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However, it remains difficult to design molecules that simultaneously possess NIR-selective absorption and the semiconductor characteristics required for OPV operation. Here, we combine Laporte-rule-guided control of molecular symmetry with intramolecular charge-transfer engineering using a strongly electron-donating indacenodipyrrole unit to develop an acceptor\u2013donor\u2013acceptor molecule P1 with absorption extending into the NIR region. Theoretical calculations predict that the dominant allowed transition of P1 is to the first excited state, whereas transitions to higher excited states are largely suppressed. Consistent with this, P1 selectively absorbs in the NIR region with negligible visible absorption, yielding a colorless and transparent appearance. The frontier-orbital energetics and excitonic parameters of P1 are suitable for NIR-selective photoelectric conversion. Notably, single-component OPVs based on P1 achieve external quantum efficiencies exceeding 15% in the NIR region while retaining high visible transparency. Time-resolved measurements further confirm effective carrier generation and charge transport under NIR photoexcitation. These results demonstrate that orbital-symmetry control can suppress visible absorption while charge-transfer-induced bandgap narrowing enables NIR photoresponse, offering a molecular design principle for colorless wavelength-selective organic optoelectronic devices.<\/jats:p>","DOI":"10.1021\/jacs.6c05512","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T13:02:35Z","timestamp":1785934955000},"page":"34195-34208","source":"Crossref","is-referenced-by-count":0,"title":["Laporte-Rule-Guided\nMolecular Symmetry Control of\nNIR-Selective Organic Semiconductors for Colorless and Transparent\nPhotovoltaics"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6218-1159","authenticated-orcid":true,"given":"Soichi","family":"Yokoyama","sequence":"first","affiliation":[{"name":"The University of Osaka , , 8-1 Mihogaoka , , ,","place":["Ibaraki, Osaka, Japan, 567-0047"]},{"name":"The University of Osaka , , 2-1 Yamadaoka , , ,","place":["Suita, Osaka, Japan, 565-0871"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0817-5249","authenticated-orcid":true,"given":"Kenta","family":"Kuroishi","sequence":"additional","affiliation":[{"name":"The University of Tokyo , , 5-1-5, Kashiwanoha , , ,","place":["Kashiwa, Chiba, Japan, 277-8581"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shunsuke","family":"Tanaka","sequence":"additional","affiliation":[{"name":"The University of Tokyo , , 5-1-5, Kashiwanoha , , ,","place":["Kashiwa, Chiba, Japan, 277-8581"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3071-6408","authenticated-orcid":true,"given":"Yuta","family":"Murotani","sequence":"additional","affiliation":[{"name":"The University of Tokyo , , 5-1-5, Kashiwanoha , , ,","place":["Kashiwa, Chiba, Japan, 277-8581"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9674-5100","authenticated-orcid":true,"given":"Ryusuke","family":"Matsunaga","sequence":"additional","affiliation":[{"name":"The University of Tokyo , , 5-1-5, Kashiwanoha , , ,","place":["Kashiwa, Chiba, Japan, 277-8581"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuhei","family":"Kawaoka","sequence":"additional","affiliation":[{"name":"artience Co., Ltd. , 6-7, 5 Chiyoda , , ,","place":["Sakado, Saitama, Japan, 350-0214"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Reo","family":"Ohno","sequence":"additional","affiliation":[{"name":"Aoyama Gakuin University , , 5-10-1 Fuchinobe, Chuo-ku , , ,","place":["Sagamihara, Kanagawa, Japan, 252-5258"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0082-2576","authenticated-orcid":true,"given":"Miki","family":"Hasegawa","sequence":"additional","affiliation":[{"name":"Aoyama Gakuin University , , 5-10-1 Fuchinobe, Chuo-ku , , ,","place":["Sagamihara, Kanagawa, Japan, 252-5258"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7429-2200","authenticated-orcid":true,"given":"Akinori","family":"Saeki","sequence":"additional","affiliation":[{"name":"The University of Osaka , , 2-1 Yamadaoka , , ,","place":["Suita, Osaka, Japan, 565-0871"]},{"name":"The University of Osaka , , 2-1 Yamadaoka , , ,","place":["Suita, Osaka, Japan, 565-0871"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7774-8701","authenticated-orcid":true,"given":"Jun","family":"Yoshinobu","sequence":"additional","affiliation":[{"name":"The University of Tokyo , , 5-1-5, Kashiwanoha , , ,","place":["Kashiwa, Chiba, Japan, 277-8581"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0208-4298","authenticated-orcid":true,"given":"Yutaka","family":"Ie","sequence":"additional","affiliation":[{"name":"The University of Osaka , , 8-1 Mihogaoka , , ,","place":["Ibaraki, Osaka, Japan, 567-0047"]},{"name":"The University of Osaka , , 2-1 Yamadaoka , , ,","place":["Suita, Osaka, Japan, 565-0871"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,4]]},"reference":[{"issue":"18","key":"2026081910215234100_cit1","doi-asserted-by":"publisher","first-page":"14180","DOI":"10.1021\/acs.chemrev.1c00955","article-title":"Renewed Prospects\nfor Organic Photovoltaics","volume":"122","author":"Zhang","year":"2022","journal-title":"Chem. 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Chem. Eng."},{"key":"2026081910215234100_cit10","doi-asserted-by":"publisher","first-page":"101673","DOI":"10.1016\/j.mtener.2024.101673","article-title":"Green-Light Wavelength-Selective\nOrganic Solar Cells: Module Fabrication and Crop Evaluation towards\nAgrivoltaics","volume":"45","author":"Chatterjee","year":"2024","journal-title":"Mater. Today Energy"},{"key":"2026081910215234100_cit11","doi-asserted-by":"publisher","first-page":"10699","DOI":"10.1038\/s41598-017-11193-1","article-title":"Semi-transparent Perovskite Solar\nCells Developed by\nConsidering Human Luminosity Function","volume":"7","author":"Kim","year":"2017","journal-title":"Sci.\nRep."},{"issue":"9","key":"2026081910215234100_cit12","doi-asserted-by":"publisher","first-page":"1816","DOI":"10.1016\/j.joule.2018.06.006","article-title":"Heat-Insulating Multifunctional\nSemitransparent Polymer Solar Cells","volume":"2","author":"Sun","year":"2018","journal-title":"Joule"},{"issue":"10","key":"2026081910215234100_cit13","doi-asserted-by":"publisher","first-page":"1807159","DOI":"10.1002\/adma.201807159","article-title":"Highly Efficient Semitransparent Organic Solar Cells\nwith Color Rendering Index Approaching 100","volume":"31","author":"Zhang","year":"2019","journal-title":"Adv. Mater."},{"issue":"1","key":"2026081910215234100_cit14","doi-asserted-by":"publisher","first-page":"2100909","DOI":"10.1002\/solr.202100909","article-title":"Ultrathin\nWide-Bandgap a-Si:H-Based Solar Cells for Transparent Photovoltaic\nApplications","volume":"6","author":"Lopez-Garcia","year":"2022","journal-title":"Sol. RRL"},{"issue":"37","key":"2026081910215234100_cit15","doi-asserted-by":"publisher","first-page":"2301480","DOI":"10.1002\/smll.202301480","article-title":"Minimizing the Carrier Collection\nLoss of the Neutral-Color Transparent Crystalline-silicon Solar Modules\nvia Hybrid Electrode Design","volume":"19","author":"Lee","year":"2023","journal-title":"Small"},{"issue":"33","key":"2026081910215234100_cit16","doi-asserted-by":"publisher","first-page":"2200402","DOI":"10.1002\/aenm.202200402","article-title":"Highly Transparent, Scalable, and Stable Perovskite\nSolar Cells with Minimal Aesthetic Compromise","volume":"13","author":"Liu","year":"2023","journal-title":"Adv. Energy Mater."},{"issue":"3","key":"2026081910215234100_cit17","doi-asserted-by":"publisher","first-page":"748","DOI":"10.1021\/ol4034622","article-title":"\u03b2-Thiophene-Fused\nBF2-Azadipyrromethenes as Near-Infrared Dyes","volume":"16","author":"Wu","year":"2014","journal-title":"Org. Lett."},{"issue":"35","key":"2026081910215234100_cit18","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202207459","article-title":"Transparent\nand Colorless Dye-Sensitized Solar Cells Based on Pyrrolopyrrole Cyanine\nSensitizers","volume":"61","author":"Baron","year":"2022","journal-title":"Angew. Chem. Int. Ed."},{"issue":"24","key":"2026081910215234100_cit19","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202303870","article-title":"Ultra-Small-Bandgap Conjugated Polymers\nBased on an\nN\u2013B\u2190N Unit","volume":"62","author":"Xu","year":"2023","journal-title":"Angew. Chem. Int.\nEd."},{"issue":"31","key":"2026081910215234100_cit20","doi-asserted-by":"publisher","first-page":"2405656","DOI":"10.1002\/advs.202405656","article-title":"Colorless\nNear-Infrared Absorbing Dyes Based on B-N Fused Donor-Acceptor-Donor\n\u03c0-Conjugated Molecules for Organic Phototransistors","volume":"11","author":"Yokoyama","year":"2024","journal-title":"Adv. Sci."},{"key":"2026081910215234100_cit21","doi-asserted-by":"publisher","first-page":"157","DOI":"10.1016\/j.solmat.2013.08.011","article-title":"Semitransparent Organic\nPhotovoltaics Using a Near-Infrared Absorbing Cyanine Dye","volume":"118","author":"Zhang","year":"2013","journal-title":"Sol. Energy Mater. Sol. Cells"},{"issue":"4","key":"2026081910215234100_cit22","doi-asserted-by":"publisher","first-page":"409","DOI":"10.1021\/jacsau.1c00045","article-title":"Transparent\nand Colorless\nDye-Sensitized Solar Cells Exceeding 75% Average Visible Transmittance","volume":"1","author":"Naim","year":"2021","journal-title":"JACS Au"},{"issue":"11","key":"2026081910215234100_cit23","doi-asserted-by":"publisher","first-page":"1399","DOI":"10.1002\/cjoc.202200688","article-title":"Advances in Polymethine\nDyes for Near-Infrared Organic Photodiodes","volume":"41","author":"He","year":"2023","journal-title":"Chin. J. Chem."},{"issue":"9","key":"2026081910215234100_cit24","doi-asserted-by":"publisher","first-page":"1401","DOI":"10.1002\/anie.200502998","article-title":"Pentarylene-\nand Hexarylenebis(Dicarboximide)s: Near-Infrared-Absorbing Polyaromatic\nDyes","volume":"45","author":"Pschirer","year":"2006","journal-title":"Angew. Chem. Int. 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Energy Mater."},{"issue":"1","key":"2026081910215234100_cit28","doi-asserted-by":"publisher","first-page":"3943","DOI":"10.1038\/s41467-020-17867-1","article-title":"Delocalization\nof Exciton and Electron Wavefunction in Non-Fullerene Acceptor Molecules\nEnables Efficient Organic Solar Cells","volume":"11","author":"Zhang","year":"2020","journal-title":"Nat.\nCommun."},{"issue":"6","key":"2026081910215234100_cit29","doi-asserted-by":"publisher","first-page":"100895","DOI":"10.1016\/j.xcrp.2022.100895","article-title":"Single Photovoltaic\nMaterial Solar Cells with Enhanced\nExciton Dissociation and Extended Electron Diffusion","volume":"3","author":"Zhang","year":"2022","journal-title":"Cell Reports Phys. Sci."},{"issue":"5","key":"2026081910215234100_cit30","doi-asserted-by":"publisher","first-page":"1825","DOI":"10.1039\/d2mh01411d","article-title":"What Is Special about Y6; the Working Mechanism of\nNeat Y6 Organic Solar Cells","volume":"10","author":"Sag\u0306lamkaya","year":"2023","journal-title":"Mater. Horizons"},{"issue":"10","key":"2026081910215234100_cit31","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202513943","article-title":"Side-Chain\nControlled Exciton Binding Energy in Y-Acceptors Toward Homo-Junction\nOrganic Solar Cells With 5.07% Efficiency","volume":"22","author":"Fan","year":"2026","journal-title":"Small"},{"issue":"41","key":"2026081910215234100_cit32","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409964","article-title":"Dibenzo[g,p]Chrysene-Based\nOrganic\nSemiconductor with Small Exciton Binding Energy via Molecular Aggregation","volume":"63","author":"Mori","year":"2024","journal-title":"Angew. Chem. Int. 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Phys."},{"issue":"38","key":"2026081910215234100_cit35","doi-asserted-by":"publisher","first-page":"13364","DOI":"10.1021\/ja053296n","article-title":"Incisive Structure-Spectroscopic\nCorrelation in Oligothiophenes Functionalized with (\u00b1) Inductive\/Mesomeric\nFluorine Groups: Joint Raman and DFT Study","volume":"127","author":"Casado","year":"2005","journal-title":"J. Am. Chem. Soc."},{"issue":"18","key":"2026081910215234100_cit36","doi-asserted-by":"publisher","first-page":"9975","DOI":"10.1021\/acs.jpcc.6b02100","article-title":"Benchmarking\nDensity Functional Theory Approaches for the Description of Symmetry\nBreaking in Long Polymethine Dyes","volume":"120","author":"Gieseking","year":"2016","journal-title":"J. Phys.\nChem. 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