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Here, we demonstrate that N\u2013H species on Mo-based catalysts enable this transformation efficiently. Unlike conventional batch processes by homogeneous catalysts that rely on ammonia or strong reductants, our scalable flow system achieves direct N2-to-amine conversion using commercial Mo, MoO2, and MoO3 with various alcohols (MeOH, EtOH, and n-PrOH), demonstrating broad applicability. Remarkably, the Mo catalysts exhibit exceptional low-temperature activity (&amp;gt;95% conversion at 225 \u00b0C), reducing the operating temperature by \u223c100 \u00b0C compared to industrial mordenite (MOR) catalysts. Mechanistic studies reveal NHx species as key intermediates, with the reaction proceeding via sequential nitrogen hydrogenation and alkylation. This strategy, combining efficient N2 utilization with a continuous flow design, meets industrial practicality and offers a promising scalable route to amine synthesis.<\/jats:p>","DOI":"10.1021\/jacs.6c06260","type":"journal-article","created":{"date-parts":[[2026,6,4]],"date-time":"2026-06-04T07:40:16Z","timestamp":1780558816000},"page":"24395-24404","source":"Crossref","is-referenced-by-count":0,"title":["Mo-Catalyzed Direct\nNitrogen-to-Amine Conversion in\nFlow via Active N\u2013H Species"],"prefix":"10.1021","volume":"148","author":[{"given":"Kailong","family":"Qian","sequence":"first","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyi","family":"He","sequence":"additional","affiliation":[{"name":"Institute of Science Tokyo , , ,","place":["Yokohama, Japan, 226-8503"]},{"name":"Kanagawa Institute of Industrial Science and Technology , 705-1 Shimoimaizumi , , ,","place":["Ebina, Kanagawa, Japan, 243-0435"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2084-9549","authenticated-orcid":true,"given":"Yangfan","family":"Lu","sequence":"additional","affiliation":[{"name":"Chongqing University , , ,","place":["Chongqing, China, 400045"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaojun","family":"Lu","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zichuang","family":"Li","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen-Qian","family":"Li","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruoqian","family":"Jiang","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sijia","family":"Zheng","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaqi","family":"Wang","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang","family":"Liu","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2593-7487","authenticated-orcid":true,"given":"Takayoshi","family":"Katase","sequence":"additional","affiliation":[{"name":"Institute of Science Tokyo , , ,","place":["Yokohama, Japan, 226-8503"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1233-7746","authenticated-orcid":true,"given":"Jie-Sheng","family":"Chen","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9039-8232","authenticated-orcid":true,"given":"Tian-Nan","family":"Ye","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,6,4]]},"reference":[{"key":"2026073023181101600_cit1","doi-asserted-by":"publisher","first-page":"61","DOI":"10.1038\/35083537","article-title":"A possible nitrogen crisis for archaean\nlife due to reduced nitrogen fixation by lightning","volume":"412","author":"Navarro-Gonza\u0301lez","year":"2001","journal-title":"Nature"},{"key":"2026073023181101600_cit2","doi-asserted-by":"publisher","first-page":"4919","DOI":"10.1021\/acs.chemrev.0c00361","article-title":"Introduction:\nReactivity of nitrogen from the ground to the atmosphere","volume":"120","author":"Holland","year":"2020","journal-title":"Chem. 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