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However, the construction of such materials is still extremely incidental and lacks a fine control. Herein, we develop a unique strategy using three-dimensional nanographenes with tunable bulky configurations to adaptively fabricate a series of noncovalent porous crystals. Stereospecific nanographenes with either unilateral or bilateral curved [1,4]diazocine domains are obtained by Scholl cyclization of tetracarbazole precursors bearing diverse substituents. Leveraging the multiple intrinsic concavities variably constructed by the rigid octagons and flexible carbazole groups, these nanographenes readily self-assemble into noncovalent porous crystals featuring straight one-dimensional, zigzag one-dimensional, or interconnected two-dimensional channels. Interestingly, coassembly with other aromatic derivatives such as pyrene further facilitates the construction of porous cocrystals from porosity-absent building blocks. Moreover, upon coassembly with fullerenes, the long-range charge-transfer interactions endow the resulting porous cocrystals with conducting properties.<\/jats:p>","DOI":"10.1021\/jacs.6c06132","type":"journal-article","created":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T08:16:01Z","timestamp":1785140161000},"source":"Crossref","is-referenced-by-count":0,"title":["Adaptive Fabrication\nof Porous Crystals through Multiple-Site\nNoncovalent Conjunction of [1,4]Diazocine-Embedded Three-Dimensionally\nConcave Nanographenes"],"prefix":"10.1021","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-9200-7740","authenticated-orcid":true,"given":"Guoli","family":"Zhang","sequence":"first","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fuwei","family":"Gan","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2422-3922","authenticated-orcid":true,"given":"Chengshuo","family":"Shen","sequence":"additional","affiliation":[{"name":"Zhejiang Sci-Tech University , , ,","place":["Hangzhou, China, 310018"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4699-6558","authenticated-orcid":true,"given":"Huibin","family":"Qiu","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,27]]},"reference":[{"key":"2026080409061414800_cit1","doi-asserted-by":"publisher","first-page":"22697","DOI":"10.1002\/anie.202010829","article-title":"Colyliform crystalline\n2D covalent organic frameworks (COFs) with quasi-3D topologies for\nrapid I2 adsorption","volume":"59","author":"Guo","year":"2020","journal-title":"Angew. 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Sci."},{"key":"2026080409061414800_cit32","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216193","article-title":"Helical bilayer nonbenzenoid nanographene bearing a\n[10]helicene with two embedded heptagons","volume":"62","author":"Yang","year":"2023","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026080409061414800_cit33","doi-asserted-by":"publisher","first-page":"27324","DOI":"10.1021\/jacs.4c09185","article-title":"A negatively curved nanographene\nwith four embedded heptagons","volume":"146","author":"Elbert","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"2026080409061414800_cit34","doi-asserted-by":"publisher","first-page":"7279","DOI":"10.1021\/acs.orglett.4c02093","article-title":"W-shaped \u03c0-extended double\nundecabenzo[7]helicene","volume":"26","author":"Shen","year":"2024","journal-title":"Org. Lett."},{"key":"2026080409061414800_cit35","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202501169","article-title":"A key fragment\nin carbon schwarzite unit cells and its triple [6]helicene precursor","volume":"137","author":"Yang","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026080409061414800_cit36","doi-asserted-by":"publisher","first-page":"7009","DOI":"10.1021\/acs.orglett.5c01902","article-title":"\u03c0-Truncation of a parent nanographene: chirally\ntwisted green fluorophores","volume":"27","author":"Meng","year":"2025","journal-title":"Org. Lett."},{"key":"2026080409061414800_cit37","doi-asserted-by":"publisher","first-page":"5952","DOI":"10.1021\/jacs.2c13823","article-title":"[1,4]Diazocine-embedded\nelectron-rich nanographenes with cooperatively dynamic skeletons","volume":"145","author":"Gan","year":"2023","journal-title":"J. Am. Chem. 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