245.","DOI":"10.1007\/978-1-4899-0462-1_10"},{"key":"ref28\/cit28","volume-title":"Solution NMR of Paramagnetic Molecules","volume":"2","author":"Bertini I.","year":"2001"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/cr020623q"},{"key":"ref30\/cit30a","volume-title":"Nitric Oxide","author":"Ignarro L. J.","year":"2010","edition":"2"},{"key":"ref30\/cit30b","doi-asserted-by":"publisher","DOI":"10.1021\/cr0006627"},{"key":"ref30\/cit30c","doi-asserted-by":"publisher","DOI":"10.1021\/cr000078y"},{"key":"ref30\/cit30d","first-page":"503","volume":"53","author":"Ignarro L. J.","year":"2002","journal-title":"J. Physiol. Pharamacol."},{"key":"ref30\/cit30e","doi-asserted-by":"publisher","DOI":"10.1126\/science.1361684"},{"key":"ref31\/cit31a","doi-asserted-by":"publisher","DOI":"10.1021\/ja505415c"},{"key":"ref31\/cit31b","doi-asserted-by":"publisher","DOI":"10.1021\/ic500586g"},{"key":"ref31\/cit31c","doi-asserted-by":"publisher","DOI":"10.1021\/ja8054996"},{"key":"ref31\/cit31d","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19931050434"},{"key":"ref32\/cit32a","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.05.007"},{"key":"ref32\/cit32b","doi-asserted-by":"publisher","DOI":"10.1080\/02603594.2013.847828"},{"key":"ref32\/cit32c","doi-asserted-by":"publisher","DOI":"10.1021\/cr000074t"},{"key":"ref33\/cit33a","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201000524"},{"key":"ref33\/cit33b","doi-asserted-by":"publisher","DOI":"10.1021\/ja0719982"},{"key":"ref33\/cit33c","doi-asserted-by":"publisher","DOI":"10.1039\/b200694b"},{"key":"ref33\/cit33d","doi-asserted-by":"publisher","DOI":"10.1021\/ic970124l"},{"key":"ref33\/cit33e","doi-asserted-by":"publisher","DOI":"10.1021\/ic50161a018"},{"key":"ref33\/cit33f","first-page":"653","volume":"4","author":"Di Vaira M.","year":"1975","journal-title":"Cryst. Struct. Commun."},{"key":"ref34\/cit34a","doi-asserted-by":"publisher","DOI":"10.1021\/ic201565d"},{"key":"ref34\/cit34b","doi-asserted-by":"publisher","DOI":"10.1021\/ic061874a"},{"key":"ref34\/cit34c","doi-asserted-by":"publisher","DOI":"10.1039\/j19700001627"},{"key":"ref34\/cit34d","doi-asserted-by":"publisher","DOI":"10.1021\/ja01000a016"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1039\/dt9840001349"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)80259-3"},{"key":"ref100\/cit100","doi-asserted-by":"publisher","DOI":"10.1021\/ja111693f"},{"key":"ref37\/cit37a","doi-asserted-by":"publisher","DOI":"10.1021\/ja4114962"},{"key":"ref37\/cit37b","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1310153110"},{"key":"ref38\/cit38a","doi-asserted-by":"publisher","DOI":"10.1039\/b803153c"},{"key":"ref38\/cit38b","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2007.04.012"},{"key":"ref38\/cit38c","doi-asserted-by":"publisher","DOI":"10.1021\/cr60317a005"},{"key":"ref39\/cit39a","doi-asserted-by":"publisher","DOI":"10.1021\/ja991664f"},{"key":"ref39\/cit39b","doi-asserted-by":"publisher","DOI":"10.1021\/ja982172q"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/ja3013825"},{"key":"ref41\/cit41","unstructured":"APEX-II, Version 2 User Manual, M86-E01078;Bruker Analytical X-ray Systems:Madison, WI, 2006."},{"key":"ref42\/cit42","unstructured":"Sheldrick, G. M.SADABS(version 2008\/1): Program for Absorption Correction for Data from Area Detector Frames;University of G\u00f6ttingen:G\u00f6ttingen, Germany, 2008."},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5b07397","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,4,16]],"date-time":"2023-04-16T13:06:37Z","timestamp":1681650397000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.5b07397"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,11,2]]},"references-count":130,"journal-issue":{"issue":"44","published-print":{"date-parts":[[2015,11,11]]}},"alternative-id":["10.1021\/jacs.5b07397"],"URL":"https:\/\/doi.org\/10.1021\/jacs.5b07397","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,11,2]]}}}