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Furthermore, we describe the surprising beneficial effect of LiBr on the most challenging of the radical\u2013radical cyclization cascades. An alternative fragmentation\u2013radical cyclization sequence of related substrates allows access to bicyclic uracil derivatives. The radical\u2013radical cyclization process constitutes the first example of a radical cascade involving ET reduction of the amide carbonyl. Products of the cascade can be readily manipulated to give highly unusual and medicinally relevant bi- and tricyclic barbiturates.<\/jats:p>","DOI":"10.1021\/jacs.6b04086","type":"journal-article","created":{"date-parts":[[2016,5,31]],"date-time":"2016-05-31T14:13:43Z","timestamp":1464704023000},"page":"7770-7775","source":"Crossref","is-referenced-by-count":76,"title":["Radical\u2013Radical\nCyclization Cascades of Barbiturates\nTriggered by Electron-Transfer Reduction of Amide-Type Carbonyls"],"prefix":"10.1021","volume":"138","author":[{"given":"Huan-Ming","family":"Huang","sequence":"first","affiliation":[{"name":"University of Manchester , Oxford Road , , , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David J.","family":"Procter","sequence":"additional","affiliation":[{"name":"University of Manchester , Oxford Road , , , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2016,5,31]]},"reference":[{"key":"2026090114225752600_cit1a","doi-asserted-by":"publisher","first-page":"3997","DOI":"10.1039\/c1ob05212h","volume":"9","author":"Anderson","year":"2011","journal-title":"Org. 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