{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T14:05:27Z","timestamp":1778853927154,"version":"3.51.4"},"reference-count":71,"publisher":"American Chemical Society (ACS)","issue":"42","license":[{"start":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T00:00:00Z","timestamp":1759881600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T00:00:00Z","timestamp":1759881600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T00:00:00Z","timestamp":1759881600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100019329","name":"Emerson Collective","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100019329","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100023581","name":"National Science Foundation Graduate Research Fellowship Program","doi-asserted-by":"publisher","award":["DGE 2146752"],"award-info":[{"award-number":["DGE 2146752"]}],"id":[{"id":"10.13039\/100023581","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005612","name":"Shionogi","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100005612","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["R35-GM130387"],"award-info":[{"award-number":["R35-GM130387"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2025,10,22]]},"DOI":"10.1021\/jacs.5c05764","type":"journal-article","created":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T15:28:57Z","timestamp":1759937337000},"page":"37940-37948","source":"Crossref","is-referenced-by-count":3,"title":["Iridium-Catalyzed, Regio- and Stereoselective Silylation of Primary and Secondary C(\n                    <i>sp<\/i>\n                    <sup>3<\/sup>\n                    )\u2013H Bonds in Primary Amines"],"prefix":"10.1021","volume":"147","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1272-1302","authenticated-orcid":true,"given":"Takahiro","family":"Suto","sequence":"first","affiliation":[{"name":"Department of Chemistry","place":["Berkeley, United States"]},{"name":"University of California","place":["Berkeley, United States"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9982-133X","authenticated-orcid":true,"given":"Chris","family":"La","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Berkeley, United States"]},{"name":"University of California","place":["Berkeley, United States"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4157-468X","authenticated-orcid":true,"given":"John F.","family":"Hartwig","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Berkeley, United States"]},{"name":"University of California","place":["Berkeley, United States"]}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"316","published-online":{"date-parts":[[2025,10,8]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1021\/cr9500038"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(00)00149-6"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300599"},{"key":"ref1\/cit1d","doi-asserted-by":"publisher","DOI":"10.1039\/c2ob25357g"},{"key":"ref1\/cit1e","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcatb.2014.12.005"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1021\/ja973527t"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1021\/ja047597t"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1021\/ja0174231"},{"key":"ref2\/cit2d","doi-asserted-by":"publisher","DOI":"10.1021\/ja034787f"},{"key":"ref2\/cit2e","doi-asserted-by":"publisher","DOI":"10.1021\/ja0482435"},{"key":"ref2\/cit2f","doi-asserted-by":"publisher","DOI":"10.1021\/ol0500719"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1021\/jo00269a054"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(98)00483-9"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00401"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/ar960061v"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199604511"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201002323"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1039\/C7RA12625E"},{"key":"ref5\/cit5d","doi-asserted-by":"publisher","DOI":"10.1039\/D0OB01938K"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1021\/ja054401w"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2009.06.003"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1021\/ja4100595"},{"key":"ref6\/cit6d","doi-asserted-by":"publisher","DOI":"10.1021\/cr400685r"},{"key":"ref6\/cit6e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b04144"},{"key":"ref6\/cit6f","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c08493"},{"key":"ref6\/cit6g","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c01443"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC04397F"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-02698-4"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00886"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1021\/jo9522062"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b02336"},{"key":"ref8\/cit8c","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-02698-4"},{"key":"ref8\/cit8d","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b08715"},{"key":"ref8\/cit8e","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b12053"},{"key":"ref8\/cit8f","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-020-00553-2"},{"key":"ref8\/cit8g","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.0c02899"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b10428"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1021\/ja017440q"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1021\/ja060036c"},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1021\/jm1013693"},{"key":"ref10\/cit10d","doi-asserted-by":"publisher","DOI":"10.1021\/jm3010114"},{"key":"ref10\/cit10e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b00548"},{"key":"ref10\/cit10f","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b03187"},{"key":"ref10\/cit10g","doi-asserted-by":"publisher","DOI":"10.1039\/D4MD00169A"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202301312"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1039\/b311203a"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.7b00608"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.3c00299"},{"key":"ref14\/cit14a","doi-asserted-by":"publisher","DOI":"10.1021\/cr500127b"},{"key":"ref14\/cit14b","doi-asserted-by":"publisher","DOI":"10.1080\/17460441.2016.1195367"},{"key":"ref14\/cit14c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.0c01473"},{"key":"ref14\/cit14d","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2025.117368"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(96)00038-5"},{"key":"ref16\/cit16a","doi-asserted-by":"publisher","DOI":"10.1021\/jm900130m"},{"key":"ref16\/cit16b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.3c00600"},{"key":"ref16\/cit16c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10542"},{"key":"ref16\/cit16d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c02892"},{"key":"ref17\/cit17a","doi-asserted-by":"publisher","DOI":"10.1021\/jm960849j"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.1021\/jo802165k"},{"key":"ref17\/cit17c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709595"},{"key":"ref18\/cit18a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06679"},{"key":"ref18\/cit18b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201609939"},{"key":"ref18\/cit18c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702628"},{"key":"ref18\/cit18d","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00615B"},{"key":"ref18\/cit18e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202113343"},{"key":"ref18\/cit18f","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b11964"},{"key":"ref18\/cit18g","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c03301"},{"key":"ref19\/cit19a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b11964"},{"key":"ref19\/cit19b","doi-asserted-by":"publisher","DOI":"10.1021\/ar200206a"},{"key":"ref19\/cit19c","doi-asserted-by":"publisher","DOI":"10.1126\/science.223.4639.902"},{"key":"ref19\/cit19d","doi-asserted-by":"publisher","DOI":"10.1021\/ic50178a023"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c05764","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c05764","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,22]],"date-time":"2025-10-22T08:35:02Z","timestamp":1761122102000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.5c05764"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,10,8]]},"references-count":71,"journal-issue":{"issue":"42","published-print":{"date-parts":[[2025,10,22]]}},"alternative-id":["10.1021\/jacs.5c05764"],"URL":"https:\/\/doi.org\/10.1021\/jacs.5c05764","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,10,8]]}}}