{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T15:12:37Z","timestamp":1786547557828,"version":"build-2736575974"},"reference-count":54,"publisher":"American Chemical Society (ACS)","issue":"31","license":[{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Basic Research Program of China (973 Program)","doi-asserted-by":"crossref","award":["2023YFA1507601"],"award-info":[{"award-number":["2023YFA1507601"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China (NSFC)","doi-asserted-by":"crossref","award":["22205138"],"award-info":[{"award-number":["22205138"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China (NSFC)","doi-asserted-by":"crossref","award":["22301176"],"award-info":[{"award-number":["22301176"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China (NSFC)","doi-asserted-by":"crossref","award":["52373213"],"award-info":[{"award-number":["52373213"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Carbon capture and storage (CCS) with solid physical adsorbents has long been considered as an energy-efficient approach to mitigate anthropogenic carbon dioxide emissions. The quest for efficient porous sorbents for short-term CO2 storage and transport is still ongoing, as current materials possess certain limitations in terms of capacity, selectivity, and stability. In this work, capitalizing on the highly modular metal\u2013organic frameworks (MOFs), we designed and synthesized a highly porous and robust zirconium MOF (SJTU-520-Zr) by employing a tetratopic linker that bears a unique shape-persistent macrocycle moiety. This functional macrocycle unit serves as inherent CO2-philic apertures within a cubic topological framework featuring three-dimensional through-space channels, which collectively enable exceptional high-pressure CO2 capture and storage performance, achieving balanced gravimetric and volumetric capacities of 1.23 g g\u20131 and 0.56 g cm\u20133, respectively, at 25 bar and 298 K. This performance places SJTU-520-Zr among the top-tier sorbents for CO2 storage, yet distinguishes itself from those that rely solely on ultrahigh surface areas. Control experiments performed with SJTU-520-Y\u2500a fragile isostructural MOF constructed from hexanuclear Y6 clusters\u2500underscore that the exceptional performance relies critically on the preservation of 3D interconnected channels and unobstructed pore apertures. Contrast experiments combined with computational calculations unraveled a unique CO2-responsive \u201cgate-opening\u201d of the shape-persistent macrocycle unit driven by favorable \u03c0\u00b7\u00b7\u00b7\u03c0 interactions, which facilitate thermodynamic CO2 access into the framework. This work, therefore, provides a blueprint for the rational design and synthesis of bespoke materials featuring shape-persistent functionality tailored for challenging applications.<\/jats:p>","DOI":"10.1021\/jacs.6c07734","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:20:14Z","timestamp":1785849614000},"page":"33342-33351","source":"Crossref","is-referenced-by-count":0,"title":["Robust\nZirconium Metal\u2013Organic Framework Bearing\nThree-Dimensional Through-Space Channels and Shape-Persistent CO2-Philic Apertures for Exceptional CO2 Capture\nand Storage"],"prefix":"10.1021","volume":"148","author":[{"given":"Yuan","family":"Geng","sequence":"first","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-5826-0200","authenticated-orcid":true,"given":"Yuanlong","family":"Zhong","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingjing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pengfu","family":"Gao","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-8257-4978","authenticated-orcid":true,"given":"Yifei","family":"Gao","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-2617-5904","authenticated-orcid":true,"given":"Wenqiang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9232-7382","authenticated-orcid":true,"given":"Zhijie","family":"Chen","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7647-9666","authenticated-orcid":true,"given":"Yi","family":"Xie","sequence":"additional","affiliation":[{"name":"Independent Researcher , , ,","place":["Evanston, IL, United States, 60201"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1458-054X","authenticated-orcid":true,"given":"Wei","family":"Gong","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,30]]},"reference":[{"key":"2026081210081453500_cit1","doi-asserted-by":"publisher","first-page":"530","DOI":"10.1038\/nature05699","article-title":"Climate Sensitivity Constrained by\nCO2 Concentrations over the Past 420 Million Years","volume":"446","author":"Royer","year":"2007","journal-title":"Nature"},{"key":"2026081210081453500_cit2","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1016\/B978-0-12-819657-1.00001-3","article-title":"CO2 Emission Sources, Greenhouse Gases, and the Global Warming Effect","volume-title":"Advances in Carbon Capture","author":"Yoro","year":"2020"},{"key":"2026081210081453500_cit3","doi-asserted-by":"publisher","first-page":"1647","DOI":"10.1126\/science.1172246","article-title":"Carbon\nCapture and Storage: How Green Can Black Be?","volume":"325","author":"Haszeldine","year":"2009","journal-title":"Science"},{"key":"2026081210081453500_cit4","volume-title":"IPCC Special Report on Carbon Dioxide\nCapture and Storage","author":"Metz","year":"2005"},{"key":"2026081210081453500_cit5","doi-asserted-by":"publisher","first-page":"1652","DOI":"10.1126\/science.1176731","article-title":"Amine Scrubbing\nfor CO2 Capture","volume":"325","author":"Rochelle","year":"2009","journal-title":"Science"},{"key":"2026081210081453500_cit6","doi-asserted-by":"publisher","first-page":"303","DOI":"10.1557\/mrs2008.63","article-title":"Carbon Dioxide Capture\nand Storage","volume":"33","author":"Benson","year":"2008","journal-title":"MRS Bull."},{"key":"2026081210081453500_cit7","doi-asserted-by":"publisher","first-page":"6058","DOI":"10.1002\/anie.201000431","article-title":"Carbon Dioxide Capture: Prospects\nfor New Materials","volume":"49","author":"D\u2019Alessandro","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081210081453500_cit8","doi-asserted-by":"publisher","first-page":"9340","DOI":"10.1039\/D2CS00508E","article-title":"Carbon Dioxide Capture\nwith Zeotype Materials","volume":"51","author":"Fu","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"2026081210081453500_cit9","doi-asserted-by":"publisher","first-page":"8584","DOI":"10.1039\/D0CS00025F","article-title":"Industrial Carbon Dioxide Capture and Utilization:\nState of the Art and Future Challenges","volume":"49","author":"Gao","year":"2020","journal-title":"Chem.\nSoc. 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Chem."},{"key":"2026081210081453500_cit35","doi-asserted-by":"publisher","first-page":"3056","DOI":"10.1073\/pnas.1615172114","article-title":"Tailoring\nPorosity and Rotational Dynamics in a Series of Octacarboxylate Metal-Organic\nFrameworks","volume":"114","author":"Moreau","year":"2017","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"2026081210081453500_cit36","doi-asserted-by":"publisher","first-page":"2992","DOI":"10.1039\/c3cc40819a","article-title":"Simultaneously High\nGravimetric and Volumetric Methane Uptake Characteristics of the Metal-Organic\nFramework NU-111","volume":"49","author":"Peng","year":"2013","journal-title":"Chem. Commun."},{"key":"2026081210081453500_cit37","doi-asserted-by":"publisher","first-page":"11757","DOI":"10.1002\/anie.201905876","article-title":"Lock-and-Key\nand Shape-Memory Effects\nin an Unconventional Synthetic Path to Magnesium Metal-Organic Frameworks","volume":"58","author":"Yang","year":"2019","journal-title":"Angew. Chem., Int. 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Mater"},{"key":"2026081210081453500_cit41","doi-asserted-by":"publisher","first-page":"2141","DOI":"10.1021\/jacs.3c11733","article-title":"Chiral Reticular\nChemistry: A Tailored Approach Crafting Highly Porous and Hydrolytically\nRobust Metal-Organic Frameworks for Intelligent Humidity Control","volume":"146","author":"Gong","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210081453500_cit42","doi-asserted-by":"publisher","first-page":"3117","DOI":"10.1021\/jacs.1c12117","article-title":"Leveraging Chiral Zr(IV)-Based Metal-Organic Frameworks to Elucidate\nCatalytically Active Rh Species in Asymmetric Hydrogenation Reactions","volume":"144","author":"Gong","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210081453500_cit43","doi-asserted-by":"publisher","first-page":"3737","DOI":"10.1021\/jacs.2c00011","article-title":"Creating\nOptimal Pockets in a Clathrochelate-Based Metal-Organic Framework\nfor Gas Adsorption and Separation: Experimental and Computational\nStudies","volume":"144","author":"Gong","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210081453500_cit44","doi-asserted-by":"publisher","first-page":"2679","DOI":"10.1021\/jacs.2c13171","article-title":"Programmed\nPolarizability Engineering in a Cyclen-Based Cubic Zr(IV) Metal-Organic\nFramework to Boost Xe\/Kr Separation","volume":"145","author":"Gong","year":"2023","journal-title":"J. Am.\nChem. 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Ed."},{"key":"2026081210081453500_cit47","doi-asserted-by":"publisher","first-page":"13299","DOI":"10.1002\/chem.201202352","article-title":"Dye Encapsulation inside a New Mesoporous Metal-Organic\nFramework for Multifunctional Solvatochromic-Response Function","volume":"18","author":"Gru\u0308nker","year":"2012","journal-title":"Chem. - Eur. J."},{"key":"2026081210081453500_cit48","doi-asserted-by":"publisher","first-page":"8875","DOI":"10.1021\/ja9015765","article-title":"Storage of Hydrogen, Methane, and Carbon Dioxide in\nHighly Porous Covalent Organic Frameworks for Clean Energy Applications","volume":"131","author":"Furukawa","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210081453500_cit49","doi-asserted-by":"publisher","first-page":"12828","DOI":"10.1021\/ja506577g","article-title":"A Robust Binary\nSupramolecular Organic Framework (SOF) with High CO2 Adsorption\nand Selectivity","volume":"136","author":"Lu\u0308","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210081453500_cit50","doi-asserted-by":"publisher","first-page":"14457","DOI":"10.1021\/ja1042935","article-title":"Exceptional\nThermal Stability in a Supramolecular Organic Framework: Porosity\nand Gas Storage","volume":"132","author":"Yang","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"2026081210081453500_cit51","doi-asserted-by":"publisher","first-page":"369","DOI":"10.1021\/je049786x","article-title":"High-Pressure\nAdsorption Equilibria\nof Methane and Carbon Dioxide on Several Activated Carbons","volume":"50","author":"Himeno","year":"2005","journal-title":"J. Chem. Eng. Data"},{"key":"2026081210081453500_cit52","doi-asserted-by":"publisher","first-page":"1095","DOI":"10.1021\/je0498917","article-title":"Adsorption Equilibrium of Methane,\nCarbon Dioxide, and Nitrogen on Zeolite 13X at High Pressures","volume":"49","author":"Cavenati","year":"2004","journal-title":"J. Chem. Eng. 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Mater."}],"container-title":["Journal of the American\nChemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c07734","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/31\/33342\/66334912\/jacs.6c07734.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/31\/33342\/66334912\/jacs.6c07734.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T14:14:16Z","timestamp":1786544056000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/31\/33342\/5237035\/Robust-Zirconium-Metal-Organic-Framework-Bearing"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,30]]},"references-count":54,"journal-issue":{"issue":"31","published-online":{"date-parts":[[2026,7,30]]},"published-print":{"date-parts":[[2026,8,12]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c07734","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,30]]}}}