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However, examples of supramolecular polymers at the liquid\u2013liquid interface are mostly unexplored. Here, we describe the supramolecular polymerization of triarylamine molecules and their light-triggered organization at a chloroform\u2013water interface. The resulting interfacial nematic layer of these 1D supramolecular polymers is further used as a template for the precise alignment of spherical gold nanoparticles coming from the water phase. These hybrid thin films are spontaneously formed in a single process, without chemical prefunctionalization of the metallic nanoparticles, and their ordering is improved by centrifugation. The resulting polymer chains and strings of nanoparticles can be co-aligned with high anisotropy over very large distances. By using a combination of experimental and theoretical investigations, we decipher the full sequence of this oriented self-assembly process. In such a highly anisotropic configuration, electron energy loss spectroscopy reveals that the self-assembled nanoparticles behave as plasmonic waveguides.<\/jats:p>","DOI":"10.1021\/jacs.6b11179","type":"journal-article","created":{"date-parts":[[2017,1,18]],"date-time":"2017-01-18T19:06:37Z","timestamp":1484766397000},"page":"2345-2350","source":"Crossref","is-referenced-by-count":79,"title":["Anisotropic\nSelf-Assembly of Supramolecular Polymers\nand Plasmonic Nanoparticles at the Liquid\u2013Liquid Interface"],"prefix":"10.1021","volume":"139","author":[{"suffix":"IV","given":"Joseph J.","family":"Armao","sequence":"first","affiliation":[{"name":"University of Strasbourg\u2212CNRS , , 23 rue du Loess , BP 84047, ,","place":["Strasbourg, France, 67034 Cedex 2"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Irina","family":"Nyrkova","sequence":"additional","affiliation":[{"name":"Institut Charles Sadron\u2212CNRS , 23 rue du Loess , BP 84047, ,","place":["Strasbourg, France, 67034 Cedex 2"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gad","family":"Fuks","sequence":"additional","affiliation":[{"name":"University of Strasbourg\u2212CNRS , , 23 rue du Loess , BP 84047, ,","place":["Strasbourg, France, 67034 Cedex 2"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Artem","family":"Osypenko","sequence":"additional","affiliation":[{"name":"University of Strasbourg\u2212CNRS , , 23 rue du Loess , BP 84047, ,","place":["Strasbourg, France, 67034 Cedex 2"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mounir","family":"Maaloum","sequence":"additional","affiliation":[{"name":"University of Strasbourg\u2212CNRS , , 23 rue du Loess , BP 84047, ,","place":["Strasbourg, France, 67034 Cedex 2"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Emilie","family":"Moulin","sequence":"additional","affiliation":[{"name":"University of Strasbourg\u2212CNRS , , 23 rue du Loess , BP 84047, ,","place":["Strasbourg, France, 67034 Cedex 2"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2071-9093","authenticated-orcid":true,"given":"Raul","family":"Arenal","sequence":"additional","affiliation":[{"name":"Instituto de Nanociencia de Aragon (INA) , , U. 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