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These measurements allow placement of these fluoride ligands on the scales of organic H-bond acceptor strength. The H-bond acceptor capability \u03b2 (Hunter scale) for the group 10 metal fluorides is far greater (1a 12.1, 1b 9.7, 2 11.6, 3 11.0) than that for group 4 metal fluorides (4a 5.8, 5a 4.7, 6a 4.7, 4b 6.9, 5b 5.6, 6b 5.4), demonstrating that the group 10 fluorides are comparable to the strongest organic H-bond acceptors, such as Me3NO, whereas group 4 fluorides fall in the same range as N-bases aniline through pyridine. Additionally, the measurement of the binding enthalpy of 4-fluorophenol to 1a in carbon tetrachloride (\u221223.5 \u00b1 0.3 kJ mol\u20131) interlocks our study with Laurence\u2019s scale of H-bond basicity of organic molecules. The much greater polarity of group 10 metal fluorides than that of the group 4 metal fluorides is consistent with the importance of p\u03c0\u2013d\u03c0 bonding in the latter. The polarity of the group 10 metal fluorides indicates their potential as building blocks for hydrogen-bonded assemblies. The synthesis of trans-[Ni(F){2-C5NF3(NH2)}(PEt3)2], which exhibits an extended chain structure assembled by hydrogen bonds between the amine and metal-fluoride groups, confirms this hypothesis.<\/jats:p>","DOI":"10.1021\/jacs.5b07509","type":"journal-article","created":{"date-parts":[[2015,8,24]],"date-time":"2015-08-24T13:31:35Z","timestamp":1440423095000},"page":"11820-11831","source":"Crossref","is-referenced-by-count":34,"title":["The\nContrasting Character of Early and Late Transition Metal Fluorides\nas Hydrogen Bond Acceptors"],"prefix":"10.1021","volume":"137","author":[{"given":"Dan A.","family":"Smith","sequence":"first","affiliation":[{"name":"University of York , , , , ,","place":["Heslington, York, U.K., YO10 5DD"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Torsten","family":"Beweries","sequence":"additional","affiliation":[{"name":"University of York , , , , ,","place":["Heslington, York, U.K., YO10 5DD"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Clemens","family":"Blasius","sequence":"additional","affiliation":[{"name":"University of York , , , , ,","place":["Heslington, York, U.K., YO10 5DD"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Naseralla","family":"Jasim","sequence":"additional","affiliation":[{"name":"University of York , , , , ,","place":["Heslington, York, U.K., YO10 5DD"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruqia","family":"Nazir","sequence":"additional","affiliation":[{"name":"University of York , , , , ,","place":["Heslington, York, U.K., YO10 5DD"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sadia","family":"Nazir","sequence":"additional","affiliation":[{"name":"University of York , , , , ,","place":["Heslington, York, U.K., YO10 5DD"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Craig C.","family":"Robertson","sequence":"additional","affiliation":[{"name":"University of Sheffield , , , ,","place":["Sheffield, U.K., S3 7HF"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Adrian C.","family":"Whitwood","sequence":"additional","affiliation":[{"name":"University of York , , , , ,","place":["Heslington, York, U.K., YO10 5DD"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christopher A.","family":"Hunter","sequence":"additional","affiliation":[{"name":"University of Cambridge , , , ,","place":["Cambridge, U.K., CB2 1EW"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lee","family":"Brammer","sequence":"additional","affiliation":[{"name":"University of Sheffield , , , ,","place":["Sheffield, U.K., S3 7HF"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robin N.","family":"Perutz","sequence":"additional","affiliation":[{"name":"University of York , , , , ,","place":["Heslington, York, U.K., YO10 5DD"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2015,8,24]]},"reference":[{"key":"2026090201042309900_cit1","doi-asserted-by":"publisher","first-page":"425","DOI":"10.1039\/B709650J","author":"Natale","year":"2008","journal-title":"Chem. 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