{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:46:08Z","timestamp":1792784768455,"version":"4.5.0"},"reference-count":43,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T00:00:00Z","timestamp":1788307200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T00:00:00Z","timestamp":1788307200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T00:00:00Z","timestamp":1788307200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-SC0023383"],"award-info":[{"award-number":["DE-SC0023383"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Braskem","id":[{"id":"https:\/\/ror.org\/05wetj454","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,16]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Electrochemical oxidative carbonylation offers a route to the synthesis of organic carbonates such as dimethyl carbonate (DMC), but its practical implementation is hindered by a competing C\u2013C coupling pathway to dimethyl oxalate (DMO), the origins of which remain poorly understood. Here we study how selectivity in methanol carbonylation is influenced by tuning the adsorption of key surface intermediates. We find, by modulating the interfacial environment using ionomers and isotopically substituted solvents, that strong CO adsorption suppresses C\u2013C coupling and directs the reaction toward carbonate formation. Enhancing methoxy binding promotes deep methoxylation that benefits the overall methanol carbonylation reaction and DMC production. We propose that adsorbed methoxycarbonyl, once viewed as an undesired intermediate, in fact serves as a branching point from which the carbonate and oxalate pathways diverge. Guided by knowledge of these descriptors, we develop a composite catalyst that leverages metal\u2013support interactions, strengthening CO binding and simultaneously accelerating alcohol dissociation, thereby increasing selectivity by 3 orders of magnitude relative to a benchmark Pd catalyst and achieving a Faradaic efficiency of 98% for DMC production.<\/jats:p>","DOI":"10.1021\/jacs.6c04323","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T16:11:10Z","timestamp":1788451870000},"page":"38654-38662","source":"Crossref","is-referenced-by-count":0,"title":["Electrochemical Oxidative\nCarbonylation: Strong CO\nBinding Suppresses C\u2013C Coupling and Steers Selectivity to Organic\nCarbonates"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0234-4483","authenticated-orcid":true,"given":"Weiyan","family":"Ni","sequence":"first","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-2961-2960","authenticated-orcid":true,"given":"Aditya","family":"Menon","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2686-5593","authenticated-orcid":true,"given":"Yiqing","family":"Chen","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2076-8116","authenticated-orcid":true,"given":"Rong","family":"Xia","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9302-5925","authenticated-orcid":true,"given":"Bosi","family":"Peng","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9237-7603","authenticated-orcid":true,"given":"Zeyan","family":"Liu","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li-Yu","family":"Wang","sequence":"additional","affiliation":[{"name":"National Tsing Hua University , , ,","place":["Hsinchu, Taiwan, 300044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6501-1136","authenticated-orcid":true,"given":"Xiaoliang","family":"Wang","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0542-0683","authenticated-orcid":true,"given":"Rui Kai","family":"Miao","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"University of Toronto , , , ,","place":["Toronto, Ontario, Canada, M5S 3G8"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao-Yan","family":"Li","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huajie","family":"Ze","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2714-6408","authenticated-orcid":true,"given":"David","family":"Sinton","sequence":"additional","affiliation":[{"name":"University of Toronto , , , ,","place":["Toronto, Ontario, Canada, M5S 3G8"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9904-9845","authenticated-orcid":true,"given":"Omar","family":"Farha","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9990-4779","authenticated-orcid":true,"given":"Chia-Min","family":"Yang","sequence":"additional","affiliation":[{"name":"National Tsing Hua University , , ,","place":["Hsinchu, Taiwan, 300044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6831-6747","authenticated-orcid":true,"given":"Linsey C.","family":"Seitz","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4220-272X","authenticated-orcid":true,"given":"Ke","family":"Xie","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0396-6495","authenticated-orcid":true,"given":"Edward H.","family":"Sargent","sequence":"additional","affiliation":[{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]},{"name":"Northwestern University , , , ,","place":["Evanston, Illinois, United States, 60208"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,2]]},"reference":[{"issue":"10","key":"2026091609110813700_cit1","doi-asserted-by":"publisher","first-page":"3079","DOI":"10.1039\/C4CS00374H","article-title":"Recent Advances in Dialkyl Carbonates\nSynthesis and Applications","volume":"44","author":"Huang","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"2026091609110813700_cit2","doi-asserted-by":"publisher","first-page":"1561","DOI":"10.3303\/CET1439261","article-title":"The Industrial Production of Dimethyl Carbonate from\nMethanol and Carbon Dioxide","volume":"39","author":"de Groot","year":"2014","journal-title":"Chem. Eng. Trans."},{"issue":"14","key":"2026091609110813700_cit3","doi-asserted-by":"publisher","first-page":"5133","DOI":"10.3390\/en15145133","article-title":"Dimethyl Carbonate: Review of Synthesis\nRoutes and Catalysts Used","volume":"15","author":"Kohli","year":"2022","journal-title":"Energies"},{"issue":"4","key":"2026091609110813700_cit4","doi-asserted-by":"publisher","first-page":"2088","DOI":"10.1021\/acssuschemeng.5b01515","article-title":"Environmental Assessment\nof Dimethyl Carbonate Production: Comparison of a Novel Electrosynthesis\nRoute Utilizing CO2 with a Commercial Oxidative Carbonylation Process","volume":"4","author":"Garcia-Herrero","year":"2016","journal-title":"ACS Sustainable Chem. Eng."},{"issue":"36","key":"2026091609110813700_cit5","doi-asserted-by":"publisher","first-page":"11033","DOI":"10.1021\/ja0724792","article-title":"Direct\nObservation of Electrocatalytic\nSynergy","volume":"129","author":"Zhuang","year":"2007","journal-title":"J. Am. Chem. Soc."},{"issue":"41","key":"2026091609110813700_cit6","doi-asserted-by":"publisher","first-page":"14693","DOI":"10.1021\/jacs.7b08208","article-title":"Spectro-Electrochemical\nExamination of the Formation of Dimethyl Carbonate from CO and Methanol\nat Different Electrode Materials","volume":"139","author":"Figueiredo","year":"2017","journal-title":"J. Am. Chem.\nSoc."},{"issue":"21","key":"2026091609110813700_cit7","doi-asserted-by":"publisher","first-page":"4764","DOI":"10.1016\/j.electacta.2009.04.009","article-title":"CO Oxidation on Non-Alloyed Pt and Ru Electrocatalysts Prepared by\nthe Polygonal Barrel-Sputtering Method","volume":"54","author":"Inoue","year":"2009","journal-title":"Electrochim.\nActa"},{"issue":"2","key":"2026091609110813700_cit8","doi-asserted-by":"publisher","first-page":"140","DOI":"10.1016\/j.jelechem.2011.02.027","article-title":"CO Stripping\nas an Electrochemical Tool for Characterization of Ru@Pt Core-Shell\nCatalysts","volume":"655","author":"Ochal","year":"2011","journal-title":"J. Electroanal. Chem."},{"issue":"17","key":"2026091609110813700_cit9","doi-asserted-by":"publisher","first-page":"5346","DOI":"10.1021\/ja0395700","article-title":"Selectivity Control\nof Carbonylation of Methanol to Dimethyl Oxalate and Dimethyl Carbonate\nover Gold Anode by Electrochemical Potential","volume":"126","author":"Funakawa","year":"2004","journal-title":"J. Am. Chem. Soc."},{"issue":"7","key":"2026091609110813700_cit10","doi-asserted-by":"publisher","first-page":"733","DOI":"10.1038\/s41560-021-00862-1","article-title":"Redox-Neutral Electrochemical\nConversion of CO2 to\nDimethyl Carbonate","volume":"6","author":"Lee","year":"2021","journal-title":"Nat. Energy"},{"issue":"1","key":"2026091609110813700_cit11","doi-asserted-by":"publisher","first-page":"110","DOI":"10.1016\/S0021-9517(03)00309-9","article-title":"Electrocatalytic\nSynthesis of DMC over the Pd\/VGCF Membrane Anode by Gas\u2013Liquid\u2013Solid\nPhase-Boundary Electrolysis","volume":"221","author":"Yamanaka","year":"2004","journal-title":"J. Catal"},{"issue":"1","key":"2026091609110813700_cit12","doi-asserted-by":"publisher","first-page":"4807","DOI":"10.1038\/s41467-019-12788-0","article-title":"Dopant-Tuned\nStabilization of Intermediates Promotes Electrosynthesis of Valuable\nC3 Products","volume":"10","author":"Zhuang","year":"2019","journal-title":"Nat. Commun."},{"issue":"22","key":"2026091609110813700_cit13","doi-asserted-by":"publisher","first-page":"6200","DOI":"10.1039\/C9GC02265A","article-title":"Catalyst Design\nCriteria and Fundamental Limitations in the Electrochemical Synthesis\nof Dimethyl Carbonate","volume":"21","author":"S\u030caric\u0301","year":"2019","journal-title":"Green Chem."},{"issue":"19","key":"2026091609110813700_cit14","doi-asserted-by":"publisher","first-page":"2501780","DOI":"10.1002\/smll.202501780","article-title":"Promoting Intermediate\nStabilization and Coupling for Dimethyl Carbonate\nElectrosynthesis","volume":"21","author":"Mi","year":"2025","journal-title":"Small"},{"issue":"11","key":"2026091609110813700_cit15","doi-asserted-by":"publisher","first-page":"3380","DOI":"10.1039\/C9EE02485A","article-title":"Modeling\nthe Electrical Double Layer to Understand the Reaction Environment\nin a CO2 Electrocatalytic System","volume":"12","author":"Bohra","year":"2019","journal-title":"Energy Environ. Sci."},{"issue":"10","key":"2026091609110813700_cit16","doi-asserted-by":"publisher","first-page":"3001","DOI":"10.1039\/C9EE01341E","article-title":"Understanding\nCation Effects in Electrochemical\nCO2 Reduction","volume":"12","author":"Ringe","year":"2019","journal-title":"Energy Environ. Sci."},{"issue":"1","key":"2026091609110813700_cit17","doi-asserted-by":"publisher","first-page":"255","DOI":"10.1021\/jp022052b","article-title":"CO Adsorption\non Pd Nanoparticles: Density Functional and Vibrational Spectroscopy\nStudies","volume":"107","author":"Yudanov","year":"2003","journal-title":"J. Phys. Chem. B"},{"key":"2026091609110813700_cit18","doi-asserted-by":"publisher","first-page":"210","DOI":"10.1016\/j.susc.2015.07.014","article-title":"CO Adsorption\nover Pd Nanoparticles: A General Framework for IR Simulations on Nanoparticles","volume":"646","author":"Zeinalipour-Yazdi","year":"2016","journal-title":"Surf. Sci."},{"issue":"10","key":"2026091609110813700_cit19","doi-asserted-by":"publisher","first-page":"7133","DOI":"10.1021\/acscatal.6b02299","article-title":"Electric\nField Effects in Electrochemical CO2 Reduction","volume":"6","author":"Chen","year":"2016","journal-title":"ACS Catal"},{"issue":"19","key":"2026091609110813700_cit20","doi-asserted-by":"publisher","first-page":"9220","DOI":"10.1073\/pnas.1900761116","article-title":"Hydrogen Bonding\nSteers the Product Selectivity of Electrocatalytic CO Reduction","volume":"116","author":"Li","year":"2019","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"issue":"1","key":"2026091609110813700_cit21","doi-asserted-by":"publisher","first-page":"46","DOI":"10.1038\/s41560-020-00735-z","article-title":"Electrochemical\nUpgrade of CO2 from\nAmine Capture Solution","volume":"6","author":"Lee","year":"2021","journal-title":"Nat. Energy"},{"issue":"23","key":"2026091609110813700_cit22","doi-asserted-by":"publisher","first-page":"5362","DOI":"10.1021\/acs.jpclett.3c00786","article-title":"Isotope Effect in D2 O\nNegative Ion Formation\nin Electron Transfer Experiments: DO\u2013D Bond Dissociation Energy","volume":"14","author":"Kumar","year":"2023","journal-title":"J. Phys. Chem. Lett."},{"issue":"6","key":"2026091609110813700_cit23","doi-asserted-by":"publisher","first-page":"1074","DOI":"10.1021\/j100824a521","article-title":"DEUTERIUM\nISOTOPE EFFECTS ON DISSOCIATION\nCONSTANTS AND FORMATION CONSTANTS1","volume":"65","author":"Li","year":"1961","journal-title":"J. Phys. Chem."},{"issue":"1","key":"2026091609110813700_cit24","doi-asserted-by":"publisher","first-page":"161","DOI":"10.1016\/j.jinorgbio.2003.10.001","article-title":"A Formula\nfor Correlating p K a Values Determined in D 2 O and H\n2 O","volume":"98","author":"Kre\u0327z\u0307el","year":"2004","journal-title":"J. Inorg. Biochem."},{"issue":"7","key":"2026091609110813700_cit25","doi-asserted-by":"publisher","first-page":"804","DOI":"10.1038\/s41563-022-01221-5","article-title":"An Efficient Nickel\nHydrogen Oxidation Catalyst for\nHydroxide Exchange Membrane Fuel Cells","volume":"21","author":"Ni","year":"2022","journal-title":"Nat.\nMater."},{"issue":"2","key":"2026091609110813700_cit26","doi-asserted-by":"publisher","first-page":"271","DOI":"10.1038\/s41557-022-01084-y","article-title":"Inverse\nKinetic Isotope Effects in\nthe Oxygen Reduction Reaction at Platinum Single Crystals","volume":"15","author":"Yang","year":"2023","journal-title":"Nat. Chem."},{"issue":"42","key":"2026091609110813700_cit27","doi-asserted-by":"publisher","first-page":"15191","DOI":"10.1021\/jacs.7b08643","article-title":"Stabilizing CuPd Nanoparticles via CuPd Coupling to\nWO2.72 Nanorods in Electrochemical Oxidation of Formic\nAcid","volume":"139","author":"Xi","year":"2017","journal-title":"J. Am. Chem. Soc."},{"issue":"6276","key":"2026091609110813700_cit28","doi-asserted-by":"publisher","first-page":"965","DOI":"10.1126\/science.aad5705","article-title":"Palladium-Tin\nCatalysts for the Direct\nSynthesis of H2 O2 with High Selectivity","volume":"351","author":"Freakley","year":"2016","journal-title":"Science"},{"issue":"3","key":"2026091609110813700_cit29","doi-asserted-by":"publisher","first-page":"419","DOI":"10.1039\/C1CC16522D","article-title":"Poisoning Effect Diminished on a\nNovel PdHoOx\/C Catalyst for the Electrooxidation of Formic Acid","volume":"48","author":"Feng","year":"2012","journal-title":"Chem. Commun."},{"issue":"6","key":"2026091609110813700_cit30","doi-asserted-by":"publisher","first-page":"550","DOI":"10.1038\/nmat3313","article-title":"Trends in Activity for the Water Electrolyser Reactions\non 3d M(Ni,Co,Fe,Mn) Hydr(Oxy)Oxide Catalysts","volume":"11","author":"Subbaraman","year":"2012","journal-title":"Nat. Mater."},{"issue":"2","key":"2026091609110813700_cit31","doi-asserted-by":"publisher","first-page":"107","DOI":"10.1038\/s41560-018-0296-8","article-title":"Multi-Site Electrocatalysts for Hydrogen\nEvolution in Neutral Media by Destabilization of Water Molecules","volume":"4","author":"Dinh","year":"2019","journal-title":"Nat. Energy"},{"key":"2026091609110813700_cit32","doi-asserted-by":"publisher","first-page":"59","DOI":"10.1016\/j.ica.2014.01.041","article-title":"Controllable Synthesis\nof Palladium\nNanoparticles and Their Catalytic Abilities in Heck and Suzuki Reactions","volume":"414","author":"Li","year":"2014","journal-title":"Inorg. Chim. Acta"},{"issue":"2","key":"2026091609110813700_cit33","doi-asserted-by":"publisher","first-page":"2412402","DOI":"10.1002\/adfm.202412402","article-title":"Synergistic Pd-Au\nCatalyst for Selective\nElectrosynthesis of Dimethyl Carbonate in Conjunction with High-Rate\nRedox System","volume":"35","author":"Fujinuma","year":"2025","journal-title":"Adv. Funct. Mater."},{"issue":"5","key":"2026091609110813700_cit34","doi-asserted-by":"publisher","first-page":"463","DOI":"10.1038\/s41929-020-0455-8","article-title":"Non-Aqueous\nGas Diffusion Electrodes for Rapid Ammonia Synthesis from Nitrogen\nand Water-Splitting-Derived Hydrogen","volume":"3","author":"Lazouski","year":"2020","journal-title":"Nat. Catal"},{"issue":"4","key":"2026091609110813700_cit35","doi-asserted-by":"publisher","first-page":"448","DOI":"10.1246\/cl.2002.448","article-title":"Selective Carbonylation of Methanol\nto Dimethyl Carbonate by Gas\u2013Liquid\u2013Solid-Phase Boundary\nElectrolysis","volume":"31","author":"Yamanaka","year":"2002","journal-title":"Chem. Lett."},{"issue":"18","key":"2026091609110813700_cit36","doi-asserted-by":"publisher","first-page":"9140","DOI":"10.1021\/jp0448752","article-title":"Active Control\nof Methanol Carbonylation\nSelectivity over Au\/Carbon Anode by Electrochemical Potential","volume":"109","author":"Funakawa","year":"2005","journal-title":"J. Phys. Chem. B"},{"issue":"1","key":"2026091609110813700_cit37","doi-asserted-by":"publisher","first-page":"130","DOI":"10.1149\/1.2043851","article-title":"Electrolytic\nCarbonylation of Methanol\nover the CuCl2 Anode in the Gas Phase","volume":"142","author":"Otsuka","year":"1995","journal-title":"J. Electrochem.\nSoc."},{"issue":"14","key":"2026091609110813700_cit38","doi-asserted-by":"publisher","first-page":"2109","DOI":"10.1016\/0013-4686(94)E0175-Y","article-title":"Dimethyl Carbonate Synthesis by Electrolytic\nCarbonylation of Methanol in the Gas Phase","volume":"39","author":"Otsuka","year":"1994","journal-title":"Electrochim. Acta"},{"issue":"25","key":"2026091609110813700_cit39","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202401311","article-title":"Stabilization of Pd0\nby Cu Alloying: Theory-Guided Design of Pd3Cu Electrocatalyst for\nAnodic Methanol Carbonylation","volume":"63","author":"Shi","year":"2024","journal-title":"Angew. Chem.\nInt. Ed."},{"issue":"5","key":"2026091609110813700_cit40","doi-asserted-by":"publisher","first-page":"054501","DOI":"10.1149\/2.0022005JES","article-title":"The Importance\nof Water Transport in High Conductivity and High-Power Alkaline Fuel\nCells","volume":"167","author":"Mandal","year":"2020","journal-title":"J. Electrochem. Soc."},{"issue":"12","key":"2026091609110813700_cit41","doi-asserted-by":"publisher","first-page":"8719","DOI":"10.1021\/acs.nanolett.0c03560","article-title":"Designing\na Nanoscale Three-Phase Electrochemical Pathway to Promote Pt-Catalyzed\nFormaldehyde Oxidation","volume":"20","author":"Xu","year":"2020","journal-title":"Nano Lett."},{"issue":"28","key":"2026091609110813700_cit42","doi-asserted-by":"publisher","first-page":"R705","DOI":"10.1088\/0953-8984\/17\/28\/R01","article-title":"Electrowetting: From Basics to Applications","volume":"17","author":"Mugele","year":"2005","journal-title":"J. Phys.: Condens. Matter."},{"issue":"10","key":"2026091609110813700_cit43","doi-asserted-by":"publisher","first-page":"2742","DOI":"10.1016\/j.joule.2021.08.013","article-title":"Electroosmotic Flow\nSteers Neutral Products and Enables\nConcentrated Ethanol Electroproduction from CO2","volume":"5","author":"Miao","year":"2021","journal-title":"Joule"}],"container-title":["Journal of the American\nChemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c04323","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/36\/38654\/68191748\/jacs.6c04323.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/36\/38654\/68191748\/jacs.6c04323.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T13:29:42Z","timestamp":1789565382000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/36\/38654\/5404905\/Electrochemical-Oxidative-Carbonylation-Strong-CO"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,2]]},"references-count":43,"journal-issue":{"issue":"36","published-online":{"date-parts":[[2026,9,2]]},"published-print":{"date-parts":[[2026,9,16]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c04323","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,2]]}}}