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The compound comprises mixed-valent [Fe2Se3]1\u2013 double chains and trigonal bipyramidal (TBP) [Fe(tren)(ea)]2+ complexes. This is the first report of Fe\u2013Se hybrid materials with interstitial Fe-amine complexes in TBP geometry. Low-field magnetic measurements reveal a bifurcation between the field-cooled and zero-field-cooled magnetization curves at 26 K. Measurements under AC applied field show frequency-dependent peaks in the in-phase part of magnetic susceptibility, indicating the system behaves as cluster spin glass. Nevertheless, under applied field of 2 T, heat capacity measurements show a peak at 24 K, suggesting transition to a long-range magnetically ordered state. The moderately negative Weiss constant, \u03b8w = \u2013 52(1) K, is indicative of antiferromagnetic nearest\u2013neighbor interactions within the chains. The isothermal magnetization curve displays a multistep hysteresis loop due to a potential spin-reorientation transition, with a high coercivity of approximately 0.75 T. X-ray absorption spectroscopy confirms the mixed-valent nature of the [Fe2Se3] double chains. The 57Fe Mo\u0308ssbauer spectroscopy reveals complex magnetic ordering in [Fe2Se3] chains at 6 K. Additionally, magnetic splitting of the signal emerging from the [Fe(tren)(ea)]2+ complex is observed, indicating magnetic interactions between complexes and chains. This hypothesis was confirmed by a comparative DFT analysis of the reported compound and a hypothetical [Zn(tren)(ea)][Fe2Se3]2, which features nonmagnetic ions in the complex.<\/jats:p>","DOI":"10.1021\/jacs.6c06985","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T14:34:48Z","timestamp":1785854088000},"page":"33364-33376","source":"Crossref","is-referenced-by-count":0,"title":["Enhanced Coercivity\nin Ferrimagnetic [Fe(tren)(ea)][Fe2Se3]2 Through Coupling of Mixed-Valent\n[Fe2Se3]1\u2013 Double Chains and\nTrigonal Bipyramidal Fe Complexes"],"prefix":"10.1021","volume":"148","author":[{"given":"Eranga H.","family":"Gamage","sequence":"first","affiliation":[{"name":"Iowa State University , , , ,","place":["Ames, Iowa, United States, 50011"]},{"name":"Ames National Laboratory , , , ,","place":["Ames, Iowa, United States, 50011"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Milo","family":"Adams","sequence":"additional","affiliation":[{"name":"Florida State University , , , ,","place":["Tallahassee, Florida, United States, 32306"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2508-5330","authenticated-orcid":true,"given":"Yao","family":"Abusa","sequence":"additional","affiliation":[{"name":"Iowa State University , , , ,","place":["Ames, Iowa, United States, 50011"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Iyanu","family":"Ojo","sequence":"additional","affiliation":[{"name":"Iowa State University , , , ,","place":["Ames, Iowa, United States, 50011"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Saeed","family":"Kamali","sequence":"additional","affiliation":[{"name":"Middle Tennessee State University , , , ,","place":["Murfreesboro, Tennessee, United States, 37132"]},{"name":"University of Tennessee Space Institute , , , ,","place":["Tullahoma, Tennessee, United States, 37388"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Govind Sasi","family":"Kumar","sequence":"additional","affiliation":[{"name":"Florida State University , , , ,","place":["Tallahassee, Florida, United States, 32306"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9693-8225","authenticated-orcid":true,"given":"Gayatri","family":"Viswanathan","sequence":"additional","affiliation":[{"name":"Iowa State University , , , ,","place":["Ames, Iowa, United States, 50011"]},{"name":"Ames National Laboratory , , , ,","place":["Ames, Iowa, United States, 50011"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-0472-9276","authenticated-orcid":true,"given":"Genevieve","family":"Amobi","sequence":"additional","affiliation":[{"name":"Iowa State University , , , ,","place":["Ames, Iowa, United States, 50011"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Yaroslavtsev","sequence":"additional","affiliation":[{"name":"MAX IV Laboratory, Lund University , Box 118, ,","place":["Lund, Sweden, 221 00"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Shatruk","sequence":"additional","affiliation":[{"name":"Florida State University , , , ,","place":["Tallahassee, Florida, United States, 32306"]},{"name":"FSU Quantum Initiative , , ,","place":["Tallahassee, Florida, United States, 32306"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1152-1912","authenticated-orcid":true,"given":"Kirill","family":"Kovnir","sequence":"additional","affiliation":[{"name":"Iowa State University , , , ,","place":["Ames, Iowa, United States, 50011"]},{"name":"Ames National Laboratory , , , ,","place":["Ames, Iowa, United States, 50011"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,1]]},"reference":[{"issue":"14","key":"2026081210074822700_cit1","doi-asserted-by":"publisher","first-page":"5737","DOI":"10.1021\/acs.chemmater.7b01561","article-title":"Tetrahedral\nTransition Metal Chalcogenides as Functional\nInorganic Materials","volume":"29","author":"Zhou","year":"2017","journal-title":"Chem. 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