{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T15:25:29Z","timestamp":1787153129304,"version":"build-2736575974"},"reference-count":54,"publisher":"American Chemical Society (ACS)","issue":"32","license":[{"start":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T00:00:00Z","timestamp":1785801600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T00:00:00Z","timestamp":1785801600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T00:00:00Z","timestamp":1785801600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001700","name":"Ministry of Education, Culture, Sports, Science and Technology","doi-asserted-by":"publisher","award":["JPMXP1122714694"],"award-info":[{"award-number":["JPMXP1122714694"]}],"id":[{"id":"10.13039\/501100001700","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP23H00298, JP24K17695"],"award-info":[{"award-number":["JP23H00298, JP24K17695"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002241","name":"Japan Science and Technology Agency","doi-asserted-by":"publisher","award":["JPMJSP2110"],"award-info":[{"award-number":["JPMJSP2110"]}],"id":[{"id":"10.13039\/501100002241","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,19]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Viscosity of porous liquids (PLs) is a critical factor for their processability and transportation, yet controlling their viscosity without compromising pore volume remains a significant challenge. In this work, we present a strategy to modulate the viscosity of type I PLs by varying surface functionality. A series of star-shaped PLs was synthesized by coordinating 12 equiv of soft polymer chains to isostructural rhodium metal\u2013organic polyhedra (RhMOPs) as central cores with different surface groups (nonsubstituted, hydroxy, tert-butyl, or dodecyloxy groups). The functional groups on the RhMOP surface were found to significantly affect the conformation of polymer chains, thereby resulting in different rheological behavior and pore accessibility. The use of RhMOPs with dodecyloxy surface groups yielded a closely compact conformation of polymer chains on the MOP surface. The obtained PLs have a viscosity as low as 1.8 \u00d7 101 Pa\u00b7s and exhibit a temperature-dependent gating effect; CO2 uptake increases with increasing temperature. By contrast, the hydroxyl group afforded PLs with a loosely stretched polymer conformation, resulting in a dramatically high viscosity of 3.0 \u00d7 109 Pa\u00b7s and high gas accessibility to the inner RhMOP pores. This work provides a feasible way to adjust PLs\u2019 rheological properties without altering pore volume to meet the requirements of different practical applications.<\/jats:p>","DOI":"10.1021\/jacs.6c07430","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T17:02:09Z","timestamp":1785862929000},"page":"34289-34299","source":"Crossref","is-referenced-by-count":0,"title":["Viscosity\nand Pore Accessibility Control of Type I\nPorous Liquids by Modifying Surface Functionality of Metal\u2013Organic\nPolyhedra"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-9645-5508","authenticated-orcid":true,"given":"Xiangmei","family":"Xiang","sequence":"first","affiliation":[{"name":"Kyoto University , , Yoshida, Sakyo-ku , ,","place":["Kyoto, Japan, 606-8501"]},{"name":"Kyoto University , , Katsura, Nishikyo-ku , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1385-8164","authenticated-orcid":true,"given":"Zaoming","family":"Wang","sequence":"additional","affiliation":[{"name":"Kyoto University , , Yoshida, Sakyo-ku , ,","place":["Kyoto, Japan, 606-8501"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masataka","family":"Yamashita","sequence":"additional","affiliation":[{"name":"Kyoto University , , Katsura, Nishikyo-ku , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7424-0750","authenticated-orcid":true,"given":"Shang-Wei","family":"Lin","sequence":"additional","affiliation":[{"name":"National Taiwan University , , ,","place":["Taipei, Taiwan, 106319"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Po-Chun","family":"Han","sequence":"additional","affiliation":[{"name":"Kyoto University , , Yoshida, Sakyo-ku , ,","place":["Kyoto, Japan, 606-8501"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mako","family":"Kuzumoto","sequence":"additional","affiliation":[{"name":"Kyoto University , , Katsura, Nishikyo-ku , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-4239-885X","authenticated-orcid":true,"given":"Ayana","family":"Miyata","sequence":"additional","affiliation":[{"name":"Kyoto University , , Yoshida, Sakyo-ku , ,","place":["Kyoto, Japan, 606-8501"]},{"name":"Kyoto University , , Katsura, Nishikyo-ku , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7443-4635","authenticated-orcid":true,"given":"Javier","family":"Lopez-Cabrelles","sequence":"additional","affiliation":[{"name":"Kyoto University , , Yoshida, Sakyo-ku , ,","place":["Kyoto, Japan, 606-8501"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuki","family":"Hosoi","sequence":"additional","affiliation":[{"name":"Kyoto University , , Katsura, Nishikyo-ku , ,","place":["Kyoto, Japan, 615-8510"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7970-1357","authenticated-orcid":true,"given":"Hsiao-Ching","family":"Yang","sequence":"additional","affiliation":[{"name":"National Tsing Hua University , , ,","place":["Hsinchu, Taiwan, 300044"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Koichi","family":"Mayumi","sequence":"additional","affiliation":[{"name":"The University of Tokyo , , 5-1-5 Kashiwanoha , , ,","place":["Kashiwa-shi, Chiba, Japan, 277-8561"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2821-9501","authenticated-orcid":true,"given":"Li-Chiang","family":"Lin","sequence":"additional","affiliation":[{"name":"National Taiwan 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