{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T14:06:21Z","timestamp":1785506781120,"version":"3.56.0"},"reference-count":49,"publisher":"American Chemical Society (ACS)","issue":"29","license":[{"start":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T00:00:00Z","timestamp":1784073600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100014988","name":"Institute of Science and Technology Austria","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100014988","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100016964","name":"Werner Siemens-Stiftung","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100016964","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,29]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Nanocrystal superlattices are commonly formed by changing concentration, solvent conditions, or particle surface chemistry. Although effective, these approaches alter multiple contributions to the interparticle potential simultaneously, making it difficult to isolate the interactions responsible for ordering or to control assembly in chemically complex environments. Here, we show that oligomeric species present in a nanocrystal reaction medium drive superlattice formation through a depletion mechanism. Using PbTe nanocrystals as a model system, we identify Pb\u2013oleate oligomers in the crude reaction mixture, characterize their solution structure, and quantify their contribution to the interparticle potential, establishing depletion as the dominant short-range interaction governing spontaneous body-centered cubic superlattice formation. We then confirm the depletion origin of ordering by showing that varying depletant concentration predictably shifts the order\u2013disorder boundary and produces a thermally reversible transition between dispersed and ordered states \u2500 behavior that is inconsistent with van der Waals or ligand-mediated mechanisms but is a direct consequence of depletion control. Having established and validated the mechanism, we demonstrate that the same depletion framework can be deliberately activated in purified dispersions and transferred across nanocrystal systems of different composition and shape, including anisotropic and binary assemblies. These results establish precursor-derived depletion as a general and chemically grounded mechanism for nanocrystal superlattice formation, and show that collective ordering can be programmed through the surrounding medium rather than through particle surface modification.<\/jats:p>","DOI":"10.1021\/jacs.6c07859","type":"journal-article","created":{"date-parts":[[2026,7,15]],"date-time":"2026-07-15T20:21:46Z","timestamp":1784146906000},"page":"31245-31252","source":"Crossref","is-referenced-by-count":0,"title":["Reaction Medium as\nan Architect of Nanocrystal Superlattices"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6962-8598","authenticated-orcid":true,"given":"Seungho","family":"Lee","sequence":"first","affiliation":[{"name":"Institute of Science and Technology Austria (ISTA) , ,","place":["Klosterneuburg, Austria, 3400"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7597-043X","authenticated-orcid":true,"given":"Daniel M.","family":"Balazs","sequence":"additional","affiliation":[{"name":"Institute of Science and Technology Austria (ISTA) , ,","place":["Klosterneuburg, Austria, 3400"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aiswarya","family":"Rayaroth","sequence":"additional","affiliation":[{"name":"Institute of Science and Technology Austria (ISTA) , ,","place":["Klosterneuburg, Austria, 3400"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sharona","family":"Horta","sequence":"additional","affiliation":[{"name":"Institute of Science and Technology Austria (ISTA) , ,","place":["Klosterneuburg, Austria, 3400"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carl P.","family":"Goodrich","sequence":"additional","affiliation":[{"name":"Institute of Science and Technology Austria (ISTA) , ,","place":["Klosterneuburg, Austria, 3400"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7031-3825","authenticated-orcid":true,"given":"Michael","family":"Engel","sequence":"additional","affiliation":[{"name":"Friedrich-Alexander-Universita\u0308t Erlangen-Nu\u0308rnberg; , , ,","place":["Erlangen, Germany, 91058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ihor","family":"Cherniukh","sequence":"additional","affiliation":[{"name":"Institute of Science and Technology Austria (ISTA) , ,","place":["Klosterneuburg, Austria, 3400"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5013-2843","authenticated-orcid":true,"given":"Maria","family":"Iba\u0301n\u0303ez","sequence":"additional","affiliation":[{"name":"Institute of Science and Technology Austria (ISTA) , ,","place":["Klosterneuburg, Austria, 3400"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,15]]},"reference":[{"issue":"36","key":"2026073109205587600_cit1","doi-asserted-by":"publisher","first-page":"31969","DOI":"10.1021\/acsnano.5c07838","article-title":"Prospects of Nanoscience with Nanocrystals:\n2025 Edition","volume":"19","author":"Iba\u0301n\u0303ez","year":"2025","journal-title":"ACS Nano"},{"issue":"18","key":"2026073109205587600_cit2","doi-asserted-by":"publisher","first-page":"11220","DOI":"10.1021\/acs.chemrev.6b00196","article-title":"Self-Assembly of\nColloidal Nanocrystals:\nFrom Intricate Structures to Functional Materials","volume":"116","author":"Boles","year":"2016","journal-title":"Chem. Rev."},{"issue":"5","key":"2026073109205587600_cit3","doi-asserted-by":"publisher","first-page":"453","DOI":"10.1038\/nnano.2015.68","article-title":"Nanoscale\nform dictates mesoscale function in plasmonic DNA\u2013nanoparticle\nsuperlattices","volume":"10","author":"Ross","year":"2015","journal-title":"Nat. Nanotechnol."},{"issue":"7860","key":"2026073109205587600_cit4","doi-asserted-by":"publisher","first-page":"535","DOI":"10.1038\/s41586-021-03492-5","article-title":"Perovskite-type superlattices from lead halide\nperovskite nanocubes","volume":"593","author":"Cherniukh","year":"2021","journal-title":"Nature"},{"issue":"5","key":"2026073109205587600_cit5","doi-asserted-by":"publisher","first-page":"522","DOI":"10.1038\/nmat4553","article-title":"Organically\nlinked iron oxide nanoparticle supercrystals\nwith exceptional isotropic mechanical properties","volume":"15","author":"Dreyer","year":"2016","journal-title":"Nat. Mater."},{"key":"2026073109205587600_cit6","doi-asserted-by":"publisher","first-page":"6420","DOI":"10.1038\/ncomms7420","article-title":"Fabrication of three-dimensionally\ninterconnected nanoparticle superlattices and their lithium-ion storage\nproperties","volume":"6","author":"Jiao","year":"2015","journal-title":"Nat. Commun."},{"issue":"44","key":"2026073109205587600_cit7","doi-asserted-by":"publisher","first-page":"15038","DOI":"10.1021\/jacs.8b09779","article-title":"Scalable\nAssembly of Crystalline Binary Nanocrystal\nSuperparticles and Their Enhanced Magnetic and Electrochemical Properties","volume":"140","author":"Yang","year":"2018","journal-title":"J. Am. Chem. Soc."},{"issue":"8","key":"2026073109205587600_cit8","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202207364","article-title":"Approaching Bulk Mobility in PbSe Colloidal Quantum\nDots 3D Superlattices","volume":"35","author":"Pinna","year":"2023","journal-title":"Adv. Mater."},{"issue":"1","key":"2026073109205587600_cit9","doi-asserted-by":"publisher","first-page":"4236","DOI":"10.1038\/s41467-019-12305-3","article-title":"Nanocrystal superlattices as phonon-engineered\nsolids and acoustic\nmetamaterials","volume":"10","author":"Yazdani","year":"2019","journal-title":"Nat. Commun."},{"issue":"23","key":"2026073109205587600_cit10","doi-asserted-by":"publisher","first-page":"14791","DOI":"10.1021\/acsnano.3c10201","article-title":"Nanocrystal\nAssemblies: Current Advances and Open Problems","volume":"18","author":"Bassani","year":"2024","journal-title":"ACS Nano"},{"issue":"34","key":"2026073109205587600_cit11","doi-asserted-by":"publisher","first-page":"11967","DOI":"10.1021\/ja103083q","article-title":"Energetic and Entropic\nContributions to Self-Assembly of Binary Nanocrystal Superlattices:\nTemperature as the Structure-Directing Factor","volume":"132","author":"Bodnarchuk","year":"2010","journal-title":"J. Am. Chem. Soc."},{"issue":"2","key":"2026073109205587600_cit12","doi-asserted-by":"publisher","first-page":"743","DOI":"10.1021\/nl903946n","article-title":"Assembly of colloidal semiconductor nanorods in solution by depletion\nattraction","volume":"10","author":"Baranov","year":"2010","journal-title":"Nano Lett."},{"issue":"51","key":"2026073109205587600_cit13","doi-asserted-by":"publisher","first-page":"16368","DOI":"10.1021\/acs.nanolett.4c04923","article-title":"Depletion-Induced Tunable Assembly\nof Complementary Platonic Solids","volume":"24","author":"Nag","year":"2024","journal-title":"Nano Lett."},{"issue":"15","key":"2026073109205587600_cit14","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adv2216","article-title":"Assessing depletion attractions between\ncolloidal nanocrystals","volume":"11","author":"Ofosu","year":"2025","journal-title":"Sci. Adv."},{"issue":"32","key":"2026073109205587600_cit15","doi-asserted-by":"publisher","first-page":"9983","DOI":"10.1021\/acs.nanolett.4c02636","article-title":"Predictive Modeling of Nanocrystal\nOrientation in Superlattices:\nInsights from Ligand Entropy","volume":"24","author":"Price","year":"2024","journal-title":"Nano Lett."},{"issue":"13","key":"2026073109205587600_cit16","doi-asserted-by":"publisher","first-page":"2406","DOI":"10.1021\/acs.jpclett.5b00946","article-title":"The Role of Ligand\nPacking Frustration in Body-Centered Cubic (bcc) Superlattices of\nColloidal Nanocrystals","volume":"6","author":"Goodfellow","year":"2015","journal-title":"J. Phys. Chem. Lett."},{"issue":"41","key":"2026073109205587600_cit17","doi-asserted-by":"publisher","first-page":"14476","DOI":"10.1021\/jacs.7b06908","article-title":"Regulating\nMultiple Variables To Understand the Nucleation and Growth and Transformation\nof PbS Nanocrystal Superlattices","volume":"139","author":"Wang","year":"2017","journal-title":"J. Am. Chem.\nSoc."},{"issue":"10","key":"2026073109205587600_cit18","doi-asserted-by":"publisher","first-page":"4250","DOI":"10.1021\/acs.nanolett.3c00299","article-title":"Temperature-Controlled\nReversible Formation and Phase Transformation of 3D Nanocrystal Superlattices\nThrough In Situ Small-Angle X-ray Scattering","volume":"23","author":"Marino","year":"2023","journal-title":"Nano Lett."},{"issue":"42","key":"2026073109205587600_cit19","doi-asserted-by":"publisher","first-page":"16651","DOI":"10.1021\/jacs.9b06010","article-title":"Revealing\nthe Effects of the Non-solvent on the Ligand Shell of Nanoparticles\nand Their Crystallization","volume":"141","author":"Lee","year":"2019","journal-title":"J. Am. Chem. Soc."},{"issue":"8","key":"2026073109205587600_cit20","doi-asserted-by":"publisher","first-page":"4500","DOI":"10.1021\/jacs.2c11120","article-title":"Diffusion-Mediated\nNucleation and\nGrowth of fcc and bcc Nanocrystal Superlattices with Designable Assembly\nof Freestanding 3D Supercrystals","volume":"145","author":"Huang","year":"2023","journal-title":"J. Am. Chem.\nSoc."},{"issue":"1","key":"2026073109205587600_cit21","doi-asserted-by":"publisher","first-page":"2802","DOI":"10.1038\/s41598-017-02121-4","article-title":"Superlattice growth and rearrangement\nduring evaporation-induced nanoparticle self-assembly","volume":"7","author":"Josten","year":"2017","journal-title":"Sci. Rep."},{"issue":"4","key":"2026073109205587600_cit22","doi-asserted-by":"publisher","first-page":"265","DOI":"10.1038\/nmat1611","article-title":"Kinetically driven\nself assembly of highly ordered\nnanoparticle monolayers","volume":"5","author":"Bigioni","year":"2006","journal-title":"Nat. Mater."},{"issue":"21","key":"2026073109205587600_cit23","doi-asserted-by":"publisher","first-page":"9675","DOI":"10.1021\/jacs.0c01809","article-title":"The Importance\nof Unbound Ligand\nin Nanocrystal Superlattice Formation","volume":"142","author":"Winslow","year":"2020","journal-title":"J. Am.\nChem. Soc."},{"issue":"12","key":"2026073109205587600_cit24","doi-asserted-by":"publisher","first-page":"20517","DOI":"10.1021\/acsnano.1c09073","article-title":"Ligand Dynamics\nin Nanocrystal Solids Studied with Quasi-Elastic Neutron Scattering","volume":"15","author":"Jansen","year":"2021","journal-title":"ACS Nano"},{"issue":"12","key":"2026073109205587600_cit25","doi-asserted-by":"publisher","first-page":"12778","DOI":"10.1021\/acsnano.8b07880","article-title":"Mechanistic Understanding of the Growth Kinetics and Dynamics of\nNanoparticle Superlattices by Coupling Interparticle Forces from Real-Time\nMeasurements","volume":"12","author":"Lee","year":"2018","journal-title":"ACS Nano"},{"issue":"13","key":"2026073109205587600_cit26","doi-asserted-by":"publisher","first-page":"5871","DOI":"10.1021\/jacs.1c12456","article-title":"In Situ Control of Crystallinity\nof 3D Colloidal Crystals\nby Tuning the Growth Kinetics of Nanoparticle Building Blocks","volume":"144","author":"Nakagawa","year":"2022","journal-title":"J. Am. Chem. Soc."},{"issue":"5","key":"2026073109205587600_cit27","doi-asserted-by":"publisher","first-page":"4382","DOI":"10.1021\/nn3010735","article-title":"One-Step Synthesis\nand Self-Assembly of Metal Oxide Nanoparticles into 3D Superlattices","volume":"6","author":"Pucci","year":"2012","journal-title":"ACS Nano"},{"issue":"17","key":"2026073109205587600_cit28","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202210749","article-title":"Rapid and Direct Liquid-Phase Synthesis of Luminescent Metal Halide\nSuperlattices","volume":"35","author":"Le","year":"2023","journal-title":"Adv. Mater."},{"issue":"2","key":"2026073109205587600_cit29","doi-asserted-by":"publisher","first-page":"667","DOI":"10.1021\/acs.nanolett.2c04532","article-title":"Growth\nand Self-Assembly of CsPbBr3 Nanocrystals in the TOPO\/PbBr2 Synthesis as Seen\nwith X-ray Scattering","volume":"23","author":"Montanarella","year":"2023","journal-title":"Nano Lett."},{"key":"2026073109205587600_cit30","doi-asserted-by":"publisher","first-page":"94907284","DOI":"10.26599\/NR.2025.94907284","article-title":"One-step preparation\nof three-dimensional superlattices during nanoparticle synthesis","volume":"18","author":"Saruyama","year":"2025","journal-title":"Nano Res."},{"issue":"7666","key":"2026073109205587600_cit31","doi-asserted-by":"publisher","first-page":"197","DOI":"10.1038\/nature23308","article-title":"High-temperature crystallization\nof nanocrystals into three-dimensional superlattices","volume":"548","author":"Wu","year":"2017","journal-title":"Nature"},{"issue":"32","key":"2026073109205587600_cit32","doi-asserted-by":"publisher","first-page":"2311714","DOI":"10.1002\/smll.202311714","article-title":"Direct synthesis of\nCuPd icosahedra supercrystals studied by in situ X-ray scattering","volume":"20","author":"Derelli","year":"2024","journal-title":"Small"},{"issue":"11","key":"2026073109205587600_cit33","doi-asserted-by":"publisher","first-page":"115504","DOI":"10.1103\/PhysRevLett.100.115504","article-title":"Gold nanoparticle\nsuperlattice crystallization\nprobed in situ","volume":"100","author":"Abecassis","year":"2008","journal-title":"Phys. Rev. Lett."},{"issue":"7","key":"2026073109205587600_cit34","doi-asserted-by":"publisher","first-page":"2425","DOI":"10.1039\/D3SC05085H","article-title":"Pseudomorphic amorphization of three-dimensional\nsuperlattices through morphological transformation of nanocrystal\nbuilding blocks","volume":"15","author":"Saruyama","year":"2024","journal-title":"Chem. Sci."},{"issue":"40","key":"2026073109205587600_cit35","doi-asserted-by":"publisher","first-page":"23416","DOI":"10.1039\/D5NR02550H","article-title":"Direct synthesis of three-dimensional Ag nanocrystal\nsuperlattices and their superhydrophobic films for a potential surface-enhanced\nRaman scattering substrate","volume":"17","author":"Zhu","year":"2025","journal-title":"Nanoscale"},{"key":"2026073109205587600_cit36","doi-asserted-by":"crossref","DOI":"10.1007\/978-3-031-52131-7","volume-title":"Colloids and the Depletion\nInteraction","author":"Lekkerkerker","year":"2024"},{"issue":"52","key":"2026073109205587600_cit37","doi-asserted-by":"publisher","first-page":"13980","DOI":"10.1002\/anie.201306009","article-title":"A directional entropic force approach to assemble anisotropic\nnanoparticles into superlattices","volume":"52","author":"Young","year":"2013","journal-title":"Angew. Chem.,\nInt. Ed."},{"issue":"4","key":"2026073109205587600_cit38","doi-asserted-by":"publisher","first-page":"1433","DOI":"10.1021\/nl100345u","article-title":"Depletion-induced shape and size\nselection of gold nanoparticles","volume":"10","author":"Park","year":"2010","journal-title":"Nano Lett."},{"issue":"5","key":"2026073109205587600_cit39","doi-asserted-by":"publisher","first-page":"2340","DOI":"10.1039\/C4DT03075C","article-title":"Coordination\ngeometry of lead carboxylates\n- spectroscopic and crystallographic evidence","volume":"44","author":"Catalano","year":"2015","journal-title":"Dalton Trans."},{"issue":"3","key":"2026073109205587600_cit40","doi-asserted-by":"publisher","first-page":"1303","DOI":"10.1021\/nl400084k","article-title":"Correlating superlattice\npolymorphs to internanoparticle distance, packing density, and surface\nlattice in assemblies of PbS nanoparticles","volume":"13","author":"Wang","year":"2013","journal-title":"Nano Lett."},{"issue":"1","key":"2026073109205587600_cit41","doi-asserted-by":"publisher","first-page":"459","DOI":"10.1016\/j.colsurfa.2004.06.039","article-title":"Solution behaviour of lead(II) carboxylates\nin organic solvents","volume":"250","author":"Burrows","year":"2004","journal-title":"Colloids Surf. A Physicochem.\nEng. Asp."},{"issue":"14","key":"2026073109205587600_cit42","doi-asserted-by":"publisher","first-page":"6974","DOI":"10.1021\/ac401623a","article-title":"The chemical\nenvironments of oleate\nspecies within samples of oleate-coated PbS quantum dots","volume":"85","author":"Cass","year":"2013","journal-title":"Anal. Chem."},{"issue":"3","key":"2026073109205587600_cit43","doi-asserted-by":"publisher","first-page":"221","DOI":"10.1021\/cr60223a001","article-title":"Properties\nof Organic Solutions of Heavy Metal Soaps","volume":"63","author":"Pilpel","year":"1963","journal-title":"Chem.\nRev."},{"issue":"17","key":"2026073109205587600_cit44","doi-asserted-by":"publisher","first-page":"4977","DOI":"10.1039\/D1SC06134H","article-title":"Persistent nucleation and size dependent attachment\nkinetics produce monodisperse PbS nanocrystals","volume":"13","author":"Abecassis","year":"2022","journal-title":"Chem. Sci."},{"issue":"7","key":"2026073109205587600_cit45","doi-asserted-by":"publisher","first-page":"1255","DOI":"10.1063\/1.1740347","article-title":"On Interaction between\nTwo Bodies Immersed in a Solution\nof Macromolecules","volume":"22","author":"Asakura","year":"1954","journal-title":"J. Chem. Phys."},{"issue":"25","key":"2026073109205587600_cit46","doi-asserted-by":"publisher","first-page":"9054","DOI":"10.1073\/pnas.1408835111","article-title":"Energy landscape of\nself-assembled superlattices of PbSe nanocrystals","volume":"111","author":"Quan","year":"2014","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"issue":"5","key":"2026073109205587600_cit47","doi-asserted-by":"publisher","first-page":"5744","DOI":"10.1103\/PhysRevE.59.5744","article-title":"Phase diagram of highly\nasymmetric\nbinary hard-sphere mixtures","volume":"59","author":"Dijkstra","year":"1999","journal-title":"Phys. Rev. E:Stat.,\nNonlinear, Soft Matter Phys."},{"issue":"9","key":"2026073109205587600_cit48","doi-asserted-by":"publisher","first-page":"3131","DOI":"10.1021\/ja110454b","article-title":"Controlling\nnanocrystal superlattice symmetry and shape-anisotropic interactions\nthrough variable ligand surface coverage","volume":"133","author":"Choi","year":"2011","journal-title":"J.\nAm. Chem. Soc."},{"issue":"45","key":"2026073109205587600_cit49","doi-asserted-by":"publisher","first-page":"E4812","DOI":"10.1073\/pnas.1418159111","article-title":"Understanding shape entropy through local dense packing","volume":"111","author":"van Anders","year":"2014","journal-title":"Proc. Natl. Acad. Sci. U.S.A."}],"container-title":["Journal of the American\nChemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c07859","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/29\/31245\/66344013\/jacs.6c07859.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/29\/31245\/66344013\/jacs.6c07859.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T13:21:06Z","timestamp":1785504066000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/29\/31245\/5237471\/Reaction-Medium-as-an-Architect-of-Nanocrystal"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,15]]},"references-count":49,"journal-issue":{"issue":"29","published-online":{"date-parts":[[2026,7,15]]},"published-print":{"date-parts":[[2026,7,29]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c07859","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,15]]}}}