{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,25]],"date-time":"2026-07-25T11:22:10Z","timestamp":1784978530996,"version":"3.55.0"},"reference-count":89,"publisher":"American Chemical Society (ACS)","issue":"45","license":[{"start":{"date-parts":[[2025,10,30]],"date-time":"2025-10-30T00:00:00Z","timestamp":1761782400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004189","name":"Max-Planck-Gesellschaft","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004189","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007215","name":"Verband der Chemischen Industrie","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100007215","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100005156","name":"Alexander von Humboldt-Stiftung","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100005156","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Max-Planck-Center on FUNdamentals of Heterogeneous CATalysis (FUNCAT)"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2025,11,12]]},"DOI":"10.1021\/jacs.5c16274","type":"journal-article","created":{"date-parts":[[2025,10,30]],"date-time":"2025-10-30T16:37:51Z","timestamp":1761842271000},"page":"42088-42099","source":"Crossref","is-referenced-by-count":2,"title":["A Heterogenized Molecular Catalyst for the Gas-Phase Cyclotrimerization of Acetylene to Benzene"],"prefix":"10.1021","volume":"147","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-5513-3035","authenticated-orcid":true,"given":"Jonathan M.","family":"Mau\u00df","sequence":"first","affiliation":[{"name":"Department of Heterogeneous Catalysis, Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sebastian","family":"Leiting","sequence":"additional","affiliation":[{"name":"Department of Heterogeneous Catalysis, Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6709-5057","authenticated-orcid":true,"given":"Christophe","family":"Far\u00e8s","sequence":"additional","affiliation":[{"name":"Department of Heterogeneous Catalysis, Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-5803-691X","authenticated-orcid":true,"given":"Anna G.","family":"Scott","sequence":"additional","affiliation":[{"name":"Department of Inorganic Spectroscopy, Max-Planck-Institut f\u00fcr Chemische Energiekonversion, Stiftstra\u00dfe 34-36, 45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergey","family":"Peredkov","sequence":"additional","affiliation":[{"name":"Department of Inorganic Spectroscopy, Max-Planck-Institut f\u00fcr Chemische Energiekonversion, Stiftstra\u00dfe 34-36, 45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5196-3400","authenticated-orcid":true,"given":"Serena","family":"DeBeer","sequence":"additional","affiliation":[{"name":"Department of Inorganic Spectroscopy, Max-Planck-Institut f\u00fcr Chemische Energiekonversion, Stiftstra\u00dfe 34-36, 45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3006-1333","authenticated-orcid":true,"given":"Claudia","family":"Weidenthaler","sequence":"additional","affiliation":[{"name":"Department of Heterogeneous Catalysis, Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3765-9848","authenticated-orcid":true,"given":"Ferdi","family":"Sch\u00fcth","sequence":"additional","affiliation":[{"name":"Department of Heterogeneous Catalysis, Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 M\u00fclheim an der Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,10,30]]},"reference":[{"key":"ref1\/cit1a","unstructured":"aMarket volume of benzene worldwide from 2015 to 2022, with a forecast\nfor 2023 to 2030. Statista, Inc., 2023. https:\/\/www.statista.com\/statistics\/1245172\/benzene-market-volume-worldwide\/(accessed 2025-06-27)."},{"key":"ref1\/cit1b","unstructured":"bBenzene Market Report by Derivative (Ethylbenzene,\nCumene, Cyclohexane, Nitrobenzene, Linear Alkylbenzene, Maleic Anhydride,\nand Others), Manufacturing Process (Pyrolysis Steam Cracking of Naphtha,\nCatalytic Reforming of Naphtha, Toluene Hydrodealkylation, Toluene\nDisproportionation, From Biomass), Application (Plastics, Resins,\nSynthetic Fibers, Rubber Lubricants, and Others), and Region 2025\u20132033. IMARC Group, 2024. https:\/\/www.imarcgroup.com\/benzene-technical-material-market-report (accessed 2025-06-27)."},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.3390\/en14134061"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1002\/apj.18"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1002\/14356007.a03_475"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00087"},{"key":"ref6\/cit6","unstructured":"Benzene Market Size, Share & Trends Analysis Report Derivative\nBy End-use, By Production Process (Catalytic Reforming), By Region,\nAnd Segment Forecasts, 2022\u20132030. Grand View Research, Inc., 2022. https:\/\/www.grandviewresearch.com\/industry-analysis\/benzene-market-report (accessed 2025-06-27)."},{"key":"ref7\/cit7","unstructured":"Richardson, J. Benzene, the need for a new global Industrial Revolution and the big challenges that lie ahead. Independent Commodity Intelligence Service (ICIS), 2021. https:\/\/www.icis.com\/asian-chemical-connections\/2021\/11\/benzene-the-need-for-a-new-global-industrial-revolution-and-the-big-challenges-that-lie-ahead\/ (accessed 2025-06-27)."},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-24780-8"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1134\/S0965544121010023"},{"key":"ref8\/cit8c","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.3c06996"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1016\/j.spc.2022.04.019"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.3c01202"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2016.02.028"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b02922"},{"key":"ref11\/cit11c","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2023.114044"},{"key":"ref11\/cit11d","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2018.03.011"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/cr400357r"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202401593"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202401794"},{"key":"ref13\/cit13c","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c02226"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202400801"},{"key":"ref15\/cit15a","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2023.122643"},{"key":"ref15\/cit15b","doi-asserted-by":"publisher","DOI":"10.1016\/j.comptc.2022.113682"},{"key":"ref15\/cit15c","doi-asserted-by":"publisher","DOI":"10.1002\/14356007.a01_097.pub4"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1021\/ja983098e"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19566010106"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.196907271"},{"key":"ref18\/cit18a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00013a094"},{"key":"ref18\/cit18b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.0c00172"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/ja00108a020"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/ja00228a042"},{"key":"ref21\/cit21a","doi-asserted-by":"publisher","DOI":"10.1021\/ja9922476"},{"key":"ref21\/cit21b","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(83)90359-X"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/ja00043a037"},{"key":"ref23\/cit23a","doi-asserted-by":"publisher","DOI":"10.1021\/ja00055a054"},{"key":"ref23\/cit23b","doi-asserted-by":"publisher","DOI":"10.1021\/cs400198f"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1039\/d4sc01053a"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1021\/jp300514f"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(93)80126-F"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.1c09015"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/ja035137e"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.9b04962"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b10887"},{"key":"ref31\/cit31a","doi-asserted-by":"publisher","DOI":"10.1039\/ft9959103975"},{"key":"ref31\/cit31b","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9517(74)90068-2"},{"key":"ref31\/cit31c","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200700721"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1021\/j100316a051"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/j100403a030"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(03)00221-7"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.19690520608"},{"key":"ref36\/cit36","doi-asserted-by":"publisher","DOI":"10.1134\/S0036023611110106"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1016\/0022-5088(65)90127-X"},{"key":"ref38\/cit38","doi-asserted-by":"publisher","DOI":"10.1107\/S1600577524002200"},{"key":"ref39\/cit39","unstructured":"Trotus, I.T. Catalytic Conversion of Acetylen to Butadien and Butenes. PhD Thesis, Ruhr-Universit\u00e4t: Bochum, 2016."},{"key":"ref40\/cit40a","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC00853K"},{"key":"ref40\/cit40b","doi-asserted-by":"publisher","DOI":"10.1039\/d2cy01424f"},{"key":"ref40\/cit40c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.2c03430"},{"key":"ref141\/cit141","doi-asserted-by":"publisher","DOI":"10.1039\/D5MR00074B"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1093\/chromsci\/5.2.68"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1134\/S0020168522070093"},{"key":"ref43\/cit43a","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(87)85044-7"},{"key":"ref43\/cit43b","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(89)85030-8"},{"key":"ref43\/cit43c","doi-asserted-by":"publisher","DOI":"10.1016\/0304-5102(87)85021-6"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.3390\/ma11020242"},{"key":"ref45\/cit45a","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.5b00021"},{"key":"ref45\/cit45b","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2009.04.049"},{"key":"ref45\/cit45c","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2006.04.013"},{"key":"ref46\/cit46a","doi-asserted-by":"publisher","DOI":"10.1080\/00268948208072151"},{"key":"ref46\/cit46b","doi-asserted-by":"publisher","DOI":"10.1039\/C9RA01205B"},{"key":"ref47\/cit47a","doi-asserted-by":"publisher","DOI":"10.1016\/0032-3861(82)90381-0"},{"key":"ref47\/cit47b","doi-asserted-by":"publisher","DOI":"10.1038\/299608a0"},{"key":"ref47\/cit47c","doi-asserted-by":"publisher","DOI":"10.1016\/0379-6779(80)90008-9"},{"key":"ref48\/cit48","volume-title":"Handbuch der Pr\u00e4parativen Anorganischen Chemie","author":"Baudler M.","year":"1981"},{"key":"ref49\/cit49a","doi-asserted-by":"publisher","DOI":"10.1021\/jp020457q"},{"key":"ref49\/cit49b","doi-asserted-by":"publisher","DOI":"10.1039\/c3cp44016h"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1016\/j.ssnmr.2005.09.003"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1021\/jp0521499"},{"key":"ref52\/cit52a","doi-asserted-by":"publisher","DOI":"10.1039\/b309570n"},{"key":"ref52\/cit52b","doi-asserted-by":"publisher","DOI":"10.1006\/snmr.2002.0063"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2008.08.095"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c00663"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.4144\/rpsj.52.113"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1002\/pi.3139"},{"key":"ref57\/cit57","volume-title":"Lehrbuch der Anorganischen Chemie","author":"Wiberg N.","year":"2007"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1021\/la00075a004"},{"key":"ref59\/cit59a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b02872"},{"key":"ref59\/cit59b","doi-asserted-by":"publisher","DOI":"10.1016\/j.heliyon.2018.e00571"},{"key":"ref59\/cit59c","doi-asserted-by":"publisher","DOI":"10.17374\/targets.2024.27.282"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c16274","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.5c16274","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,12]],"date-time":"2025-11-12T09:43:42Z","timestamp":1762940622000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.5c16274"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,10,30]]},"references-count":89,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2025,11,12]]}},"alternative-id":["10.1021\/jacs.5c16274"],"URL":"https:\/\/doi.org\/10.1021\/jacs.5c16274","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,10,30]]}}}