{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T15:21:20Z","timestamp":1786548080971,"version":"build-2736575974"},"reference-count":55,"publisher":"American Chemical Society (ACS)","issue":"31","license":[{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE-SC0024141"],"award-info":[{"award-number":["DE-SC0024141"]}],"id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006132","name":"Office of Science","doi-asserted-by":"publisher","award":["DE-SC0012704"],"award-info":[{"award-number":["DE-SC0012704"]}],"id":[{"id":"10.13039\/100006132","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-SC0024141"],"award-info":[{"award-number":["DE-SC0024141"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100015599","name":"Toyota Research Institute","doi-asserted-by":"publisher","award":["PO-002332"],"award-info":[{"award-number":["PO-002332"]}],"id":[{"id":"10.13039\/100015599","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000781","name":"European Research Council","doi-asserted-by":"publisher","award":["101106377"],"award-info":[{"award-number":["101106377"]}],"id":[{"id":"10.13039\/501100000781","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001711","name":"Schweizerischer Nationalfonds zur F?rderung der Wissenschaftlichen Forschung","doi-asserted-by":"publisher","award":["200021_188536"],"award-info":[{"award-number":["200021_188536"]}],"id":[{"id":"10.13039\/501100001711","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"Swiss National Science Foundation","doi-asserted-by":"publisher","award":["238600"],"award-info":[{"award-number":["238600"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"UK Research and Innovation","doi-asserted-by":"publisher","award":["EP\/Y023447\/1"],"award-info":[{"award-number":["EP\/Y023447\/1"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Defect engineering in Zr-based metal\u2013organic frameworks (Zr-MOFs) has focused primarily on missing-linker defects. However, recent studies suggest that node dehydroxylation\u2013which creates distortions and coordinatively unsaturated Zr sites (Zrcus)\u2013may have a more significant impact on properties. The present work uses pair distribution function (PDF) and thermogravimetric analysis coupled with systematic defect manipulation to study the effect of node dehydroxylation and missing-linker defects in UiO-66. By employing rapid heat treatment (RHT) under humid flow, we tracked the transition from high-symmetry [Zr6O4(OH)4]12+ to distorted [Zr6O6]12+ nodes. This structural evolution significantly improves As(V) uptake, whereas increasing the number of missing linkers\u2013via chemical treatment or RHT of mixed-ligand frameworks\u2013fails to enhance performance. Crucially, our detection of distorted nodes in as-synthesized UiO-66 also raises the possibility that these defects were silently present in many earlier studies that span various applications, where their role in governing performance may have been inadvertently overlooked. The present study challenges the prevailing \u201cmissing-linker\u201d paradigm and establishes cluster dehydroxylation as a defect-engineering strategy to enhance Lewis-acidic performance in Zr-MOFs.<\/jats:p>","DOI":"10.1021\/jacs.6c06764","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:23:27Z","timestamp":1785849807000},"page":"33229-33242","source":"Crossref","is-referenced-by-count":0,"title":["Node\nDistortions as a Means of Defect Engineering\nin Zr-Based MOFs"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4989-5821","authenticated-orcid":true,"given":"Till","family":"Schertenleib","sequence":"first","affiliation":[{"name":"E\u0301cole Polytechnique Fe\u0301de\u0301rale de Lausanne (EPFL) , , ,","place":["Sion, Switzerland, 1950"]},{"name":"University of Copenhagen , , ,","place":["Copenhagen, Denmark, 2100"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Timo M. O.","family":"Felder","sequence":"additional","affiliation":[{"name":"E\u0301cole Polytechnique Fe\u0301de\u0301rale de Lausanne (EPFL) , , ,","place":["Sion, Switzerland, 1950"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nazanin","family":"Taheri","sequence":"additional","affiliation":[{"name":"E\u0301cole Polytechnique Fe\u0301de\u0301rale de Lausanne (EPFL) , , ,","place":["Sion, Switzerland, 1950"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Shi","sequence":"additional","affiliation":[{"name":"E\u0301cole Polytechnique Fe\u0301de\u0301rale de Lausanne (EPFL) , , ,","place":["Sion, Switzerland, 1950"]},{"name":"Northeastern University , , ,","place":["Shenyang, China, 110819"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tanaporn","family":"Na Narong","sequence":"additional","affiliation":[{"name":"Columbia University , , , ,","place":["New York, New York, United States, 10027"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5427-1610","authenticated-orcid":true,"given":"Mehrdad","family":"Asgari","sequence":"additional","affiliation":[{"name":"University of Cambridge , , ,","place":["Cambridge, U.K., CB3 0AS"]},{"name":"University of Cambridge , , Lady Margaret Rd , ,","place":["Cambridge, U.K., CB3 0BU"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-8774-2810","authenticated-orcid":true,"given":"Pattaraphon","family":"Rodlamul","sequence":"additional","affiliation":[{"name":"E\u0301cole Polytechnique Fe\u0301de\u0301rale de Lausanne (EPFL) , , ,","place":["Sion, Switzerland, 1950"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Simon J. L.","family":"Billinge","sequence":"additional","affiliation":[{"name":"Columbia University , , , ,","place":["New York, New York, United States, 10027"]},{"name":"University of California, Santa Barbara , , , ,","place":["Santa Barbara, California, United States, 93106"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8375-2341","authenticated-orcid":true,"given":"Wendy L.","family":"Queen","sequence":"additional","affiliation":[{"name":"E\u0301cole Polytechnique Fe\u0301de\u0301rale de Lausanne (EPFL) , , ,","place":["Sion, Switzerland, 1950"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,30]]},"reference":[{"key":"2026081210100983700_cit1","doi-asserted-by":"publisher","first-page":"1347","DOI":"10.1021\/acs.cgd.9b00955","article-title":"A Decade of UiO-66 Research: A Historic Review of Dynamic\nStructure, Synthesis Mechanisms, and Characterization Techniques of\nan Archetypal Metal\u2212Organic Framework","volume":"20","author":"Winarta","year":"2020","journal-title":"Cryst. Growth Des."},{"key":"2026081210100983700_cit2","doi-asserted-by":"publisher","first-page":"1231","DOI":"10.1021\/cg301691d","article-title":"Zr- and Hf-Based Metal\u2212Organic\nFrameworks: Tracking Down the Polymorphism","volume":"13","author":"Bon","year":"2013","journal-title":"Cryst. Growth Des."},{"key":"2026081210100983700_cit3","doi-asserted-by":"publisher","first-page":"149","DOI":"10.1002\/anie.201409334","article-title":"A Highly\nStable Zeotype Mesoporous Zirconium Metal\u2212Organic Framework\nwith Ultralarge Pores","volume":"54","author":"Feng","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081210100983700_cit4","doi-asserted-by":"publisher","first-page":"10453","DOI":"10.1002\/ange.201204475","article-title":"Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal\u2212Organic\nFrameworks with Ultrahigh Stability as Biomimetic Catalysts","volume":"124","author":"Feng","year":"2012","journal-title":"Angew. Chem."},{"key":"2026081210100983700_cit5","doi-asserted-by":"publisher","first-page":"944","DOI":"10.1038\/nchem.834","article-title":"De Novo Synthesis of a Metal\u2212Organic Framework\nMaterial Featuring Ultrahigh Surface Area and Gas Storage Capacities","volume":"2","author":"Farha","year":"2010","journal-title":"Nat. Chem."},{"key":"2026081210100983700_cit6","doi-asserted-by":"publisher","first-page":"213886","DOI":"10.1016\/j.ccr.2021.213886","article-title":"The Forgotten Chemistry of Group(IV)\nMetals: A Survey on the Synthesis, Structure, and Properties of Discrete\nZr(IV), Hf(IV), and Ti(IV) Oxo Clusters","volume":"438","author":"Zhang","year":"2021","journal-title":"Coord.\nChem. Rev."},{"key":"2026081210100983700_cit7","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202215595","article-title":"Simple, Transition\nMetal Catalyst-Free Method for the\nDesign of Complex Organic Building Blocks Used to Construct Porous\nMetal\u2212Organic Frameworks","volume":"135","author":"Kochetygov","year":"2023","journal-title":"Angew. Chem."},{"key":"2026081210100983700_cit8","doi-asserted-by":"publisher","first-page":"1521","DOI":"10.1039\/C0CC03038D","article-title":"An Amino -Modified\nZr-terephthalate Metal\u2212Organic Framework as an Acid\u2212Base\nCatalyst for Cross-Aldol Condensation","volume":"47","author":"Vermoortele","year":"2011","journal-title":"Chem.\nCommun."},{"key":"2026081210100983700_cit9","doi-asserted-by":"publisher","first-page":"7245","DOI":"10.1039\/C5CE01428J","article-title":"Metal\u2212Organic Frameworks for\nApplications in Remediation of Oxyanion\/Cation-Contaminated Water","volume":"17","author":"Howarth","year":"2015","journal-title":"CrystEngComm"},{"key":"2026081210100983700_cit10","doi-asserted-by":"publisher","first-page":"93","DOI":"10.1039\/C5DT04163E","article-title":"Extraction of Sulfate from Water\nUsing a Zr-metal\u2212Organic Framework","volume":"45","author":"Howarth A","year":"2016","journal-title":"Dalton\nTrans."},{"key":"2026081210100983700_cit11","doi-asserted-by":"publisher","first-page":"6140","DOI":"10.1039\/C8CE00992A","article-title":"Extraction of Inorganic Selenium\nfrom Water by a Zr Metal\u2212Organic Framework: Investigation of\nVolumetric Uptake Capacity and Binding Motifs","volume":"20","author":"Drout R. J","year":"2018","journal-title":"CrystEngComm"},{"key":"2026081210100983700_cit12","doi-asserted-by":"publisher","first-page":"1523","DOI":"10.1021\/acscentsci.0c00803","article-title":"The Surface Chemistry\nof Metal Oxide Clusters: From Metal\u2212Organic Frameworks to Minerals","volume":"6","author":"Yang","year":"2020","journal-title":"ACS Cent. Sci."},{"key":"2026081210100983700_cit13","doi-asserted-by":"publisher","first-page":"2902","DOI":"10.1016\/j.chempr.2020.09.010","article-title":"Strategies\nfor Pore Engineering in Zirconium Metal-Organic Frameworks","volume":"6","author":"Feng","year":"2020","journal-title":"Chem"},{"key":"2026081210100983700_cit14","doi-asserted-by":"publisher","first-page":"3174","DOI":"10.1021\/jacs.9b13070","article-title":"Engineering a Highly Defective Stable\nUiO-66 with Tunable Lewis- Br\u00f8nsted Acidity: The Role of the\nHemilabile Linker","volume":"142","author":"Feng","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210100983700_cit15","doi-asserted-by":"publisher","first-page":"622","DOI":"10.1038\/s41557-019-0263-4","article-title":"Imaging Defects and Their Evolution in a Metal\u2212Organic Framework\nat Sub-Unit-Cell Resolution","volume":"11","author":"Liu","year":"2019","journal-title":"Nat. Chem."},{"key":"2026081210100983700_cit16","doi-asserted-by":"publisher","first-page":"4176","DOI":"10.1038\/ncomms5176","article-title":"Correlated\nDefect Nanoregions in a Metal\u2212Organic Framework","volume":"5","author":"Cliffe","year":"2014","journal-title":"Nat. Commun."},{"key":"2026081210100983700_cit17","doi-asserted-by":"publisher","first-page":"60715","DOI":"10.1021\/acsami.1c13525","article-title":"Generating\nCatalytic Sites in UiO-66 through Defect Engineering","volume":"13","author":"Feng","year":"2021","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026081210100983700_cit18","doi-asserted-by":"publisher","first-page":"1700","DOI":"10.1021\/cm1022882","article-title":"Disclosing the Complex\nStructure of UiO-66 Metal Organic Framework: A Synergic Combination\nof Experiment and Theory","volume":"23","author":"Valenzano","year":"2011","journal-title":"Chem. Mater."},{"key":"2026081210100983700_cit19","doi-asserted-by":"publisher","first-page":"4178","DOI":"10.1021\/jacs.6b00069","article-title":"Structural Transitions\nof the Metal-Oxide Nodes within Metal\u2212Organic Frameworks: On\nthe Local Structures of NU-1000 and UiO-66","volume":"138","author":"Platero-Prats","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210100983700_cit20","doi-asserted-by":"publisher","first-page":"268","DOI":"10.1021\/jacs.2c09877","article-title":"Node Distortion\nas a Tunable Mechanism\nfor Negative Thermal Expansion in Metal\u2212Organic Frameworks","volume":"145","author":"Chen","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210100983700_cit21","doi-asserted-by":"publisher","first-page":"1852","DOI":"10.1107\/S1600576725006259","article-title":"Benchmarking\na Modern Laboratory-Based Powder Diffraction Instrument for in Situ\nStudies in Transmission Geometry","volume":"58","author":"Vornholt","year":"2025","journal-title":"J. Appl. Crystallogr."},{"key":"2026081210100983700_cit22","doi-asserted-by":"publisher","first-page":"102619","DOI":"10.1016\/j.chempr.2025.102619","article-title":"Anisotropic\nNode Distortions in Amorphous\nMOFs: Low-valent Zr Sites as Catalytic Hotspots","volume":"11","author":"Schertenleib","year":"2025","journal-title":"Chem"},{"key":"2026081210100983700_cit23","doi-asserted-by":"publisher","first-page":"22283","DOI":"10.1002\/anie.202110585","article-title":"Fabrication\nof Integrated Copper-Based\nNanoparticles\/Amorphous Metal\u2212Organic Framework by a Facile\nSpray-Drying Method: Highly Enhanced CO2 Hydrogenation Activity for\nMethanol Synthesis","volume":"60","author":"Mitsuka","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081210100983700_cit24","doi-asserted-by":"publisher","first-page":"110","DOI":"10.1016\/j.micromeso.2019.03.006","article-title":"Evolution\nof Acid and Basic Sites in UiO-66 and UiO-66-NH2Metal-Organic Frameworks:\nFTIR Study by Probe Molecules","volume":"281","author":"Chakarova","year":"2019","journal-title":"Microporous Mesoporous\nMater."},{"key":"2026081210100983700_cit25","doi-asserted-by":"publisher","first-page":"9295","DOI":"10.1021\/acs.jpclett.2c02468","article-title":"Structural and Acidic\nCharacteristics\nof Multiple Zr Defect Sites in UiO-66 Metal\u2212Organic Frameworks","volume":"13","author":"Peng","year":"2022","journal-title":"J. Phys. Chem. Lett."},{"key":"2026081210100983700_cit26","doi-asserted-by":"publisher","first-page":"8827","DOI":"10.1021\/acs.chemmater.3c00639","article-title":"Anomalous Infrared Intensity Behavior of Acetonitrile\nDiffused into UiO-67","volume":"35","author":"McDonnell","year":"2023","journal-title":"Chem. Mater."},{"key":"2026081210100983700_cit27","doi-asserted-by":"publisher","first-page":"5537","DOI":"10.1021\/ic800292e","article-title":"Synthesis\nand Structural Determination\nof a Hexanuclear Zirconium Glycine Compound Formed in Aqueous Solution","volume":"47","author":"Pan","year":"2008","journal-title":"Inorg. Chem."},{"key":"2026081210100983700_cit28","doi-asserted-by":"publisher","first-page":"5370","DOI":"10.1021\/cg501386j","article-title":"Detailed\nStructure Analysis of Atomic\nPositions and Defects in Zirconium Metal\u2212Organic Frameworks","volume":"14","author":"\u00d8ien","year":"2014","journal-title":"Cryst. Growth Des."},{"key":"2026081210100983700_cit29","doi-asserted-by":"publisher","first-page":"11162","DOI":"10.1002\/anie.201505461","article-title":"Definitive Molecular Level Characterization\nof Defects in UiO-66 Crystals","volume":"54","author":"Trickett","year":"2015","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026081210100983700_cit30","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202504713","article-title":"Determination of the\nExperimental Minimal Formula of Metal-Organic Frameworks","volume":"12","author":"Pulparayil Mathew","year":"2025","journal-title":"Advanced Science"},{"key":"2026081210100983700_cit31","doi-asserted-by":"publisher","first-page":"11465","DOI":"10.1021\/ja405078u","article-title":"Synthesis Modulation\nas a Tool To Increase the Catalytic\nActivity of Metal\u2212Organic Frameworks: The Unique Case of UiO-66(Zr)","volume":"135","author":"Vermoortele","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210100983700_cit32","doi-asserted-by":"publisher","first-page":"10527","DOI":"10.1039\/C8DT01247D","article-title":"Selective CO 2 Adsorption by a New\nMetal\u2212Organic Framework: Synergy between Open Metal Sites and\na Charged Imidazolinium Backbone","volume":"47","author":"Kochetygov","year":"2018","journal-title":"Dalton Trans."},{"key":"2026081210100983700_cit33","doi-asserted-by":"publisher","first-page":"2751","DOI":"10.1039\/C9CS00609E","article-title":"Coordinatively Unsaturated Metal\nSites (Open Metal Sites) in Metal\u2212Organic Frameworks: Design\nand Applications","volume":"49","author":"Ko\u0308kc\u0327am-Demir","year":"2020","journal-title":"Chem. Soc. Rev."},{"key":"2026081210100983700_cit34","doi-asserted-by":"publisher","first-page":"395","DOI":"10.1039\/C4CE01672F","article-title":"Active Site Engineering in UiO-66\nType Metal\u2212Organic Frameworks by Intentional Creation of Defects:\nA Theoretical Rationalization","volume":"17","author":"Vandichel","year":"2015","journal-title":"CrystEngComm"},{"key":"2026081210100983700_cit35","doi-asserted-by":"publisher","first-page":"13850","DOI":"10.1021\/ja8057953","article-title":"A New Zirconium Inorganic Building\nBrick Forming Metal Organic Frameworks with Exceptional Stability","volume":"130","author":"Cavka","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210100983700_cit36","doi-asserted-by":"publisher","first-page":"11342","DOI":"10.1021\/acs.inorgchem.2c01513","article-title":"Hydroxylation of UiO-66 Metal\u2212Organic Frameworks\nfor High Arsenic(III) Removal Efficiency","volume":"61","author":"Somjit","year":"2022","journal-title":"Inorg.\nChem."},{"key":"2026081210100983700_cit37","doi-asserted-by":"publisher","first-page":"8997","DOI":"10.1021\/acsanm.0c01696","article-title":"Defect Control\nin Zr-Based Metal\u2212Organic\nFramework Nanoparticles for Arsenic Removal from Water","volume":"3","author":"Assaad","year":"2020","journal-title":"ACS Appl. Nano Mater."},{"key":"2026081210100983700_cit38","doi-asserted-by":"publisher","first-page":"7870","DOI":"10.1039\/C9TA13747E","article-title":"Hierarchically Porous UiO-66 with Tunable Mesopores and Oxygen Vacancies\nfor Enhanced Arsenic Removal","volume":"8","author":"Xu","year":"2020","journal-title":"J. Mater. Chem.\nA"},{"key":"2026081210100983700_cit39","doi-asserted-by":"publisher","first-page":"9449","DOI":"10.1039\/c3cc46105j","article-title":"A Facile Synthesis\nof UiO-66, UiO-67 and Their Derivatives","volume":"49","author":"Katz","year":"2013","journal-title":"Chem.\nCommun."},{"key":"2026081210100983700_cit40","doi-asserted-by":"publisher","first-page":"3749","DOI":"10.1021\/acs.chemmater.6b00602","article-title":"Defect Engineering: Tuning the Porosity and Composition\nof the Metal\u2212Organic Framework UiO-66 via Modulated Synthesis","volume":"28","author":"Shearer","year":"2016","journal-title":"Chem. Mater."},{"key":"2026081210100983700_cit41","doi-asserted-by":"publisher","first-page":"16977","DOI":"10.1021\/jacs.4c05313","article-title":"Node Distortions\nin UiO-66 Inform Negative Thermal Expansion Mechanisms: Kinetic Effects,\nFrustration, and Lattice Hysteresis","volume":"146","author":"Vornholt","year":"2024","journal-title":"J. Am.\nChem. Soc."},{"key":"2026081210100983700_cit42","doi-asserted-by":"publisher","first-page":"10104","DOI":"10.1039\/C9TA00287A","article-title":"Characterization\nof the Adsorption Site Energies and Heterogeneous Surfaces of Porous\nMaterials","volume":"7","author":"Kumar","year":"2019","journal-title":"Journal of Materials Chemistry A"},{"key":"2026081210100983700_cit43","doi-asserted-by":"publisher","first-page":"2235","DOI":"10.1021\/acs.accounts.2c00262","article-title":"Hierarchically Porous MOFs Synthesized\nby Soft-Template Strategies","volume":"55","author":"Li","year":"2022","journal-title":"Acc. Chem. Res."},{"key":"2026081210100983700_cit44","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202501096","article-title":"Controllable Synthesis\nof Hierarchically Macro-, Meso-, and Microporous UiO-66 for Efficient\nCatalysis","volume":"9","author":"Li","year":"2025","journal-title":"Small Methods"},{"key":"2026081210100983700_cit45","doi-asserted-by":"publisher","first-page":"3299","DOI":"10.1021\/jacsau.5c00440","article-title":"Archetype Mesoporous UiO-66(Zr) Enabled\nby the Salt\u2212Oil Synergetic Mechanism","volume":"5","author":"Yang","year":"2025","journal-title":"JACS Au"},{"key":"2026081210100983700_cit46","doi-asserted-by":"publisher","first-page":"2102868","DOI":"10.1002\/adfm.202102868","article-title":"Near-Linear\nControllable\nSynthesis of Mesoporosity in Hierarchical UiO-66 by Template-Free\nNucleation-Competition","volume":"31","author":"Li","year":"2021","journal-title":"Adv. Funct. Mater."},{"key":"2026081210100983700_cit47","doi-asserted-by":"publisher","first-page":"223","DOI":"10.1016\/j.jcis.2018.12.065","article-title":"Exceptional Adsorption\nof Arsenic by Zirconium Metal-Organic Frameworks: Engineering Exploration\nand Mechanism Insight","volume":"539","author":"He","year":"2019","journal-title":"J. Colloid Interface\nSci."},{"key":"2026081210100983700_cit48","doi-asserted-by":"publisher","first-page":"122804","DOI":"10.1016\/j.molliq.2023.122804","article-title":"Theoretical Chemistry\nFramework to Unravel the Monolayer Adsorption of Geogenic Anions on\nUiO-66 and ZIF-8 Organometallic Structures","volume":"388","author":"Quintero-A\u0301lvarez","year":"2023","journal-title":"J. Mol. Liq."},{"key":"2026081210100983700_cit49","unstructured":"Yang, A.; et al.\n          Diffpy.Morph: Python Tools for Model Independent\nComparisons between\nSets of 1D Functions, 2026. https:\/\/arxiv.org\/abs\/2602.06987v3 (accessed May 20, 2026)."},{"key":"2026081210100983700_cit50","doi-asserted-by":"publisher","first-page":"2201502","DOI":"10.1002\/adma.202201502","article-title":"How Reproducible Are Surface Areas Calculated from\nthe BET Equation?","volume":"34","author":"Osterrieth","year":"2022","journal-title":"Adv. Mater."},{"key":"2026081210100983700_cit51","volume-title":"NIST Chemistry Webbook"},{"key":"2026081210100983700_cit52","doi-asserted-by":"publisher","first-page":"825","DOI":"10.1107\/S1600577516002411","article-title":"A New Multipurpose\nDiffractometer PILATUS@SNBL","volume":"23","author":"Dyadkin","year":"2016","journal-title":"J. Synchrotron\nRadiat."},{"key":"2026081210100983700_cit53","doi-asserted-by":"publisher","first-page":"560","DOI":"10.1107\/S0021889813005190","article-title":"PDFgetX3: A Rapid and Highly Automatable\nProgram for Processing Powder Diffraction\nData into Total Scattering Pair Distribution Functions","volume":"46","author":"Juha\u0301s","year":"2013","journal-title":"J. Appl. Crystallogr."},{"key":"2026081210100983700_cit54","doi-asserted-by":"publisher","DOI":"10.48550\/arXiv.1402.3163","article-title":"xPDFsuite: An End-to-End Software\nSolution for High Throughput Pair Distribution Function Transformation,\nVisualization and Analysis","author":"Yang","journal-title":"arXiv (cond-mat).\n2015\u221202\u221223"},{"key":"2026081210100983700_cit55","doi-asserted-by":"publisher","first-page":"562","DOI":"10.1107\/S2053273315014473","article-title":"Complex\nModeling: A Strategy and Software Program for Combining Multiple Information\nSources to Solve Ill Posed Structure and Nanostructure Inverse Problems","volume":"71","author":"Juha\u0301s","year":"2015","journal-title":"Acta Crystallogr., Sect. A:Found. Adv."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c06764","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/31\/33229\/66343623\/jacs.6c06764.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/31\/33229\/66343623\/jacs.6c06764.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T14:21:31Z","timestamp":1786544491000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/31\/33229\/5237444\/Node-Distortions-as-a-Means-of-Defect-Engineering"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,30]]},"references-count":55,"journal-issue":{"issue":"31","published-online":{"date-parts":[[2026,7,30]]},"published-print":{"date-parts":[[2026,8,12]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c06764","relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv.15001456\/v1","asserted-by":"object"}]},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,30]]}}}