{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T14:23:35Z","timestamp":1786112615108,"version":"build-2736575974"},"reference-count":51,"publisher":"American Chemical Society (ACS)","issue":"30","license":[{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Basic Research Program of China (973 Program)","doi-asserted-by":"crossref","award":["2021YFA1501600"],"award-info":[{"award-number":["2021YFA1501600"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China (NSFC)","doi-asserted-by":"crossref","award":["22193020"],"award-info":[{"award-number":["22193020"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China (NSFC)","doi-asserted-by":"crossref","award":["22193024"],"award-info":[{"award-number":["22193024"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China (NSFC)","doi-asserted-by":"crossref","award":["22371089"],"award-info":[{"award-number":["22371089"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China (NSFC)","doi-asserted-by":"crossref","award":["22501098"],"award-info":[{"award-number":["22501098"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Controlled radical polymerization has fundamentally transformed polymer science, enabling the synthesis of materials with precisely tailored architectures and predictable molecular weights. However, achieving rapid polymerization while maintaining good control remains a great challenge in controlled radical polymerization. Herein, we report a supramolecular strategy to alleviate this problem in aqueous photoiniferter and reversible addition\u2013fragmentation chain transfer (RAFT) polymerizations through host\u2013guest complexation between cationic thiocarbonylthio-based agents and cucurbit[7]uril (CB[7]). Such encapsulation induces a significant increase in the chain transfer coefficient and photolysis efficiency of the CTA. Spectroscopic and computational analyses reveal that the macrocyclic host promotes triplet-state population via enhanced spin\u2013orbit coupling, while simultaneously lowering fragmentation barriers and facilitating reversible deactivation. This mechanistic synergy enables the synthesis of ultrahigh-molecular-weight polymers (Mn up to 2,190 kg mol\u20131) and the rapid construction of well-defined 20-block copolymers with excellent end-group fidelity and high initiator efficiency. This supramolecular strategy yields accelerated yet highly controlled polymerizations in aqueous media, providing a promising approach to balancing rate and control using dithiocarbamate-based chain transfer agents.<\/jats:p>","DOI":"10.1021\/jacs.6c05797","type":"journal-article","created":{"date-parts":[[2026,7,21]],"date-time":"2026-07-21T03:43:58Z","timestamp":1784605438000},"page":"31967-31977","source":"Crossref","is-referenced-by-count":0,"title":["Supramolecular\nModulation of Controlled Radical Polymerization"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1124-4433","authenticated-orcid":true,"given":"Shilong","family":"Zhu","sequence":"first","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8896-1767","authenticated-orcid":true,"given":"Rong-Lin","family":"Zhong","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ling-Qi","family":"Meng","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziya","family":"Qing","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6450-6268","authenticated-orcid":true,"given":"Chenyu","family":"Wu","sequence":"additional","affiliation":[{"name":"Shandong University , , ,","place":["Qingdao, China, 266042"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9690-5992","authenticated-orcid":true,"given":"Guanglu","family":"Wu","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8289-6351","authenticated-orcid":true,"given":"Steven P.","family":"Armes","sequence":"additional","affiliation":[{"name":"University of Sheffield , , Brook Hill , , ,","place":["Sheffield, South Yorkshire, U.K., S3 7HF"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2064-4132","authenticated-orcid":true,"given":"Zesheng","family":"An","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]},{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,20]]},"reference":[{"issue":"11","key":"2026080511102656400_cit1","doi-asserted-by":"publisher","first-page":"5051","DOI":"10.1021\/cr9001269","article-title":"Precision\nPolymer Synthesis by Degenerative Transfer Controlled\/Living Radical\nPolymerization Using Organotellurium, Organostibine, and Organobismuthine\nChain-Transfer Agents","volume":"109","author":"Yamago","year":"2009","journal-title":"Chem. Rev."},{"issue":"19","key":"2026080511102656400_cit2","doi-asserted-by":"publisher","first-page":"7433","DOI":"10.1021\/acs.macromol.7b00767","article-title":"50th Anniversary\nPerspective: RAFT Polymerization\u2500A User Guide","volume":"50","author":"Perrier","year":"2017","journal-title":"Macromolecules"},{"key":"2026080511102656400_cit3","doi-asserted-by":"publisher","first-page":"101311","DOI":"10.1016\/j.progpolymsci.2020.101311","article-title":"Reversible-deactivation\nradical polymerization (Controlled\/living\nradical polymerization): From discovery to materials design and applications","volume":"111","author":"Corrigan","year":"2020","journal-title":"Prog. Polym. Sci."},{"issue":"12","key":"2026080511102656400_cit4","doi-asserted-by":"publisher","first-page":"859","DOI":"10.1038\/s41570-021-00328-8","article-title":"A comparison of RAFT and ATRP methods for controlled\nradical polymerization","volume":"5","author":"Truong","year":"2021","journal-title":"Nat. Rev. Chem."},{"issue":"1","key":"2026080511102656400_cit5","doi-asserted-by":"publisher","first-page":"2","DOI":"10.1038\/s43586-024-00370-y","article-title":"Atom transfer\nradical polymerization","volume":"5","author":"Harrisson","year":"2025","journal-title":"Nat. Rev. Methods Primers"},{"issue":"14","key":"2026080511102656400_cit6","doi-asserted-by":"publisher","first-page":"5508","DOI":"10.1021\/ja501745g","article-title":"A Robust and Versatile Photoinduced\nLiving Polymerization of Conjugated\nand Unconjugated Monomers and Its Oxygen Tolerance","volume":"136","author":"Xu","year":"2014","journal-title":"J. Am. Chem. Soc."},{"issue":"1","key":"2026080511102656400_cit7","doi-asserted-by":"publisher","first-page":"93","DOI":"10.1016\/j.chempr.2016.12.007","article-title":"Ultra-High Molecular\nWeights via Aqueous Reversible-Deactivation Radical Polymerization","volume":"2","author":"Carmean","year":"2017","journal-title":"Chem"},{"issue":"43","key":"2026080511102656400_cit8","doi-asserted-by":"publisher","first-page":"19942","DOI":"10.1021\/jacs.2c08173","article-title":"Photoinduced\nIon-Pair Inner-Sphere\nElectron Transfer-Reversible Addition\u2013Fragmentation Chain Transfer\nPolymerization","volume":"144","author":"Wang","year":"2022","journal-title":"J. Am. Chem. Soc."},{"issue":"2","key":"2026080511102656400_cit9","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202314483","article-title":"Organocatalyzed Photo-Controlled\nSynthesis of Ultrahigh-Molecular-Weight Fluorinated Alternating Copolymers","volume":"63","author":"Zhou","year":"2024","journal-title":"Angew. Chem. Int. Ed."},{"issue":"35","key":"2026080511102656400_cit10","doi-asserted-by":"publisher","first-page":"32096","DOI":"10.1021\/jacs.5c10541","article-title":"Red Light-Driven,\nOxygen-Tolerant RAFT Polymerization Enabled by Methylene Blue","volume":"147","author":"Trachsel","year":"2025","journal-title":"J. Am. Chem. Soc."},{"issue":"1","key":"2026080511102656400_cit11","doi-asserted-by":"publisher","first-page":"15","DOI":"10.1038\/s44160-024-00710-6","article-title":"Photocontrolled radical\npolymerization for the synthesis of ultrahigh-molecular-weight\npolymers","volume":"4","author":"Zhu","year":"2025","journal-title":"Nat. Synth."},{"issue":"29","key":"2026080511102656400_cit12","doi-asserted-by":"publisher","first-page":"11128","DOI":"10.1021\/ja205080u","article-title":"High-Order Multiblock Copolymers\nvia Iterative Cu(0)-Mediated\nRadical Polymerizations (SET-LRP): Toward Biological Precision","volume":"133","author":"Soeriyadi","year":"2011","journal-title":"J. Am. Chem. Soc."},{"issue":"1","key":"2026080511102656400_cit13","doi-asserted-by":"publisher","first-page":"2505","DOI":"10.1038\/ncomms3505","article-title":"Rapid and quantitative\none-pot synthesis of sequence-controlled polymers by radical polymerization","volume":"4","author":"Gody","year":"2013","journal-title":"Nat. Commun."},{"issue":"2","key":"2026080511102656400_cit14","doi-asserted-by":"publisher","first-page":"171","DOI":"10.1038\/nchem.2634","article-title":"Sequence-controlled\nmethacrylic multiblock copolymers via sulfur-free RAFT emulsion polymerization","volume":"9","author":"Engelis","year":"2017","journal-title":"Nat. Chem."},{"issue":"44","key":"2026080511102656400_cit15","doi-asserted-by":"publisher","first-page":"13852","DOI":"10.1002\/anie.201707993","article-title":"Enzymatic Cascade Catalysis for the Synthesis of Multiblock\nand Ultrahigh-Molecular-Weight Polymers with Oxygen Tolerance","volume":"56","author":"Liu","year":"2017","journal-title":"Angew. Chem. Int. Ed."},{"issue":"11","key":"2026080511102656400_cit16","doi-asserted-by":"publisher","first-page":"1537","DOI":"10.1039\/D1PY01530C","article-title":"The difference\nbetween photo-iniferter\nand conventional RAFT polymerization: high livingness enables the\nstraightforward synthesis of multiblock copolymers","volume":"13","author":"Lehnen","year":"2022","journal-title":"Polym. Chem."},{"issue":"53","key":"2026080511102656400_cit17","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202301767","article-title":"The Power\nof Automation in Polymer Chemistry: Precision Synthesis of Multiblock\nCopolymers with Block Sequence Control","volume":"29","author":"Jafari","year":"2023","journal-title":"Chem.\nEur. J."},{"issue":"20","key":"2026080511102656400_cit18","doi-asserted-by":"publisher","first-page":"2001656","DOI":"10.1002\/advs.202001656","article-title":"Progress and Perspectives\nBeyond Traditional RAFT Polymerization","volume":"7","author":"Nothling","year":"2020","journal-title":"Adv.\nSci."},{"issue":"3","key":"2026080511102656400_cit19","doi-asserted-by":"publisher","first-page":"184","DOI":"10.1021\/acspolymersau.4c00101","article-title":"RAFT with Light: A\nUser Guide to Using Thiocarbonylthio Compounds in Photopolymerizations","volume":"5","author":"Beres","year":"2025","journal-title":"ACS Polym. Au."},{"issue":"6","key":"2026080511102656400_cit20","doi-asserted-by":"publisher","first-page":"379","DOI":"10.1071\/CH05072","article-title":"Living\nradical polymerization by\nthe RAFT process","volume":"58","author":"Moad","year":"2005","journal-title":"Aust. J. Chem."},{"issue":"10","key":"2026080511102656400_cit21","doi-asserted-by":"publisher","first-page":"3183","DOI":"10.1002\/anie.201810384","article-title":"Precise Polymer Synthesis\nby Autonomous Self-Optimizing Flow Reactors","volume":"58","author":"Rubens","year":"2019","journal-title":"Angew. Chem. Int. Ed."},{"issue":"11","key":"2026080511102656400_cit22","doi-asserted-by":"publisher","first-page":"5385","DOI":"10.1021\/acs.macromol.5c00820","article-title":"Reversible Deactivation Radical Polymerization\nin Heterogeneous Systems: Enhancing Access to High Molecular Weight\nPolymers","volume":"58","author":"Lian","year":"2025","journal-title":"Macromolecules"},{"issue":"3","key":"2026080511102656400_cit23","doi-asserted-by":"publisher","first-page":"593","DOI":"10.1039\/D2SC05197D","article-title":"Xanthate-supported\nphoto-iniferter (XPI)-RAFT polymerization:\nfacile and rapid access to complex macromolecules","volume":"14","author":"Lehnen","year":"2023","journal-title":"Chem. Sci."},{"issue":"3","key":"2026080511102656400_cit24","doi-asserted-by":"publisher","first-page":"291","DOI":"10.1038\/s44160-023-00463-8","article-title":"An acidic\nroute for radical polymerizations","volume":"3","author":"Hartlieb","year":"2024","journal-title":"Nat. Synth."},{"issue":"25","key":"2026080511102656400_cit25","doi-asserted-by":"publisher","first-page":"11626","DOI":"10.1039\/D5SC02594J","article-title":"Rapid and\nprecise synthesis of acrylic polymers driven by visible light","volume":"16","author":"Yu","year":"2025","journal-title":"Chem. Sci."},{"issue":"12","key":"2026080511102656400_cit26","doi-asserted-by":"publisher","first-page":"969","DOI":"10.1038\/s41929-020-00528-3","article-title":"Advances\nin supramolecular host-mediated reactivity","volume":"3","author":"Morimoto","year":"2020","journal-title":"Nat. Catal."},{"issue":"67","key":"2026080511102656400_cit27","doi-asserted-by":"publisher","first-page":"15446","DOI":"10.1002\/chem.202003897","article-title":"Cucurbit n\nurils for\nSupramolecular Catalysis","volume":"26","author":"Tang","year":"2020","journal-title":"Chem. - Eur. J."},{"issue":"6","key":"2026080511102656400_cit28","doi-asserted-by":"publisher","first-page":"625","DOI":"10.1021\/acsmacrolett.7b00343","article-title":"Photocontrolled RAFT\nPolymerization Mediated by a Supramolecular Catalyst","volume":"6","author":"Shen","year":"2017","journal-title":"ACS Macro Lett."},{"issue":"22","key":"2026080511102656400_cit29","doi-asserted-by":"publisher","first-page":"2801","DOI":"10.1039\/C9PY00393B","article-title":"Visible light induced\naqueous RAFT polymerization using a supramolecular\nperylene diimide\/cucurbit[7]uril complex","volume":"10","author":"Yang","year":"2019","journal-title":"Polym.\nChem."},{"issue":"4","key":"2026080511102656400_cit30","doi-asserted-by":"publisher","first-page":"433","DOI":"10.1021\/acsmacrolett.1c00046","article-title":"PET-RAFT Polymerization: Mechanistic Perspectives for\nFuture Materials","volume":"10","author":"Allegrezza","year":"2021","journal-title":"ACS Macro Lett."},{"issue":"2","key":"2026080511102656400_cit31","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202522611","article-title":"Triplet-Enhanced Photoiniferter\nPolymerization: Ultrafast,\nOxygen-Tolerant, and Biocompatible Synthesis of Well-Defined Polymers\nUnder Visible Light","volume":"138","author":"Tang","year":"2026","journal-title":"Angew. Chem. Int. Ed."},{"issue":"19","key":"2026080511102656400_cit32","doi-asserted-by":"publisher","DOI":"10.1002\/anie.4018657","article-title":"Ultrafast Synthesis of Ultrahigh Molecular Weight Degradable Semifluorinated\nCopolymers via Triplet-Enhanced Photoiniferter Polymerization","volume":"65","author":"Tang","year":"2026","journal-title":"Angew. Chem. Int. Ed."},{"issue":"22","key":"2026080511102656400_cit33","doi-asserted-by":"publisher","first-page":"12320","DOI":"10.1021\/acs.chemrev.5b00341","article-title":"Cucurbituril-Based Molecular Recognition","volume":"115","author":"Barrow","year":"2015","journal-title":"Chem. Rev."},{"issue":"1","key":"2026080511102656400_cit34","doi-asserted-by":"publisher","first-page":"2100514","DOI":"10.1002\/marc.202100514","article-title":"Photo-Iniferter\nRAFT Polymerization","volume":"43","author":"Hartlieb","year":"2022","journal-title":"Macromol. Rapid Commun."},{"key":"2026080511102656400_cit35","doi-asserted-by":"publisher","first-page":"101871","DOI":"10.1016\/j.progpolymsci.2024.101871","article-title":"Photoiniferter polymerization:\nIlluminating the history, ascendency, and renaissance","volume":"156","author":"Hughes","year":"2024","journal-title":"Prog. Polym. Sci."},{"issue":"5","key":"2026080511102656400_cit36","doi-asserted-by":"publisher","first-page":"1093","DOI":"10.11777\/j.issn1000-3304.2026.25326","article-title":"Visible\nLight Photoiniferter Polymerization","volume":"57","author":"Meng","year":"2026","journal-title":"ACTA Polymerica\nSinica"},{"issue":"10","key":"2026080511102656400_cit37","doi-asserted-by":"publisher","first-page":"3570","DOI":"10.1021\/ja109904u","article-title":"New Ultrahigh Affinity Host\u2013Guest\nComplexes of Cucurbit[7]uril with Bicyclo[2.2.2]octane and Adamantane\nGuests: Thermodynamic Analysis and Evaluation of M2 Affinity Calculations","volume":"133","author":"Moghaddam","year":"2011","journal-title":"J. Am. Chem. Soc."},{"issue":"7","key":"2026080511102656400_cit38","doi-asserted-by":"publisher","first-page":"2256","DOI":"10.1021\/ma020882h","article-title":"Thiocarbonylthio\nCompounds [SC(Ph)S\u2013R]\nin Free Radical Polymerization with Reversible Addition-Fragmentation\nChain Transfer (RAFT Polymerization). Role of the Free-Radical Leaving\nGroup (R)","volume":"36","author":"Chong","year":"2003","journal-title":"Macromolecules"},{"issue":"7","key":"2026080511102656400_cit39","doi-asserted-by":"publisher","first-page":"2273","DOI":"10.1021\/ma020883+","article-title":"Thiocarbonylthio Compounds (SC(Z)S\u2013R)\nin Free Radical Polymerization with Reversible Addition-Fragmentation\nChain Transfer (RAFT Polymerization). Effect of the Activating Group\nZ","volume":"36","author":"Chiefari","year":"2003","journal-title":"Macromolecules"},{"issue":"16","key":"2026080511102656400_cit40","doi-asserted-by":"publisher","first-page":"5559","DOI":"10.1021\/ma9804951","article-title":"Living Free-Radical\nPolymerization by Reversible Addition\u2013Fragmentation Chain Transfer:\nThe RAFT Process","volume":"31","author":"Chiefari","year":"1998","journal-title":"Macromolecules"},{"issue":"42","key":"2026080511102656400_cit41","doi-asserted-by":"publisher","first-page":"17769","DOI":"10.1021\/jacs.1c08654","article-title":"Ubiquitous Nature of Rate Retardation\nin Reversible Addition\u2013Fragmentation Chain Transfer Polymerization","volume":"143","author":"Bradford","year":"2021","journal-title":"J. Am. Chem. Soc."},{"issue":"3","key":"2026080511102656400_cit42","doi-asserted-by":"publisher","first-page":"350","DOI":"10.1021\/acsmacrolett.0c00043","article-title":"100th Anniversary\nof Macromolecular Science Viewpoint: Achieving Ultrahigh Molecular\nWeights with Reversible Deactivation Radical Polymerization","volume":"9","author":"An","year":"2020","journal-title":"ACS Macro Lett."},{"issue":"6080","key":"2026080511102656400_cit43","doi-asserted-by":"publisher","first-page":"434","DOI":"10.1126\/science.1215368","article-title":"Multiblock\nPolymers: Panacea or Pandora\u2019s Box?","volume":"336","author":"Bates","year":"2012","journal-title":"Science"},{"issue":"7","key":"2026080511102656400_cit44","doi-asserted-by":"publisher","first-page":"1271","DOI":"10.1039\/C9PY01571J","article-title":"Synthetic approaches for multiblock copolymers","volume":"11","author":"Beyer","year":"2020","journal-title":"Polym. Chem."},{"issue":"10","key":"2026080511102656400_cit45","doi-asserted-by":"publisher","first-page":"3438","DOI":"10.1039\/D2CS00115B","article-title":"Multiblock\ncopolymer synthesis via RAFT emulsion polymerization","volume":"52","author":"Clothier","year":"2023","journal-title":"Chem. Soc. Rev."},{"issue":"48","key":"2026080511102656400_cit46","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202314729","article-title":"Visible Light\nPhotoiniferter Polymerization\nfor Dispersity Control in High Molecular Weight Polymers","volume":"62","author":"Ma","year":"2023","journal-title":"Angew. Chem., Int. Ed. Engl."},{"issue":"10","key":"2026080511102656400_cit47","doi-asserted-by":"publisher","first-page":"3451","DOI":"10.1021\/ma402435n","article-title":"Pushing the Limit of\nthe RAFT Process: Multiblock Copolymers by One-Pot Rapid Multiple\nChain Extensions at Full Monomer Conversion","volume":"47","author":"Gody","year":"2014","journal-title":"Macromolecules"},{"issue":"27","key":"2026080511102656400_cit48","doi-asserted-by":"publisher","first-page":"4875","DOI":"10.1039\/C5PY00478K","article-title":"Preparation\nof complex multiblock\ncopolymers via aqueous RAFT polymerization at room temperature","volume":"6","author":"Martin","year":"2015","journal-title":"Polym. Chem."},{"issue":"8","key":"2026080511102656400_cit49","doi-asserted-by":"publisher","first-page":"989","DOI":"10.1021\/acsmacrolett.9b00534","article-title":"Exploitation\nof the Nanoreactor Concept\nfor Efficient Synthesis of Multiblock Copolymers via MacroRAFT-Mediated\nEmulsion Polymerization","volume":"8","author":"Clothier","year":"2019","journal-title":"ACS Macro Lett."},{"issue":"2","key":"2026080511102656400_cit50","doi-asserted-by":"publisher","first-page":"736","DOI":"10.1021\/acs.macromol.0c02415","article-title":"RAFT Emulsion Polymerization for (Multi)block Copolymer\nSynthesis: Overcoming the Constraints of Monomer Order","volume":"54","author":"Khan","year":"2021","journal-title":"Macromolecules"},{"issue":"13","key":"2026080511102656400_cit51","doi-asserted-by":"publisher","first-page":"5019","DOI":"10.1039\/D4SC00399C","article-title":"Enhanced synthesis\nof multiblock\ncopolymers via acid-triggered RAFT polymerization","volume":"15","author":"Antonopoulou","year":"2024","journal-title":"Chem. Sci."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c05797","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/30\/31967\/66069747\/jacs.6c05797.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/30\/31967\/66069747\/jacs.6c05797.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T15:23:35Z","timestamp":1785943415000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/30\/31967\/5222702\/Supramolecular-Modulation-of-Controlled-Radical"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,20]]},"references-count":51,"journal-issue":{"issue":"30","published-online":{"date-parts":[[2026,7,20]]},"published-print":{"date-parts":[[2026,8,5]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c05797","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,20]]}}}