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In this work, we demonstrate a novel approach in which the intrinsic electric field within a break junction nanocavity triggers and probes a substrate-selective, multistep cis-azobenzene diborylation reaction in the dark at the single-molecule level under ambient conditions. Our results combine the key aspects of electric field catalysis and substrate recognition to drive reactions in a nanoscale confined environment. The study further demonstrates how the reactivity landscape for the \u201cN\u2550N\u201d bond functionalization and borylation reactions can be tuned by an oriented external electrical field present within a nanometallic junction, opening a new avenue in borylation chemistry. Furthermore, theoretical studies corroborate the experimental finding by revealing how the trans\u2013cis-azobenzene isomerization energy landscape can be reshaped in the presence of an electric field to facilitate a cis-azobenzene selective diborylation reaction without the aid of a metal catalyst or external light irradiation.<\/jats:p>","DOI":"10.1021\/jacs.6c05830","type":"journal-article","created":{"date-parts":[[2026,5,20]],"date-time":"2026-05-20T19:39:26Z","timestamp":1779305966000},"page":"24357-24366","source":"Crossref","is-referenced-by-count":1,"title":["Oriented\nElectric Field-Driven Cis-Azobenzene Selective\nDiborylation Reaction at the Single-Molecule Level"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-8009-5825","authenticated-orcid":true,"given":"PA","family":"Sreelakshmi","sequence":"first","affiliation":[{"name":"Indian Institute of Science , , ,","place":["Bangalore, India, 560012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Reetu Rani","family":"Mondal","sequence":"additional","affiliation":[{"name":"Indian Institute of Science , , ,","place":["Bangalore, India, 560012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laust","family":"Rask","sequence":"additional","affiliation":[{"name":"University of Copenhagen , , Universitetsparken 5 , ,","place":["Copenhagen \u00d8, Denmark, 2100"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5437-2729","authenticated-orcid":true,"given":"Susanne","family":"Leitherer","sequence":"additional","affiliation":[{"name":"University of Copenhagen , , Universitetsparken 5 , ,","place":["Copenhagen \u00d8, Denmark, 2100"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Oscar Berlin","family":"Obel","sequence":"additional","affiliation":[{"name":"University of Copenhagen , , Universitetsparken 5 , ,","place":["Copenhagen \u00d8, Denmark, 2100"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6583-061X","authenticated-orcid":true,"given":"Umar","family":"Rashid","sequence":"additional","affiliation":[{"name":"Indian Institute of Science , , ,","place":["Bangalore, India, 560012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9024-4636","authenticated-orcid":true,"given":"Joseph M.","family":"Hamill","sequence":"additional","affiliation":[{"name":"University of Copenhagen , , Universitetsparken 5 , ,","place":["Copenhagen \u00d8, Denmark, 2100"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4090-7697","authenticated-orcid":true,"given":"Kurt V.","family":"Mikkelsen","sequence":"additional","affiliation":[{"name":"University of Copenhagen , , Universitetsparken 5 , ,","place":["Copenhagen \u00d8, Denmark, 2100"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2064-1297","authenticated-orcid":true,"given":"K.","family":"Geetharani","sequence":"additional","affiliation":[{"name":"Indian Institute of Science , , ,","place":["Bangalore, India, 560012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4361-741X","authenticated-orcid":true,"given":"Veerabhadrarao","family":"Kaliginedi","sequence":"additional","affiliation":[{"name":"Indian Institute of Science , , ,","place":["Bangalore, India, 560012"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,5,20]]},"reference":[{"issue":"2","key":"2026073023181859400_cit1","doi-asserted-by":"publisher","first-page":"98","DOI":"10.1073\/pnas.44.2.98","article-title":"Application\nof a Theory of Enzyme Specificity to Protein Synthesis","volume":"44","author":"Koshland","year":"1958","journal-title":"Proc. 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