{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T02:38:07Z","timestamp":1792550287090,"version":"4.5.0"},"reference-count":66,"publisher":"American Chemical Society (ACS)","issue":"11","license":[{"start":{"date-parts":[[2026,3,12]],"date-time":"2026-03-12T00:00:00Z","timestamp":1773273600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,3,12]],"date-time":"2026-03-12T00:00:00Z","timestamp":1773273600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,3,12]],"date-time":"2026-03-12T00:00:00Z","timestamp":1773273600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2021YFA1200302"],"award-info":[{"award-number":["2021YFA1200302"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2021YFA1500403"],"award-info":[{"award-number":["2021YFA1500403"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFA1205400"],"award-info":[{"award-number":["2022YFA1205400"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010428","name":"Innovation and Technology Fund","doi-asserted-by":"publisher","award":["9446006"],"award-info":[{"award-number":["9446006"]}],"id":[{"id":"10.13039\/501100010428","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007567","name":"City University of Hong Kong","doi-asserted-by":"publisher","award":["9020003"],"award-info":[{"award-number":["9020003"]}],"id":[{"id":"10.13039\/100007567","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22173024"],"award-info":[{"award-number":["22173024"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52372079"],"award-info":[{"award-number":["52372079"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92056204"],"award-info":[{"award-number":["92056204"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92356304"],"award-info":[{"award-number":["92356304"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002367","name":"Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["XDB36000000"],"award-info":[{"award-number":["XDB36000000"]}],"id":[{"id":"10.13039\/501100002367","id-type":"DOI","asserted-by":"publisher"}]},{"name":"JC STEM lab of Advanced CO2 Upcycling","award":["9228005"],"award-info":[{"award-number":["9228005"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2026,3,25]]},"DOI":"10.1021\/jacs.6c01959","type":"journal-article","created":{"date-parts":[[2026,3,12]],"date-time":"2026-03-12T14:09:47Z","timestamp":1773324587000},"page":"12307-12320","source":"Crossref","is-referenced-by-count":4,"title":["Sulfonic Acid Group Docking Synthesis of Platinum Clusters in MOFs Cavity Enables Low-Temperature Stable Selective CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Methanol"],"prefix":"10.1021","volume":"148","author":[{"given":"Shengxian","family":"Shao","sequence":"first","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"School of Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"University of Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaolong","family":"Liu","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Theoretical and Computational Nanoscience, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junqi","family":"Pei","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"School of Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"University of Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3129-8113","authenticated-orcid":true,"given":"Ting","family":"Tan","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Theoretical and Computational Nanoscience, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"School of Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"University of Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1104-6146","authenticated-orcid":true,"given":"Xiao","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering","place":["Beijing, P. R. China"]},{"name":"Tsinghua University","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9279-7779","authenticated-orcid":true,"given":"Qiang","family":"Zheng","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Standardization and Measurement for Nanotechnology","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"School of Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"University of Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qing","family":"Feng","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"School of Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"University of Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bohua","family":"Wang","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1376-1725","authenticated-orcid":true,"given":"Chengqian","family":"Cui","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"School of Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"University of Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kun","family":"Wang","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Caoyu","family":"Yang","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"School of Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"University of Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7231-4218","authenticated-orcid":true,"given":"Pengfei","family":"An","sequence":"additional","affiliation":[{"name":"Beijing Synchrotron Radiation Facility","place":["Beijing, P. R. China"]},{"name":"Institute of High Energy Physics, Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9669-4358","authenticated-orcid":true,"given":"Wenxing","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering","place":["Beijing, P. R. China"]},{"name":"Beijing Institute of Technology","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3750-374X","authenticated-orcid":true,"given":"Jing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing Synchrotron Radiation Facility","place":["Beijing, P. R. China"]},{"name":"Institute of High Energy Physics, Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4685-2052","authenticated-orcid":true,"given":"Bin","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering, Department of Chemistry, Center for Super-Diamond and Advanced Films (COSDAF)","place":["Hong Kong, P. R. China"]},{"name":"Hong Kong Institute for Clean Energy (HKICE) and City University of Hong Kong","place":["Hong Kong, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0610-0064","authenticated-orcid":true,"given":"Zhiyong","family":"Tang","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"School of Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"University of Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5099-4873","authenticated-orcid":true,"given":"Guodong","family":"Li","sequence":"additional","affiliation":[{"name":"Chinese Academy of Sciences (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience","place":["Beijing, P. R. China"]},{"name":"National Center for Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"School of Nanoscience and Technology","place":["Beijing, P. R. China"]},{"name":"University of Chinese Academy of Sciences","place":["Beijing, P. R. China"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,3,12]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2024.02.017"},{"key":"ref2\/cit2","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-018-0089-z"},{"key":"ref3\/cit3","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-021-00289-y"},{"key":"ref4\/cit4","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-06060-1"},{"key":"ref5\/cit5","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05362"},{"key":"ref6\/cit6","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-13638-9"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-28607-y"},{"key":"ref8\/cit8","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00723"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1038\/nature19763"},{"key":"ref10\/cit10","doi-asserted-by":"publisher","DOI":"10.1021\/cs400982n"},{"key":"ref11\/cit11","doi-asserted-by":"publisher","DOI":"10.1039\/f19868201681"},{"key":"ref12\/cit12","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c07153"},{"key":"ref13\/cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2015.12.019"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c03401"},{"key":"ref15\/cit15","doi-asserted-by":"publisher","DOI":"10.1021\/cr5002436"},{"key":"ref16\/cit16","doi-asserted-by":"publisher","DOI":"10.1126\/science.1182122"},{"key":"ref17\/cit17","doi-asserted-by":"publisher","DOI":"10.1021\/ja110073u"},{"key":"ref18\/cit18","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202300547"},{"key":"ref19\/cit19","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c01449"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1021\/ja8057953"},{"key":"ref21\/cit21","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b11386"},{"key":"ref22\/cit22","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b01886"},{"key":"ref23\/cit23","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201901349"},{"key":"ref24\/cit24","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202000041"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-020-2738-2"},{"key":"ref26\/cit26","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-024-00603-8"},{"key":"ref27\/cit27","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2017.02.033"},{"key":"ref28\/cit28","doi-asserted-by":"publisher","DOI":"10.1021\/cr300399c"},{"key":"ref29\/cit29","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.0c05747"},{"key":"ref30\/cit30","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.147601"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.7b01929"},{"key":"ref32\/cit32","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202206108"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b00602"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411703"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1103\/RevModPhys.72.621"},{"key":"ref36\/cit36","volume-title":"Advanced inorganic chemistry","author":"Cotton F. A.","year":"1999","edition":"6"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1039\/C5CE00462D"},{"key":"ref39\/cit39","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b10873"},{"key":"ref40\/cit40","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202502546"},{"key":"ref41\/cit41","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c09727"},{"key":"ref42\/cit42","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2020.06.018"},{"key":"ref43\/cit43","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-19438-w"},{"key":"ref44\/cit44","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2019.04.206"},{"key":"ref45\/cit45","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2012.05.020"},{"key":"ref46\/cit46","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202330"},{"key":"ref47\/cit47","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-15445-z"},{"key":"ref48\/cit48","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.4c00357"},{"key":"ref49\/cit49","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c00332"},{"key":"ref50\/cit50","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00584-3"},{"key":"ref51\/cit51","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.27360"},{"key":"ref52\/cit52","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c01070"},{"key":"ref53\/cit53","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00840-0"},{"key":"ref54\/cit54","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218167"},{"key":"ref55\/cit55","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c00746"},{"key":"ref56\/cit56","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05791"},{"key":"ref57\/cit57","doi-asserted-by":"publisher","DOI":"10.1021\/jp512643a"},{"key":"ref58\/cit58","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201000324"},{"key":"ref59\/cit59","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c02379"},{"key":"ref60\/cit60","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c04929"},{"key":"ref61\/cit61","doi-asserted-by":"publisher","DOI":"10.1016\/0927-0256(96)00008-0"},{"key":"ref62\/cit62","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.49.14251"},{"key":"ref63\/cit63","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.47.558"},{"key":"ref64\/cit64","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.11169"},{"key":"ref65\/cit65","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"ref66\/cit66","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.20495"},{"key":"ref67\/cit67","doi-asserted-by":"publisher","DOI":"10.1016\/j.susc.2021.121976"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c01959","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c01959","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,25]],"date-time":"2026-03-25T08:13:51Z","timestamp":1774426431000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.6c01959"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,3,12]]},"references-count":66,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2026,3,25]]}},"alternative-id":["10.1021\/jacs.6c01959"],"URL":"https:\/\/doi.org\/10.1021\/jacs.6c01959","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,3,12]]}}}