{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T18:08:05Z","timestamp":1788804485683,"version":"build-2803163510"},"reference-count":50,"publisher":"American Chemical Society (ACS)","issue":"22","license":[{"start":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T00:00:00Z","timestamp":1779840000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T00:00:00Z","timestamp":1779840000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T00:00:00Z","timestamp":1779840000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100006407","name":"Natural Science Foundation of Henan Province","doi-asserted-by":"publisher","award":["22571030"],"award-info":[{"award-number":["22571030"]}],"id":[{"id":"10.13039\/501100006407","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Basic Research Program of China (973 Program)","doi-asserted-by":"crossref","award":["2022YFA1503302"],"award-info":[{"award-number":["2022YFA1503302"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,6,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The conversion of nitrogen oxides into nitrogen-containing chemicals is critical to the global nitrogen cycle, but utilizing resources derived from NOx gas presents significant challenges. Herein we report a biomimetic strategy to incorporate a catalytic partner into coordination capsules for efficient N\u2013O bond cleavage and \u03b1-amino acid synthesis. This strategy includes the generation of NO adducts via glutathione-mediated NO binding and enzymatic NO activation via the formation of substrate-involved intermediates. The metal centers interact with the NO adducts, anodically shifting the redox potential up to \u22120.34 VNHE. Under the optimized conditions, the enzymatic manifold facilitates an ammonia conversion rate of 182.16 \u03bcmol\u00b7h\u20131\u00b7cm\u20131 and a Faradaic efficiency (FE) of 87.1% with the lowest overpotential of \u22120.3 VRHE, surpassing the performance of most reported electrocatalysts. When both the \u03b1-keto acid and the NO adduct were incorporated within the capsules, efficient electrocatalytic conversion of NO into amino acids was achieved with a high FE of 55.2%, providing an attractive way to elucidate enzyme-like activation dynamics.<\/jats:p>","DOI":"10.1021\/jacs.6c01915","type":"journal-article","created":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T10:41:15Z","timestamp":1779878475000},"page":"22407-22412","source":"Crossref","is-referenced-by-count":0,"title":["Glutathione-Mediated\nBiomimetic NO Activation with\nCoordination Capsules for NH3 and \u03b1-Amino\nAcid Electrosynthesis"],"prefix":"10.1021","volume":"148","author":[{"given":"Yao","family":"Wang","sequence":"first","affiliation":[{"name":"Dalian University of Technology , , ,","place":["Dalian, China, 116024"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Lv","sequence":"additional","affiliation":[{"name":"Dalian University of Technology , , ,","place":["Dalian, China, 116024"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6877-3577","authenticated-orcid":true,"given":"Xu","family":"Jing","sequence":"additional","affiliation":[{"name":"Dalian University of Technology , , ,","place":["Dalian, China, 116024"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinfeng","family":"Wang","sequence":"additional","affiliation":[{"name":"Dalian University of Technology , , ,","place":["Dalian, China, 116024"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1638-6633","authenticated-orcid":true,"given":"Chunying","family":"Duan","sequence":"additional","affiliation":[{"name":"Dalian University of Technology , , ,","place":["Dalian, China, 116024"]},{"name":"Nanjing University , , ,","place":["Nanjing, China, 210093"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,5,27]]},"reference":[{"key":"2026090713183907400_cit1","doi-asserted-by":"publisher","first-page":"eaar6611","DOI":"10.1126\/science.aar6611","article-title":"Beyond fossil fuel-driven nitrogen transformations","volume":"360","author":"Chen","year":"2018","journal-title":"Science"},{"key":"2026090713183907400_cit2","doi-asserted-by":"publisher","first-page":"1125","DOI":"10.1038\/s41929-023-01060-w","article-title":"The why and how of NOx electroreduction\nto ammonia","volume":"6","author":"John","year":"2023","journal-title":"Nat. Catal."},{"key":"2026090713183907400_cit3","doi-asserted-by":"publisher","first-page":"214783","DOI":"10.1016\/j.ccr.2022.214783","article-title":"Recent advances\nin catalytic nitrogen fixation using\ntransition metal\u2013dinitrogen complexes under mild reaction conditions","volume":"472","author":"Tanabe","year":"2022","journal-title":"Coord. Chem. Rev."},{"key":"2026090713183907400_cit4","doi-asserted-by":"publisher","first-page":"5582","DOI":"10.1021\/acs.chemrev.9b00638","article-title":"Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined\nMolecular Coordination Complexes","volume":"120","author":"Chalkley","year":"2020","journal-title":"Chem. Rev."},{"key":"2026090713183907400_cit5","doi-asserted-by":"publisher","first-page":"9027","DOI":"10.1039\/D4EE03156C","article-title":"Electrocatalytic nitrogen cycle:\nmechanism, materials, and momentum","volume":"17","author":"Li","year":"2024","journal-title":"Energy Environ.\nSci."},{"key":"2026090713183907400_cit6","doi-asserted-by":"publisher","first-page":"2963","DOI":"10.1016\/j.chempr.2024.07.006","article-title":"Electrocatalytic reduction\nof nitrogen oxide species to ammonia","volume":"10","author":"Liu","year":"2024","journal-title":"Chem"},{"key":"2026090713183907400_cit7","doi-asserted-by":"publisher","first-page":"2312645","DOI":"10.1002\/adma.202312645","article-title":"Selective Electrocatalytic\nConversion of Nitric Oxide to High Value-Added Chemicals","volume":"36","author":"Wang","year":"2024","journal-title":"Adv. Mater."},{"key":"2026090713183907400_cit8","doi-asserted-by":"publisher","first-page":"10044","DOI":"10.1021\/jacs.4c00898","article-title":"Carbon Support\nEnhanced Mass Transfer and Metal\u2013Support Interaction Promoted\nActivation for Low-Concentrated Nitric Oxide Electroreduction to Ammonia","volume":"146","author":"Meng","year":"2024","journal-title":"J. Am. Chem. Soc."},{"issue":"11","key":"2026090713183907400_cit9","doi-asserted-by":"publisher","first-page":"2309470","DOI":"10.1002\/adma.202309470","article-title":"Cu@Co with Dilatation Strain for\nHigh-Performance Electrocatalytic Reduction of Low-Concentration Nitric\nOxide","volume":"36","author":"Wu","year":"2024","journal-title":"Adv. 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Mater."},{"key":"2026090713183907400_cit27","doi-asserted-by":"publisher","first-page":"19951","DOI":"10.1021\/jacs.4c03367","article-title":"Enzymatic Activation\nand Continuous Electrochemical\nProduction of Methane from Dilute CO2 Sources with a Self-Healing\nCapsule","volume":"146","author":"Wang","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"2026090713183907400_cit28","doi-asserted-by":"publisher","first-page":"1817","DOI":"10.1021\/ic061625m","article-title":"Cobaloximes\nas Functional Models\nfor Hydrogenases. 2. Proton Electroreduction Catalyzed by Difluoroborylbis(dimethylglyoximato)cobalt(II)\nComplexes in Organic Media","volume":"46","author":"Baffert","year":"2007","journal-title":"Inorg. Chem."},{"key":"2026090713183907400_cit29","doi-asserted-by":"publisher","first-page":"10958","DOI":"10.1073\/pnas.162095599","article-title":"The reduction potential\nof nitric oxide (NO) and its importance to NO biochemistry","volume":"99","author":"Bartberger","year":"2002","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2026090713183907400_cit30","doi-asserted-by":"publisher","first-page":"2134","DOI":"10.1021\/jacs.9b11273","article-title":"Host\u2013Guest-Induced\nElectron Transfer Triggers\nRadical-Cation Catalysis","volume":"142","author":"Spicer","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"2026090713183907400_cit31","doi-asserted-by":"publisher","first-page":"e202319135","DOI":"10.1002\/anie.202319135","article-title":"Identification\nof Cu(111) as Superior\nActive Sites for Electrocatalytic NO Reduction to NH3 with\nHigh Single-Pass Conversion Efficiency","volume":"63","author":"Xiao","year":"2024","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026090713183907400_cit32","doi-asserted-by":"publisher","first-page":"41355","DOI":"10.1021\/jacs.5c10404","article-title":"Molecularly Engineered Co\u2013Phthalocyanine Covalent\nOrganic Frameworks for Efficient Nitric Oxide-to-Ammonia Electroreduction","volume":"147","author":"Han","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026090713183907400_cit33","doi-asserted-by":"publisher","first-page":"3823","DOI":"10.1021\/jacsau.4c00475","article-title":"Two-Dimensional\nMOF Constructed by a Binuclear-Copper Motif for High-Performance Electrocatalytic\nNO Reduction to NH3","volume":"4","author":"Luo","year":"2024","journal-title":"JACS Au"},{"key":"2026090713183907400_cit34","doi-asserted-by":"publisher","first-page":"7243","DOI":"10.1038\/s41467-024-51256-2","article-title":"Integrated electrocatalytic synthesis of ammonium nitrate\nfrom dilute NO gas on metal organic frameworks-modified gas diffusion\nelectrodes","volume":"15","author":"Pan","year":"2024","journal-title":"Nat. Commun."},{"key":"2026090713183907400_cit35","doi-asserted-by":"publisher","first-page":"2410","DOI":"10.1021\/acs.accounts.7b00327","article-title":"Electron Bifurcation:\nThermodynamics\nand Kinetics of Two-Electron Brokering in Biological Redox Chemistry","volume":"50","author":"Zhang","year":"2017","journal-title":"Acc. Chem. Res."},{"key":"2026090713183907400_cit36","doi-asserted-by":"publisher","first-page":"e19123","DOI":"10.1002\/anie.202519123","article-title":"NADH Mimic-Decorated Coordination Capsules for Biomimetic\nCapture of NO and Electrocatalytic Reduction to NH3","volume":"65","author":"Wang","year":"2026","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090713183907400_cit37","doi-asserted-by":"publisher","first-page":"e202504499","DOI":"10.1002\/anie.202504499","article-title":"Mechanistic Insights\ninto the CO2-Assisted NO Electrochemical Deoxygenation and Hydrogenation","volume":"64","author":"Li","year":"2025","journal-title":"Angew. Chem., Int. 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Chem., Int. Ed."},{"key":"2026090713183907400_cit41","doi-asserted-by":"publisher","first-page":"12707","DOI":"10.1021\/jacs.9b05351","article-title":"Metal\u2013Organic Capsules with NADH Mimics as Switchable\nSelectivity Regulators for Photocatalytic Transfer Hydrogenation","volume":"141","author":"Wei","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"2026090713183907400_cit42","doi-asserted-by":"publisher","first-page":"15812","DOI":"10.1021\/jacs.2c06688","article-title":"Chloride-Mediated Alkene Activation\nDrives Enantioselective Thiourea and Hydrogen Chloride Co-Catalyzed\nPrins Cyclizations","volume":"144","author":"Kutateladze","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026090713183907400_cit43","doi-asserted-by":"publisher","first-page":"29272","DOI":"10.1021\/jacs.4c08547","article-title":"Reserving\nElectrons in Cofactor Decorated Coordination\nCapsules for Biomimetic Electrosynthesis of \u03b1-Hydroxy\/amino\nEsters","volume":"146","author":"Wang","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"2026090713183907400_cit44","doi-asserted-by":"publisher","first-page":"85","DOI":"10.1126\/science.1138748","article-title":"Acid Catalysis\nin Basic Solution:\nA Supramolecular Host Promotes Orthoformate Hydrolysis","volume":"316","author":"Pluth","year":"2007","journal-title":"Science"},{"key":"2026090713183907400_cit45","doi-asserted-by":"publisher","first-page":"92","DOI":"10.1038\/s41557-024-01650-6","article-title":"Hydrophobic\nassembly of molecular catalysts at the gas\u2013liquid\u2013solid\ninterface drives highly selective CO2 electromethanation","volume":"17","author":"McKee","year":"2025","journal-title":"Nat. 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Ed."},{"key":"2026090713183907400_cit49","doi-asserted-by":"publisher","first-page":"1","DOI":"10.31635\/ccschem.026.202507128","article-title":"Inducing and Fixing\nCoordination Chirality of Capsules for Biomimetic Asymmetric Catalysis","author":"Yang","year":"2026","journal-title":"CCS Chem."},{"key":"2026090713183907400_cit50","doi-asserted-by":"publisher","first-page":"8871","DOI":"10.1021\/jacs.5c00583","article-title":"Tailoring Activation Intermediates\nof CO2 Initiates C\u2013N Coupling for Highly Selective\nUrea Electrosynthesis","volume":"147","author":"Zhao","year":"2025","journal-title":"J. Am. Chem. 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