{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T15:26:36Z","timestamp":1787153196551,"version":"build-2736575974"},"reference-count":79,"publisher":"American Chemical Society (ACS)","issue":"32","license":[{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100004147","name":"Tsinghua University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004147","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Basic Research Program of China (973 Program)","doi-asserted-by":"crossref","award":["2022YFA1503900"],"award-info":[{"award-number":["2022YFA1503900"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China (NSFC)","doi-asserted-by":"crossref","award":["22272087"],"award-info":[{"award-number":["22272087"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China (NSFC)","doi-asserted-by":"crossref","award":["92477122"],"award-info":[{"award-number":["92477122"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,19]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Zeolite-supported gold catalysts exhibit exceptional performance across a range of industrially relevant reactions. While previous research has predominantly focused on optimizing catalyst structures through static synthesis parameters, the dynamic structural transformations of Au species under reaction conditions and their subsequent catalytic implications remain largely unexplored. Herein, we utilize advanced electron microscopy and spectroscopy to track the reaction-driven structural evolution of Au nanoclusters supported on hierarchical TS-1 zeolite during the direct epoxidation of propylene with H2 and O2. Comprehensive catalytic and characterization analyses reveal that these structural transformations are actively driven by complex interactions among the Au nanoclusters, the Na promoter, and the in situ-formed oxygenate products. Remarkably, using this direct epoxidation reaction feed as a targeted pretreatment enhances the catalytic performance of the Au-zeolite catalysts by 2- to 4-fold across a broad range of oxidation reactions, including CO oxidation, the selective oxidation of ethanol to acetaldehyde, the selective oxidation of methane to acetic acid, and the oxidation of silane to silanol. These findings establish that exposure to a reactive atmosphere can serve as a powerful, generalized strategy to intentionally modulate the structural features and amplify the catalytic properties of zeolite-supported metal catalysts.<\/jats:p>","DOI":"10.1021\/jacs.6c08430","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T13:04:29Z","timestamp":1785935069000},"page":"34456-34471","source":"Crossref","is-referenced-by-count":0,"title":["Harnessing Reaction-Driven\nStructural Evolution of\nZeolite-Supported Gold Catalyst for Selective Oxidation Reactions"],"prefix":"10.1021","volume":"148","author":[{"given":"Feng","family":"He","sequence":"first","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-7135-4406","authenticated-orcid":true,"given":"Wenying","family":"Li","sequence":"additional","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianxiang","family":"Chen","sequence":"additional","affiliation":[{"name":"The Hong Kong Polytechnic University , , Hunghom , ,","place":["Hong Kong, China, QR702"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alina","family":"Skorynina","sequence":"additional","affiliation":[{"name":"ALBA Synchrotron Light Source , Cerdanyola del Valle\u0300s , ,","place":["Barcelona, Spain, 08290"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5067-0481","authenticated-orcid":true,"given":"Lichen","family":"Liu","sequence":"additional","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]},{"name":"Ordos Laboratory , , ,","place":["Ordos, Inner Mongolia, China, 017000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,5]]},"reference":[{"issue":"11","key":"2026081910251391400_cit1","doi-asserted-by":"publisher","first-page":"1030","DOI":"10.1038\/s41929-022-00870-8","article-title":"Enhanced\nCO2 utilization in dry reforming\nof methane achieved through nickel-mediated hydrogen spillover in\nzeolite crystals","volume":"5","author":"Zhu","year":"2022","journal-title":"Nat. Catal."},{"issue":"24","key":"2026081910251391400_cit2","doi-asserted-by":"publisher","first-page":"7484","DOI":"10.1021\/jacs.6b03518","article-title":"In Situ Confinement\nof Ultrasmall Pd Clusters within Nanosized Silicalite-1 Zeolite for\nHighly Efficient Catalysis of Hydrogen Generation","volume":"138","author":"Wang","year":"2016","journal-title":"J. Am. Chem. Soc."},{"issue":"44","key":"2026081910251391400_cit3","doi-asserted-by":"publisher","first-page":"19450","DOI":"10.1002\/anie.202003349","article-title":"Subnanometer\nBimetallic Platinum\u2013Zinc Clusters in Zeolites for Propane Dehydrogenation","volume":"59","author":"Sun","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"issue":"41","key":"2026081910251391400_cit4","doi-asserted-by":"publisher","first-page":"13514","DOI":"10.1021\/jacs.8b09568","article-title":"Zeolite-Encapsulated\nPt Nanoparticles for Tandem Catalysis","volume":"140","author":"Cho","year":"2018","journal-title":"J. Am.\nChem. Soc."},{"issue":"20","key":"2026081910251391400_cit5","doi-asserted-by":"publisher","first-page":"12278","DOI":"10.1021\/acs.chemrev.1c00243","article-title":"Metal\u2013Organic\nFramework-Based Hierarchically Porous Materials: Synthesis and Applications","volume":"121","author":"Cai","year":"2021","journal-title":"Chem. Rev."},{"issue":"7855","key":"2026081910251391400_cit6","doi-asserted-by":"publisher","first-page":"551","DOI":"10.1038\/s41586-021-03410-9","article-title":"A highly stable and\nflexible zeolite electrolyte solid-state Li\u2013air battery","volume":"592","author":"Chi","year":"2021","journal-title":"Nature"},{"issue":"7824","key":"2026081910251391400_cit7","doi-asserted-by":"publisher","first-page":"221","DOI":"10.1038\/s41586-020-2671-4","article-title":"Rare-earth\u2013platinum alloy\nnanoparticles in mesoporous zeolite for catalysis","volume":"585","author":"Ryoo","year":"2020","journal-title":"Nature"},{"issue":"9","key":"2026081910251391400_cit8","doi-asserted-by":"publisher","first-page":"6039","DOI":"10.1021\/acs.chemrev.2c00315","article-title":"Metal Sites in Zeolites:\nSynthesis, Characterization,\nand Catalysis","volume":"123","author":"Zhang","year":"2023","journal-title":"Chem. 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Lett."},{"issue":"4","key":"2026081910251391400_cit14","doi-asserted-by":"publisher","first-page":"3311","DOI":"10.1021\/acscatal.8b04798","article-title":"Reversible\nMetal Aggregation and Redispersion Driven by the Catalytic Water Gas\nShift Half-Reactions: Interconversion of Single-Site Rhodium Complexes\nand Tetrarhodium Clusters in Zeolite HY","volume":"9","author":"Fang","year":"2019","journal-title":"ACS\nCatal."},{"issue":"2","key":"2026081910251391400_cit15","doi-asserted-by":"publisher","first-page":"99","DOI":"10.1038\/s41929-021-00729-4","article-title":"Induced activation of the commercial Cu\/ZnO\/Al2O3 catalyst for the steam reforming of methanol","volume":"5","author":"Li","year":"2022","journal-title":"Nat. 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Soc."},{"key":"2026081910251391400_cit28","doi-asserted-by":"publisher","first-page":"329","DOI":"10.1163\/156856798X00276","article-title":"Selective Oxidation\nof Propylene over Gold Deposited on Titanium-based Oxides","volume":"24","author":"Haruta","year":"1998","journal-title":"Res. Chem. lntermed."},{"key":"2026081910251391400_cit29","doi-asserted-by":"publisher","first-page":"144895","DOI":"10.1016\/j.cej.2023.144895","article-title":"Synthesis\nstrategy of atomically dispersed Au clusters induced by\nNH3 on TS-1: Significantly improve the epoxidation activity\nof propylene","volume":"472","author":"Peng","year":"2023","journal-title":"Chem. Eng. J."},{"issue":"1","key":"2026081910251391400_cit30","doi-asserted-by":"publisher","first-page":"3249","DOI":"10.1038\/s41467-024-47538-4","article-title":"Nanoparticles as an\nantidote for poisoned gold single-atom catalysts in sustainable propylene\nepoxidation","volume":"15","author":"Wang","year":"2024","journal-title":"Nat. Commun."},{"issue":"10","key":"2026081910251391400_cit31","doi-asserted-by":"publisher","first-page":"2327","DOI":"10.1021\/jacsau.2c00380","article-title":"Confining Gold Nanoparticles in Preformed Zeolites by Post-Synthetic\nModification Enhances Stability and Catalytic Reactivity and Selectivity","volume":"2","author":"Eom","year":"2022","journal-title":"JACS Au"},{"issue":"33","key":"2026081910251391400_cit32","doi-asserted-by":"publisher","first-page":"18185","DOI":"10.1002\/anie.202104952","article-title":"Precisely Engineered Supported Gold\nClusters as a Stable Catalyst for Propylene Epoxidation","volume":"60","author":"Kapil","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"issue":"5","key":"2026081910251391400_cit33","doi-asserted-by":"publisher","first-page":"1598","DOI":"10.1039\/D1CY02270A","article-title":"Migration of zeolite-encapsulated Pt and Au under reducing\nenvironments","volume":"12","author":"Hou","year":"2022","journal-title":"Catal. Sci. Technol."},{"key":"2026081910251391400_cit34","doi-asserted-by":"publisher","first-page":"517","DOI":"10.1126\/science.abe3558","article-title":"In situ manipulation\nof the active Au-TiO2 interface with\natomic precision during CO oxidation","volume":"371","author":"Yuan","year":"2021","journal-title":"Science"},{"issue":"5","key":"2026081910251391400_cit35","doi-asserted-by":"publisher","first-page":"761","DOI":"10.1038\/s44160-025-00988-0","article-title":"A gold catalyst stabilized in an\nopen-porosity TS-1 zeolite for the direct epoxidation of propylene","volume":"5","author":"He","year":"2026","journal-title":"Nat. Synth."},{"key":"2026081910251391400_cit36","doi-asserted-by":"publisher","first-page":"7841","DOI":"10.1021\/jp072873m","article-title":"Mechanistic Implications\nof Aun\/Ti-Lattice Proximity for Propylene Epoxidation","volume":"111","author":"Joshi","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"2026081910251391400_cit37","doi-asserted-by":"publisher","first-page":"105","DOI":"10.1016\/j.jcat.2018.06.015","article-title":"Propylene\noxide inhibits propylene epoxidation over Au\/TS-1","volume":"365","author":"Harris","year":"2018","journal-title":"J. Catal."},{"key":"2026081910251391400_cit38","doi-asserted-by":"publisher","first-page":"284","DOI":"10.1016\/j.jcat.2016.03.019","article-title":"Kinetic\nstudy of propene oxide and water formation\nin hydro-epoxidation of propene on Au\/Ti\u2013SiO2 catalyst","volume":"338","author":"Kanungo","year":"2016","journal-title":"J. Catal."},{"issue":"29","key":"2026081910251391400_cit39","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300319","article-title":"Carbon\nDeposit Analysis in Catalyst\nDeactivation, Regeneration, and Rejuvenation","volume":"62","author":"Vogt","year":"2023","journal-title":"Angew. Chem., Int. 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Phys."},{"issue":"21","key":"2026081910251391400_cit44","doi-asserted-by":"publisher","first-page":"5562","DOI":"10.1039\/b925206a","article-title":"EXAFS as a tool to interrogate the size and shape of\nmono and bimetallic catalyst nanoparticles","volume":"12","author":"Beale","year":"2010","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026081910251391400_cit45","doi-asserted-by":"publisher","first-page":"2548","DOI":"10.1021\/jp066005l","article-title":"Redox Behavior of Gold Species in Zeolite NaY: Characterization\nby Infrared Spectroscopy of Adsorbed CO","volume":"111","author":"Mihaylov","year":"2007","journal-title":"J.\nPhys. Chem. C"},{"issue":"6","key":"2026081910251391400_cit46","doi-asserted-by":"publisher","first-page":"795","DOI":"10.1002\/cite.200700029","article-title":"Characterization\nof the Oxidation States of Supported Gold Species by IR Spectroscopy\nof Adsorbed CO","volume":"79","author":"Mihaylov","year":"2007","journal-title":"Chem. Ing. Technol."},{"key":"2026081910251391400_cit47","doi-asserted-by":"publisher","first-page":"1720","DOI":"10.1021\/ar3002427","article-title":"Sintering of Catalytic\nNanoparticles: Particle Migration or Ostwald Ripening?","volume":"46","author":"Hansen","year":"2013","journal-title":"Acc. Chem. Res."},{"issue":"10","key":"2026081910251391400_cit48","doi-asserted-by":"publisher","first-page":"4455","DOI":"10.1021\/acs.chemrev.9b00417","article-title":"Chemical\nand Thermal Sintering of Supported Metals with Emphasis on Cobalt\nCatalysts During Fischer\u2013Tropsch Synthesis","volume":"120","author":"Rahmati","year":"2020","journal-title":"Chem. Rev."},{"issue":"41","key":"2026081910251391400_cit49","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409784","article-title":"Boosting the Stability of Subnanometer Pt Catalysts by the Presence\nof Framework Indium(III) Sites in Zeolite","volume":"63","author":"Zhu","year":"2024","journal-title":"Angew.\nChem., Int. Ed."},{"key":"2026081910251391400_cit50","doi-asserted-by":"publisher","first-page":"497","DOI":"10.1126\/science.adu6907","article-title":"A self-regenerating\nPt\/Ge-MFI zeolite for propane dehydrogenation with high endurance","volume":"388","author":"Hong","year":"2025","journal-title":"Science"},{"issue":"6216","key":"2026081910251391400_cit51","doi-asserted-by":"publisher","first-page":"1498","DOI":"10.1126\/science.1260526","article-title":"Catalytically\nactive Au-O(OH)x-species stabilized by alkali ions on zeolites\nand mesoporous oxides","volume":"346","author":"Yang","year":"2014","journal-title":"Science"},{"issue":"17","key":"2026081910251391400_cit52","doi-asserted-by":"publisher","first-page":"8155","DOI":"10.1021\/acs.iecr.9b07011","article-title":"Dual-Component\nSodium and Cesium Promoters for Au\/TS-1: Enhancement\nof Propene Epoxidation with Hydrogen and Oxygen","volume":"59","author":"Ren","year":"2020","journal-title":"Ind. Eng. Chem. 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