{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T06:18:44Z","timestamp":1788589124893,"version":"build-2803163510"},"reference-count":43,"publisher":"American Chemical Society (ACS)","issue":"38","license":[{"start":{"date-parts":[[2025,9,12]],"date-time":"2025-09-12T00:00:00Z","timestamp":1757635200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["CHE-2100345"],"award-info":[{"award-number":["CHE-2100345"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["1R01GM132205"],"award-info":[{"award-number":["1R01GM132205"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2025,9,24]]},"DOI":"10.1021\/jacs.5c12001","type":"journal-article","created":{"date-parts":[[2025,9,12]],"date-time":"2025-09-12T10:47:57Z","timestamp":1757674077000},"page":"35055-35068","source":"Crossref","is-referenced-by-count":6,"title":["Optimizing the Synthesis of Deuterated Isotopomers and Isotopologues of Cyclohexene using Molecular Rotational Resonance Spectroscopy"],"prefix":"10.1021","volume":"147","author":[{"given":"Justin T.","family":"Weatherford-Pratt","sequence":"first","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jacob A.","family":"Smith","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin S.","family":"Holdren","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haley N.","family":"Scolati","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0497-6660","authenticated-orcid":true,"given":"Reilly E.","family":"Sonstrom","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Megan N.","family":"Ericson","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sarah E.","family":"Brewster","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-1410-5980","authenticated-orcid":true,"given":"Alvin Q.","family":"Meng","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0939-3309","authenticated-orcid":true,"given":"Diane A.","family":"Dickie","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Brooks H.","family":"Pate","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0939-6980","authenticated-orcid":true,"given":"W. Dean","family":"Harman","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Charlottesville, United States"]},{"name":"University of Virginia","place":["Charlottesville, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,9,12]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9530376"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/cr50004a004"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1855"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1002\/bmb.2006.49403402066"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biochem.7b00765"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1186\/s40734-017-0051-5"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1200\/JCO.21.00163"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.2147\/DDDT.S379496"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00795"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1002\/jlcr.3743"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1038\/s41573-023-00703-8"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1002\/bies.950070506"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1021\/acs.oprd.2c00318"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00884"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b00924"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-020-2268-y"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218961"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.3c00053"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/acs.oprd.3c00028"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202100635"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202207275"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1002\/chir.23596"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1021\/ja710260v"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b00490"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.9b00279"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.202100103"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05118"},{"key":"ref28\/cit28","volume-title":"Chiral Analysis 2nd ed. 671 Advances in Spectroscopy, Chromatography, and Emerging Methods","author":"Pate B. H.","year":"2018"},{"key":"ref29\/cit29","doi-asserted-by":"crossref","unstructured":"Pate, B. H.; West, C.; Xu, Y.; Thomas, J.; Patterson, D.; Caminati, W.; Evangelisti, L. A chiral tagging strategy for determining absolute configuration and enantiomeric excess by molecule rotational spectroscopy. In  International Symposium on Molecular Spectroscopy, 2017, https:\/\/dx.doi.org\/10.15278\/isms.2017.RG03.","DOI":"10.15278\/isms.2017.RG03"},{"key":"ref30\/cit30","author":"Mayer K. J.","year":"2019","journal-title":"International Symposium on Molecular Spectroscopy"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(01)01121-6"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/ja066128j"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800957"},{"key":"ref34\/cit34","volume-title":"Microwave Molecular Spectra","author":"Gordy W.","year":"1984","edition":"3"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1119\/1.1933338"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1139\/v67-420"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/ja01596a015"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1016\/0923-1137(94)90096-5"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202010835"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.0c00151"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1021\/ja039824h"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-52127-6"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1002\/ansa.202300021"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c12001","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c12001","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,9,24]],"date-time":"2025-09-24T08:14:27Z","timestamp":1758701667000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.5c12001"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,12]]},"references-count":43,"journal-issue":{"issue":"38","published-print":{"date-parts":[[2025,9,24]]}},"alternative-id":["10.1021\/jacs.5c12001"],"URL":"https:\/\/doi.org\/10.1021\/jacs.5c12001","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,12]]}}}