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Mechanistic studies are\nlacking but in some of these cases, Ni nanoparticles were found to\nbe active (refs 24 and 26)."},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/ol900778m"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2011.03.007"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC01378J"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1246\/cl.150154"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.9b00364"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1021\/om2005673"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.7b00256"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208202"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1021\/om1008499"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c06662"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.4c00299"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1039\/B617136B"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1039\/b801115j"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1021\/ja9026727"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200900290"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt00415d"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702772"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1021\/ic900204c"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/ja402480v"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.8b00594"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202201932"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.7b00497"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c04537"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1039\/c4dt01250j"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b01388"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202000009"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC03128F"},{"key":"ref49\/cit49","unstructured":"An\nelectronic influence\ncan be gleaned from the deviation of the ratio of\n                      meta\n                      :\n                      para\n                      isomers from the pure statistical ratio of\n2:1. The\n                      m\n                      :\n                      p\n                      ratio is higher for\n                      5\n                      (2.4:1) and lower for\n                      6\n                      (1.3:1). Hence\n                      para\n                      C\u2013H activation is favored for an EWG (as in\n                      6\n                      ) and disfavored for an EDG (as in\n                      5\n                      )."},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020816)41:16<3056::AID-ANIE3056>3.0.CO;2-#"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1039\/c2sc20776a"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt50599e"},{"key":"ref53\/cit53","unstructured":"Turbomole\nV7.4, 2019, a development of University\nof Karlsruhe and Forschungszentrum Karlsruhe GmbH,\n1989\u20132007, TURBOMOLE GmbH, since 2007; available from http:\/\/www.turbomole.com."},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.91.146401"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21759"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1039\/P29930000799"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1039\/b515623h"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201200497"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1002\/aic.690480220"},{"key":"ref62\/cit62","unstructured":"Eckert, F.; Klamt, A.\n                      COSMOtherm\n                      , Version C3.0, Release 16.01; COSMOlogic GmbH & Co. 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