{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,31]],"date-time":"2026-10-31T12:47:04Z","timestamp":1793450824770,"version":"4.5.0"},"reference-count":54,"publisher":"American Chemical Society (ACS)","issue":"37","license":[{"start":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T00:00:00Z","timestamp":1757030400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T00:00:00Z","timestamp":1757030400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T00:00:00Z","timestamp":1757030400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100021174","name":"Guangdong Provincial Key Laboratory Of Catalysis","doi-asserted-by":"publisher","award":["G03050K003"],"award-info":[{"award-number":["G03050K003"]}],"id":[{"id":"10.13039\/501100021174","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFA1503703"],"award-info":[{"award-number":["2022YFA1503703"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2024B1515020055"],"award-info":[{"award-number":["2024B1515020055"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22231004"],"award-info":[{"award-number":["22231004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22271135"],"award-info":[{"award-number":["22271135"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22301125"],"award-info":[{"award-number":["22301125"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22425011"],"award-info":[{"award-number":["22425011"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Guangdong Innovative Program","award":["2019BT02Y335"],"award-info":[{"award-number":["2019BT02Y335"]}]},{"name":"New Cornerstone Science Foundation"},{"name":"Shenzhen Science and Technology Program","award":["KQTD20210811090112004"],"award-info":[{"award-number":["KQTD20210811090112004"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2025,9,17]]},"DOI":"10.1021\/jacs.5c10649","type":"journal-article","created":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T20:51:18Z","timestamp":1757105478000},"page":"33879-33887","source":"Crossref","is-referenced-by-count":40,"title":["Triplet Carbene Insertion Enables Modular Access to C2-Substituted Bicyclo[1.1.1]pentanes"],"prefix":"10.1021","volume":"147","author":[{"given":"Jin-Teng","family":"Che","sequence":"first","affiliation":[{"name":"Shenzhen Grubbs Institute, Department of Chemistry","place":["Shenzhen, China"]},{"name":"Southern University of Science and Technology","place":["Shenzhen, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong-Bo","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shenzhen Grubbs Institute, Department of Chemistry","place":["Shenzhen, China"]},{"name":"Southern University of Science and Technology","place":["Shenzhen, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-1590-5618","authenticated-orcid":true,"given":"Wei-Yi","family":"Ding","sequence":"additional","affiliation":[{"name":"Shenzhen Grubbs Institute, Department of Chemistry","place":["Shenzhen, China"]},{"name":"Southern University of Science and Technology","place":["Shenzhen, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4262-5626","authenticated-orcid":true,"given":"Shao-Hua","family":"Xiang","sequence":"additional","affiliation":[{"name":"Shenzhen Grubbs Institute, Department of Chemistry","place":["Shenzhen, China"]},{"name":"Southern University of Science and Technology","place":["Shenzhen, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8219-9970","authenticated-orcid":true,"given":"Bin","family":"Tan","sequence":"additional","affiliation":[{"name":"Shenzhen Grubbs Institute, Department of Chemistry","place":["Shenzhen, China"]},{"name":"Southern University of Science and Technology","place":["Shenzhen, China"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,9,5]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.1c01215"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1039\/C8OB02812E"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-024-00623-0"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1021\/jm300094u"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201900589"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.3c00014"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202317333"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.3762\/bjoc.20.78"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1039\/D5CC00816F"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505803"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202106352"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19911240326"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4020(95)00628-L"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c03612"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2108881118"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-021-00786-z"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-023-01342-7"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02616"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-024-01710-x"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c03542"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c01734"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c12163"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10542"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c07190"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1038\/s42004-022-00811-3"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1039\/D4QO01741B"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1039\/D4GC03193H"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c08206"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)98361-9"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)99513-9"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)91317-6"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)96386-0"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)83253-6"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.9b01947"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202205103"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b02026"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c11244"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.3c01664"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202401475"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c03569"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1039\/D4CC04832F"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.4c04519"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-024-01239-9"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00869"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b09036"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202111892"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.202200654"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202300214"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1016\/j.tchem.2022.100024"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c02350"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202000525"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC01165F"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1021\/cr300503r"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-025-01340-7"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c10649","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c10649","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,9,17]],"date-time":"2025-09-17T08:17:58Z","timestamp":1758097078000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.5c10649"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,5]]},"references-count":54,"journal-issue":{"issue":"37","published-print":{"date-parts":[[2025,9,17]]}},"alternative-id":["10.1021\/jacs.5c10649"],"URL":"https:\/\/doi.org\/10.1021\/jacs.5c10649","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,5]]}}}