{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T02:23:46Z","timestamp":1791512626302,"version":"4.3.4"},"reference-count":54,"publisher":"American Chemical Society (ACS)","issue":"33","license":[{"start":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T00:00:00Z","timestamp":1786924800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T00:00:00Z","timestamp":1786924800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T00:00:00Z","timestamp":1786924800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-SC0019445"],"award-info":[{"award-number":["DE-SC0019445"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100018190","name":"Cornell Atkinson Center for Sustainability, Cornell University","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100018190","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,26]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The living vinyl-addition polymerization of norbornenes is a robust method for accessing high-molecular-weight, solvent-processable materials with a chemically inert backbone and varied block copolymer architectures. However, the extent of its livingness and the underlying mechanisms of the loss of molecular weight control remain underexplored and unoptimized. In this work, we provide a functional guide to achieving improved molecular weight control through the systematic exploration of vinyl-addition polymerization by a tri-tert-butylphosphine-ligated cationic palladium initiator. We developed a time-delay chain extension experimental protocol to quantify the livingness of a given polymerization and enable identification of how the catalyst counteranion, trace impurities, and polymerization conditions impact the reactivity of the propagating chain end. Reagents that can both halt propagation and remove the polymer from the palladium chain end were identified through complementary studies of polymer quenching protocols. Ultimately, we establish a series of guidelines for achieving highly living vinyl-addition polymerizations of norbornene monomers and apply them to the synthesis of a nonablock copolymer on the benchtop, expanding the toolkit of living methodologies for the synthetic polymer chemist while providing an experimental framework for the optimization of living polymerizations.<\/jats:p>","DOI":"10.1021\/jacs.6c07480","type":"journal-article","created":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T20:01:51Z","timestamp":1786996911000},"page":"35668-35680","source":"Crossref","is-referenced-by-count":1,"title":["Expanding the Living\nPolymerization Toolkit: Mechanistic\nInsights and Optimization of Vinyl-Addition Polymerization of Norbornenes"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3635-8720","authenticated-orcid":true,"given":"Julia E.","family":"Borowski","sequence":"first","affiliation":[{"name":"Cornell University , , , ,","place":["Ithaca, New York, United States, 14853"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6184-1626","authenticated-orcid":true,"given":"Alexandra J.","family":"Macbeth","sequence":"additional","affiliation":[{"name":"Cornell University , , , ,","place":["Ithaca, New York, United States, 14853"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-4288-216X","authenticated-orcid":true,"given":"Ethan B.","family":"Flanagan","sequence":"additional","affiliation":[{"name":"Cornell University , , , ,","place":["Ithaca, New York, United States, 14853"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abigail L.","family":"Taylor","sequence":"additional","affiliation":[{"name":"Cornell University , , , ,","place":["Ithaca, New York, United States, 14853"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-1653-2249","authenticated-orcid":true,"given":"Demetrios H.","family":"Patrinos","sequence":"additional","affiliation":[{"name":"Cornell University , , , ,","place":["Ithaca, New York, United States, 14853"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2222-3825","authenticated-orcid":true,"given":"Brett P.","family":"Fors","sequence":"additional","affiliation":[{"name":"Cornell University , , , ,","place":["Ithaca, New York, United States, 14853"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3400-2552","authenticated-orcid":true,"given":"Geoffrey W.","family":"Coates","sequence":"additional","affiliation":[{"name":"Cornell University , , , ,","place":["Ithaca, New York, United States, 14853"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,17]]},"reference":[{"key":"2026090104491733700_cit1","doi-asserted-by":"publisher","first-page":"6979","DOI":"10.1021\/acs.macromol.7b01440","article-title":"50th Anniversary Perspective: Living\nPolymerization\u2500Emphasizing the Molecule in Macromolecules","volume":"50","author":"Grubbs","year":"2017","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit2","doi-asserted-by":"publisher","first-page":"2603","DOI":"10.1021\/acs.macromol.6b02711","article-title":"50th Anniversary Perspective: Metal-Catalyzed\nLiving Radical Polymerization: Discovery and Perspective","volume":"50","author":"Ouchi","year":"2017","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit3","doi-asserted-by":"publisher","first-page":"7433","DOI":"10.1021\/acs.macromol.7b00767","article-title":"50th Anniversary Perspective: RAFT Polymerization\u2500A User\nGuide","volume":"50","author":"Perrier","year":"2017","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit4","doi-asserted-by":"publisher","first-page":"1575","DOI":"10.1016\/j.chempr.2020.06.014","article-title":"Recent Developments\nand Future Challenges in Controlled Radical Polymerization: A 2020\nUpdate","volume":"6","author":"Parkatzidis","year":"2020","journal-title":"Chem"},{"key":"2026090104491733700_cit5","doi-asserted-by":"publisher","first-page":"276","DOI":"10.1038\/536276a","article-title":"Sixty Years\nof Living Polymers","volume":"536","author":"Patterson","year":"2016","journal-title":"Nature"},{"key":"2026090104491733700_cit6","doi-asserted-by":"publisher","DOI":"10.1351\/goldbook.L03597","volume-title":"\u2018Living\npolymerization\u2019 in IUPAC Compendium of Chemical Terminology","author":"International Union of Pure and Applied Chemistry.","year":"2025","edition":"5th"},{"key":"2026090104491733700_cit7","doi-asserted-by":"crossref","DOI":"10.1002\/047147875X","volume-title":"Principles of Polymerization","author":"Odian","year":"2004","edition":"4th"},{"key":"2026090104491733700_cit8","doi-asserted-by":"publisher","first-page":"373","DOI":"10.1021\/ar960248m","article-title":"\u201cLiving\u201d\nFree Radical Polymerization: A Unique Technique for the Preparation\nof Controlled Macromolecular Architectures","volume":"30","author":"Hawker","year":"1997","journal-title":"Acc. Chem. Res."},{"key":"2026090104491733700_cit9","doi-asserted-by":"publisher","first-page":"2921","DOI":"10.1021\/cr940534g","article-title":"Atom Transfer Radical Polymerization","volume":"101","author":"Matyjaszewski","year":"2001","journal-title":"Chem.\nRev."},{"key":"2026090104491733700_cit10","doi-asserted-by":"publisher","first-page":"A258","DOI":"10.1289\/ehp.115-a258","article-title":"Radical Departure:\nPolymerization Does More With Less","volume":"115","author":"Frazer","year":"2007","journal-title":"Environ.\nHealth Perspect."},{"key":"2026090104491733700_cit11","doi-asserted-by":"publisher","first-page":"1133","DOI":"10.1021\/ar800075n","article-title":"Toward Living Radical Polymerization","volume":"41","author":"Moad","year":"2008","journal-title":"Acc. Chem. Res."},{"key":"2026090104491733700_cit12","doi-asserted-by":"publisher","first-page":"38","DOI":"10.1016\/j.progpolymsci.2011.08.004","article-title":"Complex Polymer Architectures via RAFT Polymerization:\nFrom Fundamental Process to Extending the Scope Using Click Chemistry\nand Nature\u2019s Building Blocks","volume":"37","author":"Gregory","year":"2012","journal-title":"Prog. Polym.\nSci."},{"key":"2026090104491733700_cit13","doi-asserted-by":"publisher","first-page":"101311","DOI":"10.1016\/j.progpolymsci.2020.101311","article-title":"Reversible-Deactivation Radical Polymerization (Controlled\/Living\nRadical Polymerization): From Discovery to Materials Design and Applications","volume":"111","author":"Corrigan","year":"2020","journal-title":"Prog. Polym. Sci."},{"key":"2026090104491733700_cit14","doi-asserted-by":"publisher","first-page":"1883","DOI":"10.1021\/ma401175m","article-title":"Advances in Living Anionic Polymerization:\nFrom Functional Monomers, Polymerization Systems, to Macromolecular\nArchitectures","volume":"47","author":"Hirao","year":"2014","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit15","doi-asserted-by":"crossref","DOI":"10.1002\/9780470825150.ch9","article-title":"Living Alkene Polymerization for Polyolefin Architectures","volume-title":"Complex Macromolecular Architectures: Synthesis, Characterization,\nand Self-Assembly","author":"Anderson-Wile","year":"2011"},{"key":"2026090104491733700_cit16","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.progpolymsci.2006.08.006","article-title":"Living Ring-Opening\nMetathesis Polymerization","volume":"32","author":"Bielawski","year":"2007","journal-title":"Prog. Polym. Sci."},{"key":"2026090104491733700_cit17","doi-asserted-by":"publisher","first-page":"247","DOI":"10.1016\/j.progpolymsci.2007.01.002","article-title":"Living Ring-Opening\nPolymerizations of Heterocyclic Monomers","volume":"32","author":"Penczek","year":"2007","journal-title":"Prog.\nPolym. Sci."},{"key":"2026090104491733700_cit18","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202300818","article-title":"Single-Component Catalysts for the Vinyl-Addition Polymerization\nof Norbornene and Its Derivatives","volume":"15","author":"Bermesheva","year":"2023","journal-title":"ChemCatChem"},{"key":"2026090104491733700_cit19","doi-asserted-by":"publisher","first-page":"15076","DOI":"10.1021\/acscatal.2c04345","article-title":"Air-Stable\nSingle-Component Pd-Catalysts for Vinyl-Addition\nPolymerization of Functionalized Norbornenes","volume":"12","author":"Bermesheva","year":"2022","journal-title":"ACS Catal."},{"key":"2026090104491733700_cit20","doi-asserted-by":"publisher","first-page":"327","DOI":"10.1021\/acsmacrolett.5b00079","article-title":"Living Vinyl Addition Polymerization\nof Substituted Norbornenes by a t-Bu3P-Ligated\nMethylpalladium Complex","volume":"4","author":"Kim","year":"2015","journal-title":"ACS Macro Lett."},{"key":"2026090104491733700_cit21","doi-asserted-by":"publisher","first-page":"10273","DOI":"10.1021\/acsaem.1c02094","article-title":"Multiblock Copolymer\nAnion-Exchange Membranes Derived from Vinyl Addition Polynorbornenes","volume":"4","author":"Selhorst","year":"2021","journal-title":"ACS Appl. Energy Mater."},{"key":"2026090104491733700_cit22","doi-asserted-by":"publisher","first-page":"3003","DOI":"10.1002\/(SICI)1099-0488(19991101)37:21&lt;3003::AID-POLB10&gt;3.0.CO;2-T","article-title":"Functionalized Polynorbornene Dielectric Polymers: Adhesion and Mechanical\nProperties","volume":"37","author":"Grove","year":"1999","journal-title":"J. Polym. Sci., Part B: Polym. Phys."},{"key":"2026090104491733700_cit23","doi-asserted-by":"publisher","first-page":"4226","DOI":"10.1021\/ma00042a030","article-title":"Addition Polymerization\nof Norbornene Catalyzed by Palladium(2+)\nCompounds. A Polymerization Reaction with Rare Chain Transfer and\nChain Termination","volume":"25","author":"Mehler","year":"1992","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit24","doi-asserted-by":"publisher","first-page":"6791","DOI":"10.1021\/acs.chemmater.5b03030","article-title":"Hydroxyhexafluoroisopropylnorbornene\nBlock and Random\nCopolymers via Vinyl Addition Polymerization and Their Application\nas Biobutanol Pervaporation Membranes","volume":"27","author":"Kim","year":"2015","journal-title":"Chem.\nMater."},{"key":"2026090104491733700_cit25","doi-asserted-by":"publisher","first-page":"394","DOI":"10.1016\/j.memsci.2018.10.041","article-title":"Anionic Multiblock Copolymer Membrane\nBased on Vinyl Addition Polymerization of Norbornenes: Applications\nin Anion-Exchange Membrane Fuel Cells","volume":"570\u2013571","author":"Mandal","year":"2019","journal-title":"J. Membr.\nSci."},{"key":"2026090104491733700_cit26","doi-asserted-by":"publisher","first-page":"479","DOI":"10.1002\/1521-3927(20010401)22:7&lt;479::AID-MARC479&gt;3.0.CO;2-C","article-title":"The Vinyl Homopolymerization of Norbornene","volume":"22","author":"Janiak","year":"2001","journal-title":"Macromol. Rapid Commun."},{"key":"2026090104491733700_cit27","doi-asserted-by":"publisher","first-page":"3678","DOI":"10.1021\/om030018t","article-title":"Vinyl Polymerization\nof Norbornene with Neutral Salicylaldiminato Nickel(II) Complexes","volume":"22","author":"Sun","year":"2003","journal-title":"Organometallics"},{"key":"2026090104491733700_cit28","doi-asserted-by":"publisher","first-page":"77","DOI":"10.1016\/j.reactfunctpolym.2003.11.007","article-title":"Random Copolymerizations\nof Norbornene with Other Monomers Catalyzed by Novel Ni Compounds\nInvolving N- or O-Donated Ligands","volume":"58","author":"Suzuki","year":"2004","journal-title":"React. Funct.\nPolym."},{"key":"2026090104491733700_cit29","doi-asserted-by":"publisher","first-page":"145","DOI":"10.1134\/S181123821901017X","article-title":"Norbornene Addition Polymerization\nwith Catalysts Based on Transition Metal Compounds: 2008\u20132018","volume":"61","author":"Suslov","year":"2019","journal-title":"Polym. Sci., Ser. C"},{"key":"2026090104491733700_cit30","doi-asserted-by":"publisher","first-page":"4588","DOI":"10.1021\/om060347w","article-title":"Syntheses\nand Structures\nof Bulky Monophosphine-Ligated Methylpalladium Complexes: Application\nto Homo- and Copolymerization of Norbornene and\/or Methoxycarbonylnorbornene","volume":"25","author":"Yamashita","year":"2006","journal-title":"Organometallics"},{"key":"2026090104491733700_cit31","doi-asserted-by":"publisher","first-page":"40676","DOI":"10.1021\/jacs.5c13303","article-title":"User-Friendly Living\nCoordination\u2013Insertion Polymerizations with Broad Functional\nGroup Tolerance","volume":"147","author":"Hsu","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026090104491733700_cit32","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202304778","article-title":"Direct\nInsertion Polymerization of\nIonic Monomers: Rapid Production of Anion Exchange Membranes","volume":"62","author":"Hsu","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090104491733700_cit33","doi-asserted-by":"publisher","first-page":"3","DOI":"10.1021\/acs.macromol.6b02355","article-title":"50th Anniversary Perspective: Block Polymers\u2500Pure\nPotential","volume":"50","author":"Bates","year":"2017","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit34","doi-asserted-by":"publisher","first-page":"243","DOI":"10.1021\/acsmacrolett.0c00855","article-title":"Geared Toward\nApplications: A Perspective on Functional Sequence-Controlled Polymers","volume":"10","author":"Yang","year":"2021","journal-title":"ACS Macro Lett."},{"key":"2026090104491733700_cit35","doi-asserted-by":"publisher","first-page":"16471","DOI":"10.1021\/jacs.5c03175","article-title":"Designing Highly\nConductive Anion\nExchange Membranes: Tuning Domain Continuity with ABC Block Copolymer\nSelf-Assembly","volume":"147","author":"Macbeth","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026090104491733700_cit36","doi-asserted-by":"publisher","first-page":"5199","DOI":"10.1021\/acs.macromol.0c00401","article-title":"Wavelength-Controlled\nSynthesis and Degradation of Thermoplastic Elastomers Based on Intrinsically\nPhotoresponsive Phenyl Vinyl Ketone","volume":"53","author":"De Alwis Watuthanthrige","year":"2020","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit37","doi-asserted-by":"publisher","first-page":"3865","DOI":"10.1021\/acs.orglett.5c00543","article-title":"Eliminating Bimolecular\nDecomposition to Address Sustainability in Cross-Coupling: Supported\nPd\u2013PEPPSI\u2013IPentCl","volume":"27","author":"Nnamdi","year":"2025","journal-title":"Org. Lett."},{"key":"2026090104491733700_cit38","doi-asserted-by":"publisher","first-page":"127","DOI":"10.1021\/cr5004375","article-title":"Deactivation\nin Homogeneous Transition Metal Catalysis: Causes, Avoidance, and\nCure","volume":"115","author":"Crabtree","year":"2015","journal-title":"Chem. Rev."},{"key":"2026090104491733700_cit39","doi-asserted-by":"publisher","first-page":"6355","DOI":"10.1039\/D1PY01039E","article-title":"Cocatalyst\nversus precatalyst impact on the vinyl-addition polymerization of\nnorbornenes with polar groups: looking at the other side of the coin","volume":"12","author":"Bermesheva","year":"2021","journal-title":"Polym. Chem."},{"key":"2026090104491733700_cit40","doi-asserted-by":"publisher","first-page":"5660","DOI":"10.1039\/D1CS01169C","article-title":"Synthetic\napplications of hydride abstractionreactions by organic oxidants","volume":"51","author":"Miller","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"2026090104491733700_cit41","doi-asserted-by":"publisher","first-page":"1128","DOI":"10.1039\/c3nj41145a","article-title":"Structure and Computational Studies\nof a Cationic T-Shaped Pd-Complex","volume":"37","author":"Walter","year":"2013","journal-title":"New J. Chem."},{"key":"2026090104491733700_cit43","doi-asserted-by":"publisher","first-page":"2802","DOI":"10.1021\/om010232m","article-title":"Novel,\nEfficient, Palladium-Based System for the Polymerization of Norbornene\nDerivatives: Scope and Mechanism","volume":"20","author":"Hennis","year":"2001","journal-title":"Organometallics"},{"key":"2026090104491733700_cit44","doi-asserted-by":"publisher","first-page":"6762","DOI":"10.1021\/acs.macromol.1c00858","article-title":"Synthesis of Vinyl-Addition Polynorbornene\nCopolymers\nBearing Pendant n-Alkyl Chains and Systematic Investigation\nof Their Properties","volume":"54","author":"Kim","year":"2021","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit45","doi-asserted-by":"publisher","first-page":"8969","DOI":"10.1021\/ma0209287","article-title":"Addition Polymerization\nof Norbornene-Type Monomers. High Activity Cationic Allyl Palladium\nCatalysts","volume":"35","author":"Lipian","year":"2002","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit46","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1002\/jlac.19244370102","article-title":"U\u0308ber\nSterische Hinderung in Bru\u0308ckenringen (Bredtsche Regel) Und\nU\u0308ber Die Meso-Trans-Stellung in Kondensierten Ringsystemen\nDes Hexamethylens","volume":"437","author":"Bredt","year":"1924","journal-title":"Justus Liebigs Ann. Chem."},{"key":"2026090104491733700_cit47","doi-asserted-by":"publisher","DOI":"10.1351\/goldbook.B00732","volume-title":"\u2018Bredt\u2019s rule\u2019 in IUPAC Compendium\nof Chemical\nTerminology","author":"International Union of Pure and Applied Chemistry.","year":"2025","edition":"5th"},{"key":"2026090104491733700_cit48","doi-asserted-by":"publisher","first-page":"2984","DOI":"10.1021\/ma702779a","article-title":"\u03b2, \u03b3-Carbon\u2013Carbon\nBond Cleavage\nas a Prelude to Chain Transfer in Ester-Functionalized Norbornene\nPolymerization","volume":"41","author":"McDermott","year":"2008","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit49","doi-asserted-by":"publisher","first-page":"13078","DOI":"10.1002\/chem.201706102","article-title":"Diversifying\nCross-Coupling Strategies,\nCatalysts and Monomers for the Controlled Synthesis of Conjugated\nPolymers","volume":"24","author":"Baker","year":"2018","journal-title":"Chem.\u2013Eur. J."},{"key":"2026090104491733700_cit50","doi-asserted-by":"publisher","first-page":"1822","DOI":"10.1021\/acsaem.2c03682","article-title":"Quaternized Polynorbornene Random\nCopolymers for Fuel Cell Devices","volume":"6","author":"Lehmann","year":"2023","journal-title":"ACS Appl.\nEnergy Mater."},{"key":"2026090104491733700_cit51","doi-asserted-by":"publisher","first-page":"200","DOI":"10.1002\/anie.199602001","article-title":"Chiral Phosphanyldihydrooxazoles\nin Asymmetric Catalysis: Enantioselective Heck Reactions","volume":"35","author":"Loiseleur","year":"1996","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090104491733700_cit52","doi-asserted-by":"publisher","first-page":"709","DOI":"10.1021\/ol9901063","article-title":"Highly Selective Palladium-Catalyzed\nHeck Reactions of Aryl Bromides with Cycloalkenes","volume":"1","author":"Hartung","year":"1999","journal-title":"Org. Lett."},{"key":"2026090104491733700_cit53","doi-asserted-by":"publisher","first-page":"2087","DOI":"10.1021\/ja952654r","article-title":"Dramatic Increase of Turnover Numbers\nin Palladium-Catalyzed Coupling Reactions Using High-Pressure Conditions","volume":"118","author":"Hillers","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"2026090104491733700_cit54","doi-asserted-by":"publisher","first-page":"6705","DOI":"10.1021\/ma971639z","article-title":"Addition Polymerization\nof Cyclopentene with Nickel and Palladium Catalysts","volume":"31","author":"McLain","year":"1998","journal-title":"Macromolecules"},{"key":"2026090104491733700_cit55","doi-asserted-by":"publisher","first-page":"14217","DOI":"10.1039\/D3SC02588H","article-title":"Visible light-induced palladium\u2013carbon\nbond weakening in catalytically relevant T-shaped complexes","volume":"14","author":"Waddell","year":"2023","journal-title":"Chem. Sci."}],"container-title":["Journal of the American\nChemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c07480","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/33\/35668\/66673657\/jacs.6c07480.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/33\/35668\/66673657\/jacs.6c07480.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T08:49:29Z","timestamp":1788252569000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/33\/35668\/5263791\/Expanding-the-Living-Polymerization-Toolkit"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,17]]},"references-count":54,"journal-issue":{"issue":"33","published-online":{"date-parts":[[2026,8,17]]},"published-print":{"date-parts":[[2026,8,26]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c07480","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,17]]}}}