{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,7]],"date-time":"2026-08-07T14:23:31Z","timestamp":1786112611144,"version":"build-2736575974"},"reference-count":64,"publisher":"American Chemical Society (ACS)","issue":"30","license":[{"start":{"date-parts":[[2026,7,24]],"date-time":"2026-07-24T00:00:00Z","timestamp":1784851200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000781","name":"European Research Council","doi-asserted-by":"publisher","award":["101095974"],"award-info":[{"award-number":["101095974"]}],"id":[{"id":"10.13039\/501100000781","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013461","name":"Anhui Normal University","doi-asserted-by":"publisher","award":["202210880001"],"award-info":[{"award-number":["202210880001"]}],"id":[{"id":"10.13039\/501100013461","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004543","name":"China Scholarship Council","doi-asserted-by":"publisher","award":["202210880001"],"award-info":[{"award-number":["202210880001"]}],"id":[{"id":"10.13039\/501100004543","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52402125"],"award-info":[{"award-number":["52402125"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100020631","name":"European Innovation Council and Small and Medium-sized Enterprises Executive Agency","doi-asserted-by":"publisher","award":["101098649"],"award-info":[{"award-number":["101098649"]}],"id":[{"id":"10.13039\/100020631","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100012542","name":"Sichuan Provincial Science and Technology Support Program","doi-asserted-by":"publisher","award":["2024JDRC0008"],"award-info":[{"award-number":["2024JDRC0008"]}],"id":[{"id":"10.13039\/100012542","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Chiral hybrid perovskites (CHPs) are highly promising for next-generation chiroptoelectronics and spintronics. However, the incorporation of bulky organic chiral groups to impart chirality inevitably reduces structural dimensionality, leading to pronounced bandgap widening, which fundamentally limits their applications in narrow-bandgap optoelectronic devices. Here, for the first time, we report the construction of a pair of narrow-bandgap zero-dimensional (0D) CHPs, (R\/S-MBA)2PtI6 (MBA = methylbenzylammonium), rationally designed by incorporating a 5d transition metal, Pt(IV), with energetically accessible 5d orbitals, in a chiral hybrid structure. The materials exhibit a small band gap of 1.27 eV, among the lowest values reported to date for intrinsic chiral systems. (R\/S-MBA)2PtI6 adopts a unique 0D structure with quasi-layered packing, in which the terminal ammonium groups of the chiral cations are uniformly embedded within the inorganic sublayer, forming an extended hydrogen-bonding network. Electronic structure calculations reveal that the I(p) orbitals and their hybridization with Pt(d) orbitals define the band-edge states, while hydrogen bonding further tunes the electronic energy levels through local octahedral distortion and lone pair stabilization. The intrinsic integration of such a narrow bandgap with chiroptical activity endows the materials with broadband photoresponse and high polarization selectivity (g = 0.26). Notably, it also shows sensitive X-ray response with a sensitivity of 1410.8 \u03bcC Gy1\u2013 cm\u20132 and a low detection limit of 426.7 nGy s\u20131. These findings demonstrate that hydrogen-bonding-regulated 5d orbital-energy alignment provides an effective strategy to overcome the conventional trade-off between chirality-induced structural dimensionality reduction and bandgap widening in CHPs.<\/jats:p>","DOI":"10.1021\/jacs.6c07362","type":"journal-article","created":{"date-parts":[[2026,7,27]],"date-time":"2026-07-27T04:57:46Z","timestamp":1785128266000},"page":"32167-32176","source":"Crossref","is-referenced-by-count":0,"title":["Narrow-Bandgap Zero-Dimensional\nChiral Hybrid Perovskites"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6628-0565","authenticated-orcid":true,"given":"Zhongyuan","family":"Li","sequence":"first","affiliation":[{"name":"Anhui Normal University , , ,","place":["Wuhu, China, 241000"]},{"name":"Istituto Italiano di Tecnologia , , Via Morego 30 , ,","place":["Genova, Italy, 16163"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haitao","family":"Zhao","sequence":"additional","affiliation":[{"name":"Anhui Normal University , , ,","place":["Wuhu, China, 241000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiasheng","family":"Xie","sequence":"additional","affiliation":[{"name":"Southwest Jiaotong University , , , ,","place":["Chengdu, Sichuan, China, 610031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1537-7148","authenticated-orcid":true,"given":"Shihai","family":"You","sequence":"additional","affiliation":[{"name":"Southwest Jiaotong University , , , ,","place":["Chengdu, Sichuan, China, 610031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shence","family":"Zhang","sequence":"additional","affiliation":[{"name":"Istituto Italiano di Tecnologia , , Via Morego 30 , ,","place":["Genova, Italy, 16163"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6201-9546","authenticated-orcid":true,"given":"Gabriele","family":"Saleh","sequence":"additional","affiliation":[{"name":"Istituto Italiano di Tecnologia , , Via Morego 30 , ,","place":["Genova, Italy, 16163"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4386-7985","authenticated-orcid":true,"given":"Liberato","family":"Manna","sequence":"additional","affiliation":[{"name":"Istituto Italiano di Tecnologia , , Via Morego 30 , ,","place":["Genova, Italy, 16163"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,24]]},"reference":[{"key":"2026080511123017600_cit1","doi-asserted-by":"publisher","first-page":"1231","DOI":"10.1016\/j.chempr.2022.01.014","article-title":"Rationalizing the Design and Implementation of Chiral\nHybrid Perovskites","volume":"8","author":"Pietropaolo","year":"2022","journal-title":"Chem"},{"key":"2026080511123017600_cit2","doi-asserted-by":"publisher","first-page":"794","DOI":"10.1016\/j.matt.2020.12.018","article-title":"Chiral\nHalide Perovskite\nCrystals for Optoelectronic Applications","volume":"4","author":"Dang","year":"2021","journal-title":"Matter"},{"key":"2026080511123017600_cit3","doi-asserted-by":"publisher","first-page":"423","DOI":"10.1038\/s41578-020-0181-5","article-title":"Chiral-Perovskite Optoelectronics","volume":"5","author":"Long","year":"2020","journal-title":"Nat. Rev.\nMater."},{"key":"2026080511123017600_cit4","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202008785","article-title":"Recent Progress\nof Chiral Perovskites:\nMaterials, Synthesis, and Properties","volume":"33","author":"Ma","year":"2021","journal-title":"Adv. Mater."},{"key":"2026080511123017600_cit5","doi-asserted-by":"publisher","first-page":"24377","DOI":"10.1021\/jacs.4c05992","article-title":"Unraveling\nthe Role\nof Structural Topology on Chirality Transfer and Chiroptical Properties\nin Chiral Germanium Iodides","volume":"146","author":"Coccia","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"2026080511123017600_cit6","doi-asserted-by":"publisher","first-page":"3124","DOI":"10.1038\/s41467-023-38927-2","article-title":"Unraveling Chirality Transfer Mechanism\nby Structural Isomer-Derived Hydrogen Bonding Interaction in 2D Chiral\nPerovskite","volume":"14","author":"Son","year":"2023","journal-title":"Nat. Commun."},{"key":"2026080511123017600_cit7","doi-asserted-by":"publisher","first-page":"3140","DOI":"10.1021\/acs.chemrev.8b00417","article-title":"Quantum and Dielectric Confinement\nEffects in Lower-Dimensional Hybrid Perovskite Semiconductors","volume":"119","author":"Katan","year":"2019","journal-title":"Chem. Rev."},{"key":"2026080511123017600_cit8","doi-asserted-by":"publisher","first-page":"2230","DOI":"10.1021\/acs.chemrev.0c01006","article-title":"The 2D\nHalide Perovskite Rulebook:\nHow The Spacer Influences Everything from The Structure to Optoelectronic\nDevice Efficiency","volume":"121","author":"Li","year":"2021","journal-title":"Chem. Rev."},{"key":"2026080511123017600_cit9","doi-asserted-by":"publisher","first-page":"1704418","DOI":"10.1002\/adma.201704418","article-title":"Ideal Bandgap Organic-Inorganic Hybrid\nPerovskite Solar Cells","volume":"29","author":"Yang","year":"2017","journal-title":"Adv. Mater."},{"key":"2026080511123017600_cit10","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abg2418","article-title":"Broadband Infrared Photodetection Using a Narrow Bandgap\nConjugated Polymer","volume":"7","author":"Vella","year":"2021","journal-title":"Sci. Adv."},{"key":"2026080511123017600_cit11","doi-asserted-by":"publisher","first-page":"849","DOI":"10.1134\/S1063782624601468","article-title":"Advantages of Narrow\nBandgap Nanoparticles in Semiconductor Development and their Applications","volume":"58","author":"Islam","year":"2024","journal-title":"Semiconductors"},{"key":"2026080511123017600_cit12","doi-asserted-by":"publisher","first-page":"4558","DOI":"10.1021\/acs.chemrev.5b00715","article-title":"Organic\u2013Inorganic\nPerovskites: Structural Versatility\nfor Functional Materials Design","volume":"116","author":"Saparov","year":"2016","journal-title":"Chem. Rev."},{"key":"2026080511123017600_cit13","doi-asserted-by":"publisher","first-page":"3104","DOI":"10.1021\/acs.chemrev.8b00477","article-title":"Tuning\nthe Luminescence of Layered\nHalide Perovskites","volume":"119","author":"Smith","year":"2019","journal-title":"Chem. Rev."},{"key":"2026080511123017600_cit14","doi-asserted-by":"publisher","first-page":"3321","DOI":"10.1021\/acsnano.7b08202","article-title":"Composite Nature of\nLayered Hybrid Perovskites: Assessment on Quantum\nand Dielectric Confinements and Band Alignment","volume":"12","author":"Traore","year":"2018","journal-title":"ACS Nano"},{"key":"2026080511123017600_cit15","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202501133","article-title":"Self-Powered Circularly\nPolarized Photodetectors Based on Chiral\n(R\/S-MBA) 2PbI4 Perovskite","volume":"13","author":"Zhang","year":"2025","journal-title":"Adv. Opt. Mater."},{"key":"2026080511123017600_cit16","doi-asserted-by":"publisher","first-page":"18062","DOI":"10.1021\/jacs.2c07891","article-title":"Chain-to-Layer\nDimensionality Engineering of Chiral Hybrid Perovskites to Realize\nPassive Highly Circular-Polarization-Sensitive Photodetection","volume":"144","author":"Zhu","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026080511123017600_cit17","doi-asserted-by":"publisher","first-page":"16166","DOI":"10.1039\/D0TA05433J","article-title":"A Critical Review on\nBismuth and Antimony Halide Based Perovskites\nand Their Derivatives for Photovoltaic Applications: Recent Advances\nand Challenges","volume":"8","author":"Jin","year":"2020","journal-title":"J. Mater. Chem. A"},{"key":"2026080511123017600_cit18","doi-asserted-by":"publisher","first-page":"4073","DOI":"10.1021\/acs.jpclett.2c00698","article-title":"Exciton\u2013Phonon Coupling of Chiral One-Dimensional Lead-Free\nHybrid Metal Halides at Room Temperature","volume":"13","author":"Li","year":"2022","journal-title":"J.\nPhys. Chem. Lett."},{"key":"2026080511123017600_cit19","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202501022","article-title":"Nonlinear\nOptical Properties of 0D Chiral Hybrid Bismuth Iodides","volume":"37","author":"Chaturvedi","year":"2025","journal-title":"Adv. Mater."},{"key":"2026080511123017600_cit20","doi-asserted-by":"publisher","first-page":"4909","DOI":"10.1103\/PhysRevB.27.4909","article-title":"Electronic Structure of Substitutional\nChalcogen Impurities in Silicon","volume":"27","author":"Singh","year":"1983","journal-title":"Phys. Rev.\nB"},{"key":"2026080511123017600_cit21","doi-asserted-by":"publisher","first-page":"1254","DOI":"10.1021\/acs.jpclett.6b00376","article-title":"Lead-Free\nHalide Double Perovskites\nvia Heterovalent Substitution of Noble Metals","volume":"7","author":"Volonakis","year":"2016","journal-title":"J. Phys. Chem. Lett."},{"key":"2026080511123017600_cit22","doi-asserted-by":"crossref","DOI":"10.1021\/acsenergylett.6c00105","article-title":"Transition-Metal-Doped\nHalide Perovskites\nfor Near-Infrared Emissions: Beyond Oxides","author":"Saikia","year":"2026","journal-title":"ACS Energy Lett."},{"key":"2026080511123017600_cit23","doi-asserted-by":"publisher","first-page":"44700","DOI":"10.1021\/acsami.0c11429","article-title":"Novel Lead-Free\nMaterial Cs2PtI6 with Narrow Bandgap and Ultra-Stability\nfor Its Photovoltaic Application","volume":"12","author":"Yang","year":"2020","journal-title":"ACS Appl.\nMater. Interfaces"},{"key":"2026080511123017600_cit24","doi-asserted-by":"publisher","DOI":"10.1002\/eom2.12492","article-title":"Pt and Pt-Group Transition\nMetal 0D Vacancy Ordered\nHalide Perovskites: A Review","volume":"6","author":"Liu","year":"2024","journal-title":"EcoMat"},{"key":"2026080511123017600_cit25","doi-asserted-by":"publisher","first-page":"115556","DOI":"10.1016\/j.ssc.2024.115556","article-title":"First-Principles Investigations\non the Physical Properties of the Double Perovskite Cs2OsI6","volume":"389","author":"Chen","year":"2024","journal-title":"Solid State Commun."},{"key":"2026080511123017600_cit26","doi-asserted-by":"publisher","first-page":"15045","DOI":"10.1021\/jacs.3c14491","article-title":"Structural Asymmetry\nand Chiral-Induced Spin Selectivity in Chiral Palladium-Halide Semiconductors","volume":"146","author":"Nam","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"2026080511123017600_cit27","doi-asserted-by":"publisher","first-page":"37771","DOI":"10.1021\/jacs.5c13847","article-title":"The Interplay between Luminescence\nDissymmetry Factor and Quantum Yield: Symmetric and Asymmetric Hydrogen\nBonding","volume":"147","author":"Wang","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026080511123017600_cit28","doi-asserted-by":"publisher","first-page":"3041","DOI":"10.1007\/s11426-024-2473-6","article-title":"Dramatical Enhancement\nof Circular Dichroism in Chiral Hybrid Perovskites via Carboxylic\nHydrogen Bond Engineering","volume":"68","author":"Li","year":"2025","journal-title":"Sci. China Chem."},{"key":"2026080511123017600_cit29","doi-asserted-by":"publisher","first-page":"1941","DOI":"10.1021\/acs.chemmater.8b04642","article-title":"Zero-Dimensional\nLead-Free Hybrid\nPerovskite-like Material with a Quantum-Well Structure","volume":"31","author":"Pious","year":"2019","journal-title":"Chem. Mater."},{"key":"2026080511123017600_cit30","doi-asserted-by":"publisher","first-page":"2304899","DOI":"10.1002\/adfm.202304899","article-title":"Zero-Dimensional\nTin Halide Perovskite with Long Charge Carrier Lifetime and Anisotropic\nPhotoconductivity for Selective Deep-UV Photodetection","volume":"34","author":"Ajayakumar","year":"2024","journal-title":"Adv. Funct. Mater."},{"key":"2026080511123017600_cit31","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202411332","article-title":"Dimethylamine\nBismuth Iodide: A Lead-Free Perovskite Enabling Ultra-Sensitive UVC\nPhotodetection with Low Operating Voltage and High Detectivity","volume":"37","author":"Ajayakumar","year":"2025","journal-title":"Adv. Mater."},{"key":"2026080511123017600_cit32","doi-asserted-by":"publisher","first-page":"917","DOI":"10.1021\/ic990921e","article-title":"Evolution\nof the Jahn-Teller Distortion of MnO6 Octahedra in RMnO3 Perovskites (R= Pr, Nd, Dy, Tb, Ho, Er, Y): A Neutron Diffraction\nStudy","volume":"39","author":"Alonso","year":"2000","journal-title":"Inorg. Chem."},{"key":"2026080511123017600_cit33","doi-asserted-by":"publisher","first-page":"10","DOI":"10.1107\/S0108768103026661","article-title":"Jahn-Teller Distortions, Cation Ordering and Octahedral\nTilting in Perovskites","volume":"60","author":"Lufaso","year":"2004","journal-title":"Struct. Sci."},{"key":"2026080511123017600_cit34","doi-asserted-by":"publisher","first-page":"11169","DOI":"10.1103\/PhysRevB.54.11169","article-title":"Efficient\nIterative Schemes for ab Initio Total-Energy\nCalculations using a Plane-Wave Basis Set","volume":"54","author":"Kresse","year":"1996","journal-title":"Phys.\nRev. B"},{"key":"2026080511123017600_cit35","doi-asserted-by":"publisher","first-page":"1758","DOI":"10.1103\/PhysRevB.59.1758","article-title":"From Ultrasoft Pseudopotentials\nto the Projector Augmented-Wave\nMethod","volume":"59","author":"Kresse","year":"1999","journal-title":"Phys. Rev. B"},{"key":"2026080511123017600_cit36","doi-asserted-by":"publisher","first-page":"15","DOI":"10.1016\/0927-0256(96)00008-0","article-title":"Efficiency of ab-Initio Total Energy Calculations for\nMetals and Semiconductors using a Plane-Wave Basis Set","volume":"6","author":"Kresse","year":"1996","journal-title":"Comput. Mater. Sci."},{"key":"2026080511123017600_cit37","doi-asserted-by":"publisher","first-page":"243","DOI":"10.1016\/0092-640X(76)90027-9","article-title":"Neutral-Atom Electron Binding Energies\nfrom Relaxed-Orbital Relativistic\nHartree-Fock-Slater Calculations 2 \u2264 Z \u2264 106","volume":"18","author":"Huang","year":"1976","journal-title":"At. Data Nucl. Data Tables"},{"key":"2026080511123017600_cit38","doi-asserted-by":"publisher","first-page":"8524","DOI":"10.1021\/acs.chemmater.1c03035","article-title":"Methylammonium\nGoverns Structural and Optical Properties of Hybrid Lead Halide Perovskites\nthrough Dynamic Hydrogen Bonding","volume":"33","author":"Saleh","year":"2021","journal-title":"Chem. Mater."},{"key":"2026080511123017600_cit39","doi-asserted-by":"publisher","first-page":"2910","DOI":"10.1002\/adfm.201500216","article-title":"MoS\/Si Heterojunction\nwith Vertically Standing Layered Structure for Ultrafast, High-Detectivity,\nSelf-Driven Visible-Near Infrared Photodetectors","volume":"25","author":"Wang","year":"2015","journal-title":"Adv. Funct. Mater."},{"key":"2026080511123017600_cit40","doi-asserted-by":"publisher","first-page":"595","DOI":"10.1002\/smll.201502336","article-title":"High Detectivity Graphene-Silicon\nHeterojunction Photodetector","volume":"12","author":"Li","year":"2016","journal-title":"Small"},{"key":"2026080511123017600_cit41","doi-asserted-by":"publisher","first-page":"9686","DOI":"10.1021\/jacs.4c17796","article-title":"Chiral-Polar Photovoltage-Driven Efficient Self-Powered Circularly\nPolarized Light Detection in Three-Dimensional Hybrid Perovskites","volume":"147","author":"Zhang","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026080511123017600_cit42","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202212685","article-title":"Circularly\nPolarized Luminescence from Zero-Dimensional Hybrid Lead-Tin Bromide\nwith Near-Unity Photoluminescence Quantum Yield","volume":"61","author":"Wei","year":"2022","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026080511123017600_cit43","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202510842","article-title":"Chiral Molecules\nInduce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals","volume":"137","author":"Babu","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026080511123017600_cit44","doi-asserted-by":"publisher","first-page":"1927","DOI":"10.1038\/s41467-019-09942-z","article-title":"Circularly Polarized\nLight Detection Using Chiral Hybrid Perovskite","volume":"10","author":"Chen","year":"2019","journal-title":"Nat. Commun."},{"key":"2026080511123017600_cit45","doi-asserted-by":"publisher","first-page":"376","DOI":"10.1038\/nphys1606","article-title":"Mott Physics\nand Band Topology in Materials with Strong\nSpin\u2013Orbit Interaction","volume":"6","author":"Pesin","year":"2010","journal-title":"Nat. Phys."},{"key":"2026080511123017600_cit46","doi-asserted-by":"publisher","first-page":"871","DOI":"10.1038\/nmat4360","article-title":"New Perspectives for Rashba Spin\u2013Orbit Coupling","volume":"14","author":"Manchon","year":"2015","journal-title":"Nat. Mater."},{"key":"2026080511123017600_cit47","doi-asserted-by":"publisher","first-page":"2406443","DOI":"10.1002\/adma.202406443","article-title":"High sensitivity\nX-ray Detectors with Low Degradation Based on Deuterated Halide Perovskite\nSingle Crystals","volume":"36","author":"Liu","year":"2024","journal-title":"Adv. Mater."},{"key":"2026080511123017600_cit48","doi-asserted-by":"publisher","first-page":"10917","DOI":"10.1021\/acsami.1c21948","article-title":"Interfaces,\nSurface passivation of MAPbBr3 Perovskite Single Crystals\nto Suppress Ion Migration and Enhance Photoelectronic Performance","volume":"14","author":"Chen","year":"2022","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026080511123017600_cit49","doi-asserted-by":"publisher","first-page":"2103078","DOI":"10.1002\/adma.202103078","article-title":"Elimination of Interfacial-Electrochemical-Reaction-Induced Polarization\nin Perovskite Single Crystals for Ultrasensitive and Stable X-ray\nDetector Arrays","volume":"33","author":"Song","year":"2021","journal-title":"Adv. Mater."},{"key":"2026080511123017600_cit50","unstructured":"NIST Physical Measurement Laboratory, X.-R. F. F.\n          , Attenuation, and\nScattering Tableshttps:\/\/www.nist.gov\/pml\/x-ray-form-factor-attenuation-and-scattering-tables, accessed Apr, 08 2026."},{"key":"2026080511123017600_cit51","doi-asserted-by":"publisher","first-page":"1066","DOI":"10.1038\/s41467-019-08981-w","article-title":"Halide Lead Perovskites\nfor Ionizing Radiation Detection","volume":"10","author":"Wei","year":"2019","journal-title":"Nat. Commun."},{"key":"2026080511123017600_cit52","doi-asserted-by":"publisher","first-page":"6665","DOI":"10.1039\/D2TC00599A","article-title":"Inch-Size Cs3Bi2I9 Polycrystalline Wafers with Near-Intrinsic\nProperties for Ultralow-Detection-Limit X-Ray Detection","volume":"10","author":"Bu","year":"2022","journal-title":"J. Mater. Chem. C"},{"key":"2026080511123017600_cit53","doi-asserted-by":"publisher","first-page":"1778","DOI":"10.1021\/acs.jpclett.1c00090","article-title":"Zero-Dimensional\nLead-Free FA3Bi2I9 Single Crystals\nfor High-Performance X-Ray Detection","volume":"12","author":"Li","year":"2021","journal-title":"J. Phys.\nChem. Lett."},{"key":"2026080511123017600_cit54","doi-asserted-by":"publisher","first-page":"2412504","DOI":"10.1002\/advs.202412504","article-title":"Multiple\nInteractions in Polar Lead-Free Perovskites toward Highly\nStable X-Ray Detection","volume":"12","author":"Qu","year":"2025","journal-title":"Adv. Sci."},{"key":"2026080511123017600_cit55","doi-asserted-by":"publisher","first-page":"5461","DOI":"10.1039\/D4TC00375F","article-title":"Suppression of Ion\nMigration in Lead-Free Zero-Dimensional Perovskite FA3BiBr6 Single Crystals for X-Ray Detection","volume":"12","author":"Ji","year":"2024","journal-title":"J. Mater. Chem. C"},{"key":"2026080511123017600_cit56","doi-asserted-by":"publisher","first-page":"38283","DOI":"10.1021\/acsami.4c08648","article-title":"Lead-Free Bismuth-Based\nPerovskite X-Ray Detector with High Sensitivity and Low Detection\nLimit","volume":"16","author":"Zhao","year":"2024","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026080511123017600_cit57","doi-asserted-by":"publisher","first-page":"32711","DOI":"10.1021\/acsami.5c04169","article-title":"High-Performance X-Ray\nDetection Made of Bismuth Perovskite Single\nCrystal Based on Hydrogen-Bond-Free and Interlayer-Spacing Engineering\nStrategies","volume":"17","author":"Zheng","year":"2025","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026080511123017600_cit58","doi-asserted-by":"publisher","first-page":"5258","DOI":"10.1038\/s41467-021-25648-7","article-title":"Determination\nof X-Ray Detection Limit and Applications in Perovskite X-Ray Detectors","volume":"12","author":"Pan","year":"2021","journal-title":"Nat. Commun."},{"key":"2026080511123017600_cit59","doi-asserted-by":"publisher","first-page":"180","DOI":"10.1016\/j.matt.2020.04.017","article-title":"Inch-Size\n0D-Structured Lead-Free Perovskite Single Crystals for Highly Sensitive\nStable X-Ray Imaging","volume":"3","author":"Liu","year":"2020","journal-title":"Matter"},{"key":"2026080511123017600_cit60","doi-asserted-by":"publisher","first-page":"2303523","DOI":"10.1002\/adfm.202303523","article-title":"Inch-Size\nSingle Crystals of Lead-Free Chiral Perovskites with Bulk Photovoltaic\nEffect for Stable Self-Driven X-Ray Detection","volume":"33","author":"You","year":"2023","journal-title":"Adv. Funct. Mater."},{"key":"2026080511123017600_cit61","doi-asserted-by":"publisher","first-page":"2400193","DOI":"10.1002\/adom.202400193","article-title":"Confinement-Driven\nBulk Photovoltaic in Lead-Free Hybrid Perovskite for Self-Powered\nX-Ray Detection","volume":"12","author":"Fu","year":"2024","journal-title":"Adv. Opt. Mater."},{"key":"2026080511123017600_cit62","doi-asserted-by":"publisher","first-page":"7702","DOI":"10.1038\/s41467-022-35441-9","article-title":"Circular Polarized\nLight-Dependent Anomalous Photovoltaic Effect from Achiral Hybrid\nPerovskites","volume":"13","author":"Zhu","year":"2022","journal-title":"Nat. Commun."},{"key":"2026080511123017600_cit63","doi-asserted-by":"crossref","unstructured":"Iannone, F.; Ambrosino, F.; Bracco, G.; De Rosa, M.; Funel, A.; Guarnieri, G.; Migliori, S.; Palombi, F.; Ponti, G.; Santomauro, G. In  CRESCO ENEA HPC Clusters: A Working Example\nof A Multifabric GPFS Spectrum Scale Layout,  2019\nInternational Conference on High Performance Computing & Simulation\n(HPCS); IEEE: 2019; pp 1051\u20131052.","DOI":"10.1109\/HPCS48598.2019.9188135"},{"key":"2026080511123017600_cit64","doi-asserted-by":"publisher","first-page":"920","DOI":"10.1016\/j.future.2017.11.032","article-title":"Fast Access to Remote Objects 2.0: A Renewed\nGateway to ENEAGRID Distributed Computing Resources","volume":"94","author":"Mariano","year":"2019","journal-title":"Future Gener. Comput. Syst."}],"container-title":["Journal of the American\nChemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c07362","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/30\/32167\/66241866\/jacs.6c07362.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/30\/32167\/66241866\/jacs.6c07362.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T15:23:11Z","timestamp":1785943391000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/30\/32167\/5231474\/Narrow-Bandgap-Zero-Dimensional-Chiral-Hybrid"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,24]]},"references-count":64,"journal-issue":{"issue":"30","published-online":{"date-parts":[[2026,7,24]]},"published-print":{"date-parts":[[2026,8,5]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c07362","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,24]]}}}