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Here, by creating two enantiomeric pairs of high-nuclearity copper sulfide nanoclusters with a mixed-valence Cu(II)\/Cu(I) configuration, we endow these nanoscale assemblies with an intrinsic capacity for electron uptake under mild reducing conditions. The resulting charge imbalance provides an effective thermodynamic driving force that realizes a positively charged metal ion migrating inward through multiple atomic layers and occupying the cluster core. This system thus represents a rare example of a nanocluster platform that simultaneously combines reduction tolerance and structural robustness, preserving its atomic framework despite the incorporation of a single atom effectively modifying the electronic structure, particularly the local chirality. In situ absorption and circular dichroism spectroscopies establish that the transformation proceeds through a continuous, single-particle process rather than a fragmentation-reconstruction pathway, while ex situ pair distribution function analysis resolves key local steps in the structural evolution, offering mechanistic insights into this unique migration behavior.<\/jats:p>","DOI":"10.1021\/jacs.6c03831","type":"journal-article","created":{"date-parts":[[2026,6,29]],"date-time":"2026-06-29T16:33:18Z","timestamp":1782750798000},"page":"35340-35353","source":"Crossref","is-referenced-by-count":3,"title":["Single-Atom Migration\ninto a Chiral Multilayer Nanocluster\nArchitecture"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-5093-8074","authenticated-orcid":true,"given":"Yuhao","family":"Jin","sequence":"first","affiliation":[{"name":"Tongji University , , ,","place":["Shanghai, China, 201804"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Fang","sequence":"additional","affiliation":[{"name":"Tongji University , , ,","place":["Shanghai, China, 201804"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoyu","family":"Pan","sequence":"additional","affiliation":[{"name":"Tongji University , , ,","place":["Shanghai, China, 201804"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenyi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Bruker (Beijing) Scientific Technology Co. 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Crystallogr."},{"key":"2026090104492258200_cit76","doi-asserted-by":"crossref","first-page":"222","DOI":"10.1016\/B978-0-12-823144-9.00040-6","article-title":"Local Structure Determination\nUsing Total Scattering Data","volume-title":"Comprehensive\nInorganic Chemistry III","author":"Billinge","year":"2023"},{"key":"2026090104492258200_cit77","doi-asserted-by":"publisher","first-page":"3533","DOI":"10.1021\/ja00905a001","article-title":"Hard and\nSoft Acids and Bases","volume":"85","author":"Pearson","year":"1963","journal-title":"J. Am. Chem. Soc."},{"issue":"5","key":"2026090104492258200_cit78","doi-asserted-by":"publisher","first-page":"998","DOI":"10.1134\/S0022476625050130","article-title":"Crystal Structure of [Ag(StBu)]","volume":"66","author":"Abramov","year":"2025","journal-title":"J. Struct. 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