{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T22:16:58Z","timestamp":1792793818114,"version":"4.5.0"},"reference-count":73,"publisher":"American Chemical Society (ACS)","issue":"48","license":[{"start":{"date-parts":[[2025,11,18]],"date-time":"2025-11-18T00:00:00Z","timestamp":1763424000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["2453332"],"award-info":[{"award-number":["2453332"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000928","name":"Welch Foundation","doi-asserted-by":"publisher","award":["A-1907"],"award-info":[{"award-number":["A-1907"]}],"id":[{"id":"10.13039\/100000928","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["R35GM137797"],"award-info":[{"award-number":["R35GM137797"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2025,12,3]]},"DOI":"10.1021\/jacs.5c14648","type":"journal-article","created":{"date-parts":[[2025,11,18]],"date-time":"2025-11-18T19:49:24Z","timestamp":1763495364000},"page":"44336-44345","source":"Crossref","is-referenced-by-count":7,"title":["Multisite Proton-Coupled Electron Transfer Enables Iodanyl Radical Catalysis"],"prefix":"10.1021","volume":"147","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6283-9344","authenticated-orcid":true,"given":"Phong","family":"Thai","sequence":"first","affiliation":[{"name":"Department of Chemistry","place":["College Station, United States"]},{"name":"Texas A&M University","place":["College Station, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Brandon L.","family":"Frey","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["College Station, United States"]},{"name":"Texas A&M University","place":["College Station, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Remy F.","family":"Lalisse","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry","place":["Los Angeles, United States"]},{"name":"University of California","place":["Los Angeles, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lauv","family":"Patel","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["College Station, United States"]},{"name":"Texas A&M University","place":["College Station, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2876-7612","authenticated-orcid":true,"given":"Poulami","family":"Mukherjee","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry","place":["Los Angeles, United States"]},{"name":"University of California","place":["Los Angeles, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhihui","family":"Song","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry","place":["College Park, United States"]},{"name":"University of Maryland","place":["College Park, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4418-916X","authenticated-orcid":true,"given":"Raanan","family":"Carmieli","sequence":"additional","affiliation":[{"name":"Department of Chemical Research Support","place":["Rehovot, Israel"]},{"name":"Weizmann Institute of Science","place":["Rehovot, Israel"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8151-7519","authenticated-orcid":true,"given":"Osvaldo","family":"Gutierrez","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry","place":["Los Angeles, United States"]},{"name":"University of California","place":["Los Angeles, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3717-2001","authenticated-orcid":true,"given":"David C.","family":"Powers","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["College Station, United States"]},{"name":"Texas A&M University","place":["College Station, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,11,18]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00303"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c01493"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00516G"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00206b"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c12816"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c05498"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00649G"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-019-0146-7"},{"key":"ref9\/cit9","doi-asserted-by":"crossref","DOI":"10.1002\/9781118341155","volume-title":"Hypervalent Iodine Chemistry: Preparation, Structure, and Synthetic Applications of Polyvalent Iodine Compounds","author":"Zhdankin V. V.","year":"2013"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00572"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1016\/j.trechm.2020.07.008"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1126\/science.aau5105"},{"key":"ref13\/cit13","volume-title":"Electron Transfer and Radical Processes in Transition-Metal Chemistry","author":"Astruc D.","year":"1995"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1038\/nature08634"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/cr020406p"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.04.007"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/cr00029a003"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c10092"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC03819A"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/9783527829569.ch12"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00206J"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00547"},{"key":"ref23\/cit23","doi-asserted-by":"crossref","DOI":"10.1002\/9781118909911","volume-title":"Iodine Chemistry and Applications","author":"Kaiho T.","year":"2014"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201914226"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202101002"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.202000501"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c02309"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202300477"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202205277"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507180"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b02979"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904379"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1055\/s-0037-1610373"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201900540"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60464k"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2873"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201804159"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC00549F"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.06.006"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b13918"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1021\/ja00505a038"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201304359"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-025-01749-4"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c05077"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201503479"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c01385"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.7b00148"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c07330"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202400560"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c05562"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17303-4"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1021\/ja507918c"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00521"},{"key":"ref54\/cit54","volume-title":"Electrochemical Methods: Fundamentals and Applications","author":"Faulkner L. R.","year":"2002"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1149\/1945-7111\/abb83c"},{"key":"ref56\/cit56","volume-title":"Handbook of Organic Chemistry","author":"Dean J. A.","year":"1987"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1021\/jo00165a018"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1039\/c1cp22032b"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1021\/ct100641a"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.3390\/10010217"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10964"},{"key":"ref62\/cit62","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202107898"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202009175"},{"key":"ref64\/cit64","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC02773G"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC08253F"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.7b01425"},{"key":"ref67\/cit67","doi-asserted-by":"publisher","DOI":"10.1039\/C7GC03130K"},{"key":"ref68\/cit68","doi-asserted-by":"publisher","DOI":"10.1021\/ja111652v"},{"key":"ref69\/cit69","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201102984"},{"key":"ref70\/cit70","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2010.11.015"},{"key":"ref71\/cit71","doi-asserted-by":"publisher","DOI":"10.1055\/a-2029-0617"},{"key":"ref73\/cit73","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202100960"},{"key":"ref74\/cit74","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201600191"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c14648","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c14648","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,3]],"date-time":"2025-12-03T09:13:31Z","timestamp":1764753211000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.5c14648"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11,18]]},"references-count":73,"journal-issue":{"issue":"48","published-print":{"date-parts":[[2025,12,3]]}},"alternative-id":["10.1021\/jacs.5c14648"],"URL":"https:\/\/doi.org\/10.1021\/jacs.5c14648","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,11,18]]}}}