{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T15:03:12Z","timestamp":1784732592457,"version":"3.55.0"},"reference-count":83,"publisher":"American Chemical Society (ACS)","issue":"28","license":[{"start":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T00:00:00Z","timestamp":1783641600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T00:00:00Z","timestamp":1783641600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T00:00:00Z","timestamp":1783641600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2026,7,22]]},"DOI":"10.1021\/jacs.6c06473","type":"journal-article","created":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T20:56:32Z","timestamp":1783716992000},"page":"30083-30095","source":"Crossref","is-referenced-by-count":0,"title":["The Role of Ligand Dearomatization for Metal\u2013Ligand Cooperation in Mn(I)-Catalyzed Hydrophosphination"],"prefix":"10.1021","volume":"148","author":[{"given":"Esther G.","family":"Sinnema","sequence":"first","affiliation":[{"name":"Stratingh Institute for Chemistry","place":["Groningen, The Netherlands"]},{"name":"University of Groningen","place":["Groningen, The Netherlands"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jan L.","family":"Sneep","sequence":"additional","affiliation":[{"name":"Stratingh Institute for Chemistry","place":["Groningen, The Netherlands"]},{"name":"University of Groningen","place":["Groningen, The Netherlands"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4204-3474","authenticated-orcid":true,"given":"Marta","family":"Casti\u00f1eira Reis","sequence":"additional","affiliation":[{"name":"Centro Singular de Investigaci\u00f3n en Qu\u00edmica Biol\u00f3xica e Materiais Moleculares (CIQUS), C\/Jenaro de la Fuente s\/n, Campus Vida","place":["Santiago de Compostela, Spain"]},{"name":"Universidade de Santiago de Compostela","place":["Santiago de Compostela, Spain"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pieter","family":"van der Meulen","sequence":"additional","affiliation":[{"name":"Stratingh Institute for Chemistry","place":["Groningen, The Netherlands"]},{"name":"University of Groningen","place":["Groningen, The Netherlands"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Folkert","family":"de Vries","sequence":"additional","affiliation":[{"name":"Stratingh Institute for Chemistry","place":["Groningen, The Netherlands"]},{"name":"University of Groningen","place":["Groningen, The Netherlands"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2411-1250","authenticated-orcid":true,"given":"Syuzanna R.","family":"Harutyunyan","sequence":"additional","affiliation":[{"name":"Stratingh Institute for Chemistry","place":["Groningen, The Netherlands"]},{"name":"University of Groningen","place":["Groningen, The Netherlands"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,10]]},"reference":[{"key":"ref1\/cit1a","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00031B"},{"key":"ref1\/cit1b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00081"},{"key":"ref1\/cit1c","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60302D"},{"key":"ref1\/cit1d","unstructured":"dB\u00f6rner, A., Ed.\n                      Phosphorus Ligands in Asymmetric Catalysis: Synthesis and Applications\n                      ; Wiley-VCH, Weinheim, Germany, 2008; pp 1\u20131546."},{"key":"ref1\/cit1e","doi-asserted-by":"crossref","first-page":"239","DOI":"10.1007\/978-1-4613-3623-5_7","volume-title":"Homogeneous Catalysis with Metal Phosphine Complexes","author":"Rauchfuss T. B.","year":"1983"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202200988"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201602749"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1021\/cs400685c"},{"key":"ref2\/cit2d","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03144"},{"key":"ref2\/cit2e","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.01.006"},{"key":"ref2\/cit2f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.0c00667"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1021\/om990882e"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc00925c"},{"key":"ref3\/cit3c","doi-asserted-by":"publisher","DOI":"10.1021\/ol202480r"},{"key":"ref3\/cit3d","doi-asserted-by":"publisher","DOI":"10.1021\/ol2024339"},{"key":"ref3\/cit3e","doi-asserted-by":"publisher","DOI":"10.1021\/ol401560q"},{"key":"ref3\/cit3f","doi-asserted-by":"publisher","DOI":"10.1021\/ol402351c"},{"key":"ref3\/cit3g","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC01610F"},{"key":"ref3\/cit3h","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201406298"},{"key":"ref3\/cit3i","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC00763E"},{"key":"ref3\/cit3j","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201801061"},{"key":"ref3\/cit3k","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b04787"},{"key":"ref3\/cit3l","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.0c00783"},{"key":"ref3\/cit3m","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2022.08.008"},{"key":"ref3\/cit3n","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.3c02031"},{"key":"ref3\/cit3o","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c02772"},{"key":"ref3\/cit3p","doi-asserted-by":"publisher","DOI":"10.1021\/ja0449574"},{"key":"ref3\/cit3q","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218798"},{"key":"ref3\/cit3r","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202306511"},{"key":"ref3\/cit3s","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112860"},{"key":"ref3\/cit3t","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c19022"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10756"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC06694C"},{"key":"ref4\/cit4c","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adf8742"},{"key":"ref4\/cit4d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.2c04256"},{"key":"ref4\/cit4e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202316785"},{"key":"ref4\/cit4f","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202415623"},{"key":"ref4\/cit4g","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c16130"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1021\/ja100606v"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(02)01808-9"},{"key":"ref5\/cit5c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c09654"},{"key":"ref5\/cit5d","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2022.08.019"},{"key":"ref5\/cit5e","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC06950D"},{"key":"ref5\/cit5f","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201916076"},{"key":"ref5\/cit5g","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2013.10.158"},{"key":"ref5\/cit5h","doi-asserted-by":"publisher","DOI":"10.1021\/om201115n"},{"key":"ref5\/cit5i","doi-asserted-by":"publisher","DOI":"10.1021\/om300405h"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1021\/ja0555163"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201301417"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1039\/b212408d"},{"key":"ref6\/cit6d","doi-asserted-by":"publisher","DOI":"10.1055\/s-2003-42092"},{"key":"ref7\/cit7a","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00998J"},{"key":"ref7\/cit7b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201503873"},{"key":"ref7\/cit7c","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00509F"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-018-0049-z"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03540"},{"key":"ref8\/cit8c","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b01791"},{"key":"ref8\/cit8d","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT00476H"},{"key":"ref8\/cit8e","doi-asserted-by":"publisher","DOI":"10.1021\/ja411374j"},{"key":"ref8\/cit8f","doi-asserted-by":"publisher","DOI":"10.1021\/ja3097674"},{"key":"ref8\/cit8g","doi-asserted-by":"publisher","DOI":"10.1021\/om050433g"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.6b00408"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1039\/C9CY01601E"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702406"},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC02598D"},{"key":"ref10\/cit10d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.3c00399"},{"key":"ref10\/cit10e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b00864"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201405295"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b02505"},{"key":"ref11\/cit11c","doi-asserted-by":"publisher","DOI":"10.1021\/ar700134q"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b01729"},{"key":"ref12\/cit12b","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201700042"},{"key":"ref12\/cit12c","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201605218"},{"key":"ref12\/cit12d","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201607233"},{"key":"ref12\/cit12e","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b03709"},{"key":"ref13\/cit13a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c01683"},{"key":"ref13\/cit13b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c13113"},{"key":"ref13\/cit13c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c00362"},{"key":"ref14\/cit14","doi-asserted-by":"publisher","DOI":"10.1021\/ja030272c"},{"key":"ref15\/cit15a","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC04698K"},{"key":"ref15\/cit15b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201609757"},{"key":"ref15\/cit15c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462544"},{"key":"ref15\/cit15d","doi-asserted-by":"publisher","DOI":"10.1021\/jo052409i"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c06473","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c06473","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T14:30:29Z","timestamp":1784730629000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.6c06473"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,10]]},"references-count":83,"journal-issue":{"issue":"28","published-print":{"date-parts":[[2026,7,22]]}},"alternative-id":["10.1021\/jacs.6c06473"],"URL":"https:\/\/doi.org\/10.1021\/jacs.6c06473","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,10]]}}}