{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T14:36:29Z","timestamp":1787150189008,"version":"build-2736575974"},"reference-count":59,"publisher":"American Chemical Society (ACS)","issue":"32","license":[{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100005145","name":"Basic Research Program of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20250050"],"award-info":[{"award-number":["BK20250050"]}],"id":[{"id":"10.13039\/501100005145","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012462","name":"Collaborative Innovation Center of Suzhou Nano Science and Technology","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100012462","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013314","name":"Higher Education Discipline Innovation Project","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100013314","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22472111"],"award-info":[{"award-number":["22472111"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["W2512052"],"award-info":[{"award-number":["W2512052"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,19]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Four-electron aqueous zinc\u2013iodine (Zn\u2013I2) batteries with I\u2013\/I0\/I+ conversion could achieve high energy density, but the development is largely impeded by I+ hydrolysis and sluggish redox kinetics. Here, by introducing 1-ethylpyridine hydrobromide (EB) as an electrolyte additive, we designed aqueous zinc\u2013dual halogen (iodine\u2013bromine) batteries to address these issues, which enable reversible six-electron conversion with high capacity and long-term cycling stability. In situ X-ray absorption spectroscopy, Raman spectroscopy, and theoretical calculations reveal that the donor\u2013acceptor interactions within I\u2013Br interhalogen compounds induce an electron push\u2013pull effect, enabling a kinetically enhanced four-electron pathway (I\u2013\/I2Br\u2013\/IBr2\u2013) followed by an activated two-electron pathway of bromine (IBr2\u2013\/IBr3\u2013) upon charging, while partial IBr3\u2013 undergoes an I+\/Br0 co-reduction reaction with enhanced bromine utilization during discharge, leading to asymmetric yet overall reversible six-electron conversion. In addition, the cation groups of EB reconstruct the H-bond network of bulk water and electrostatically anchor IBr2\u2013 and IBr3\u2013 species, thereby reducing the water activity and stabilizing the interhalogen compounds. These synergistic effects enable zinc\u2013dual halogen batteries to achieve a remarkable capacity of 656 mAh g\u20131 at 0.5 A g\u20131 and sustained cycling stability with a high initial capacity of 436.8 mAh g\u20131 over 2200 cycles at 10 A g\u20131. This work extends the application of interhalogen chemistry for constructing high-energy-density aqueous batteries with multielectron redox reactions.<\/jats:p>","DOI":"10.1021\/jacs.6c08547","type":"journal-article","created":{"date-parts":[[2026,8,6]],"date-time":"2026-08-06T03:11:38Z","timestamp":1785985898000},"page":"34472-34484","source":"Crossref","is-referenced-by-count":0,"title":["Electron Push\u2013Pull\nEffect Drives Reversible\nSix-Electron Redox Reaction in Aqueous Zinc\u2013Dual Halogen Batteries"],"prefix":"10.1021","volume":"148","author":[{"given":"Shiqi","family":"Shen","sequence":"first","affiliation":[{"name":"Soochow University , , , ,","place":["Suzhou, Jiangsu, China, 215123"]},{"name":"Suzhou Laboratory , , ,","place":["Suzhou, Jiangsu, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianran","family":"Yan","sequence":"additional","affiliation":[{"name":"Soochow University , , , ,","place":["Suzhou, Jiangsu, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shusheng","family":"Huang","sequence":"additional","affiliation":[{"name":"Soochow University , , , ,","place":["Suzhou, Jiangsu, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Wang","sequence":"additional","affiliation":[{"name":"Soochow University , , , ,","place":["Suzhou, Jiangsu, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongniu","family":"Wang","sequence":"additional","affiliation":[{"name":"Suzhou Laboratory , , ,","place":["Suzhou, Jiangsu, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3446-3172","authenticated-orcid":true,"given":"Liang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Soochow University , , , ,","place":["Suzhou, Jiangsu, China, 215123"]},{"name":"Soochow University , , , ,","place":["Suzhou, Jiangsu, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,5]]},"reference":[{"key":"2026081910225423600_cit1","doi-asserted-by":"publisher","first-page":"928","DOI":"10.1126\/science.1212741","article-title":"Electrical energy storage for the\ngrid: a battery of choices","volume":"334","author":"Dunn","year":"2011","journal-title":"Science"},{"key":"2026081910225423600_cit2","doi-asserted-by":"publisher","first-page":"1355","DOI":"10.1038\/s41560-023-01370-0","article-title":"An active and durable\nmolecular catalyst for aqueous\npolysulfide-based redox flow batteries","volume":"8","author":"Lei","year":"2023","journal-title":"Nat.\nEnergy"},{"key":"2026081910225423600_cit3","doi-asserted-by":"publisher","first-page":"582","DOI":"10.1038\/s41560-020-00772-8","article-title":"Assessment methods\nand performance metrics for redox flow batteries","volume":"6","author":"Yao","year":"2021","journal-title":"Nat. Energy"},{"key":"2026081910225423600_cit4","doi-asserted-by":"publisher","first-page":"3577","DOI":"10.1021\/cr100290v","article-title":"Electrochemical energy storage for\ngreen grid","volume":"111","author":"Yang","year":"2011","journal-title":"Chem. Rev."},{"key":"2026081910225423600_cit5","doi-asserted-by":"publisher","first-page":"1415","DOI":"10.1016\/j.joule.2023.06.007","article-title":"Zinc-ion batteries\nfor stationary energy storage","volume":"7","author":"Gourley","year":"2023","journal-title":"Joule"},{"key":"2026081910225423600_cit6","doi-asserted-by":"publisher","first-page":"543","DOI":"10.1038\/s41563-018-0063-z","article-title":"Highly reversible\nzinc metal anode for aqueous batteries","volume":"17","author":"Wang","year":"2018","journal-title":"Nat.\nMater."},{"issue":"6465","key":"2026081910225423600_cit7","doi-asserted-by":"publisher","first-page":"645","DOI":"10.1126\/science.aax6873","article-title":"Reversible epitaxial electrodeposition of metals in\nbattery anodes","volume":"366","author":"Zheng","year":"2019","journal-title":"Science"},{"issue":"23","key":"2026081910225423600_cit8","doi-asserted-by":"publisher","first-page":"2108856","DOI":"10.1002\/adma.202108856","article-title":"Recent advances of aqueous rechargeable zinc-iodine\nbatteries: challenges,\nsolutions, and prospects","volume":"34","author":"Lin","year":"2022","journal-title":"Adv. Mater."},{"issue":"23","key":"2026081910225423600_cit9","doi-asserted-by":"publisher","first-page":"2201716","DOI":"10.1002\/adma.202201716","article-title":"Polyiodide confinement\nby starch enables shuttle-free Zn\u2013iodine batteries","volume":"34","author":"Zhang","year":"2022","journal-title":"Adv. Mater."},{"issue":"13","key":"2026081910225423600_cit10","doi-asserted-by":"publisher","first-page":"2105598","DOI":"10.1002\/advs.202105598","article-title":"A universal\npolyiodide regulation using quaternization engineering\ntoward high value-added and ultra-stable zinc-iodine batteries","volume":"9","author":"Zhang","year":"2022","journal-title":"Adv. Sci."},{"issue":"1","key":"2026081910225423600_cit11","doi-asserted-by":"publisher","first-page":"170","DOI":"10.1038\/s41467-020-20331-9","article-title":"A four-electron Zn-I2 aqueous\nbattery enabled by reversible I\u2013\/I2\/I+ conversion","volume":"12","author":"Zou","year":"2021","journal-title":"Nat.\nCommun."},{"issue":"31","key":"2026081910225423600_cit12","doi-asserted-by":"publisher","first-page":"21377","DOI":"10.1021\/jacs.4c03615","article-title":"Dynamical\nJanus interface design for reversible and fast-charging zinc\u2013iodine\nbattery under extreme operating conditions","volume":"146","author":"Zong","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"2026081910225423600_cit13","doi-asserted-by":"publisher","first-page":"1257","DOI":"10.1021\/ja01321a001","article-title":"The hydrolysis\nof iodine monochloride","volume":"56","author":"Philbrick","year":"1934","journal-title":"J. Am. Chem. Soc."},{"issue":"6","key":"2026081910225423600_cit14","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202513389","article-title":"Dual-electrode synergistic\nelectrolyte enabling highly reversible multi-electron redox in aqueous\nzinc-iodine batteries","volume":"38","author":"Chen","year":"2025","journal-title":"Adv. Mater."},{"key":"2026081910225423600_cit15","doi-asserted-by":"publisher","first-page":"79","DOI":"10.1007\/s40820-025-01928-5","article-title":"\u201cProton-Iodine\u201d regulation of protonated polyaniline\ncatalyst for high-performance electrolytic Zn-I2 batteries","volume":"18","author":"Liu","year":"2026","journal-title":"Nano Micro Lett."},{"key":"2026081910225423600_cit16","doi-asserted-by":"publisher","first-page":"323","DOI":"10.1039\/D3EE03297C","article-title":"Synergistic\neffects of Lewis acid\u2013base\nand Coulombic interactions for high-performance Zn\u2013I2 batteries","volume":"17","author":"He","year":"2024","journal-title":"Energy Environ. Sci."},{"issue":"25","key":"2026081910225423600_cit17","doi-asserted-by":"publisher","first-page":"21686","DOI":"10.1021\/jacs.5c03581","article-title":"Discovery\nof high-capacity asymmetric three-stage redox reactions of iodine\nfor aqueous batteries","volume":"147","author":"Xie","year":"2025","journal-title":"J. Am. Chem. Soc."},{"issue":"42","key":"2026081910225423600_cit18","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202514375","article-title":"Synergistic Effects of Electrolyte\nAdditives in a Dual-Salt System\nfor High-Performance Four Electron Aqueous Zinc\u2013Iodine Batteries\nAcross a Wide Temperature Range","volume":"64","author":"Luo","year":"2025","journal-title":"Angew. Chem.,\nInt. Ed."},{"issue":"1","key":"2026081910225423600_cit19","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202410988","article-title":"Iodine\/Chlorine multi-electron conversion realizes high energy density\nzinc-iodine batteries","volume":"12","author":"Zhao","year":"2025","journal-title":"Adv. Sci."},{"issue":"25","key":"2026081910225423600_cit20","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202403187","article-title":"Activating and stabilizing\na reversible four electron redox reaction\nof I\u2013\/I+ for aqueous Zn-iodine battery","volume":"63","author":"Wang","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"issue":"46","key":"2026081910225423600_cit21","doi-asserted-by":"publisher","first-page":"2415979","DOI":"10.1002\/adma.202415979","article-title":"All-climate energy-dense cascade aqueous Zn-I2 batteries\nenabled by a polycationic hydrogel electrolyte","volume":"37","author":"Liu","year":"2025","journal-title":"Adv. Mater."},{"key":"2026081910225423600_cit22","doi-asserted-by":"publisher","first-page":"3357","DOI":"10.1039\/D3SC06155H","article-title":"Stabilized four-electron\naqueous zinc\u2013iodine batteries by\nquaternary ammonium complexation","volume":"15","author":"Jiang","year":"2024","journal-title":"Chem. Sci."},{"key":"2026081910225423600_cit23","doi-asserted-by":"publisher","first-page":"18435","DOI":"10.1021\/jacs.2c06927","article-title":"Halogenated Zn2+ solvation\nstructure for reversible Zn metal batteries","volume":"144","author":"Zhang","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026081910225423600_cit24","doi-asserted-by":"publisher","first-page":"7838","DOI":"10.1021\/ja00202a026","article-title":"Kinetics of hydrolysis of iodine\nmonochloride measured by the pulsed-accelerated-flow method","volume":"111","author":"Wang","year":"1989","journal-title":"J. Am. Chem. Soc."},{"issue":"26","key":"2026081910225423600_cit25","doi-asserted-by":"publisher","first-page":"2401924","DOI":"10.1002\/adma.202401924","article-title":"Halide exchange in perovskites enables bromine\/iodine\nhybrid cathodes for highly durable zinc ion batteries","volume":"36","author":"Wang","year":"2024","journal-title":"Adv. Mater."},{"issue":"1","key":"2026081910225423600_cit26","doi-asserted-by":"publisher","first-page":"6738","DOI":"10.1038\/s41467-023-42549-z","article-title":"Manipulating\ncoordination environment for a high-voltage aqueous copper-chlorine\nbattery","volume":"14","author":"Zhang","year":"2023","journal-title":"Nat. Commun."},{"issue":"47","key":"2026081910225423600_cit27","doi-asserted-by":"publisher","first-page":"11312","DOI":"10.1002\/chem.201701555","article-title":"From square-planar\n[ICl4]\u2212 to novel chloroiodates (III)?\nA systematic experimental and theoretical investigation of their ionic\nliquids","volume":"23","author":"Burgenmeister","year":"2017","journal-title":"Chem.\u2013Eur. J."},{"key":"2026081910225423600_cit28","doi-asserted-by":"publisher","first-page":"20389","DOI":"10.1021\/acsnano.2c06362","article-title":"A high-performance\nquasi-solid-state aqueous zinc-dual halogen battery","volume":"16","author":"Lv","year":"2022","journal-title":"ACS Nano"},{"issue":"18","key":"2026081910225423600_cit29","doi-asserted-by":"publisher","first-page":"2312246","DOI":"10.1002\/adma.202312246","article-title":"Development of inverse-opal-structured charge-deficient Co9S8@ nitrogen-doped-carbon to catalytically enable high\nenergy and high power for the two-electron transfer I+\/I\u2013 electrode","volume":"36","author":"Hu","year":"2024","journal-title":"Adv. Mater."},{"key":"2026081910225423600_cit30","doi-asserted-by":"publisher","first-page":"104487","DOI":"10.1016\/j.ensm.2025.104487","article-title":"A dilute kosmotropic\neutectic electrolyte for practical\nfour-electron aqueous Zn-Iodine batteries","volume":"81","author":"Li","year":"2025","journal-title":"Energy\nStorage Mater."},{"issue":"32","key":"2026081910225423600_cit31","doi-asserted-by":"publisher","first-page":"2405473","DOI":"10.1002\/adma.202405473","article-title":"Aqueous electrolyte with weak hydrogen bonds for four-electron zinc\u2013iodine\nbattery operates in a wide temperature range","volume":"36","author":"Liu","year":"2024","journal-title":"Adv. Mater."},{"key":"2026081910225423600_cit32","doi-asserted-by":"publisher","first-page":"1674","DOI":"10.1016\/j.scib.2024.02.014","article-title":"Practical four-electron\nzinc-iodine aqueous batteries enabled by\norbital hybridization induced adsorption-catalysis","volume":"69","author":"Liu","year":"2024","journal-title":"Sci. Bull."},{"key":"2026081910225423600_cit33","doi-asserted-by":"publisher","first-page":"16350","DOI":"10.1021\/jacs.5c02085","article-title":"Coordination chemistry toward advanced\nZn\u2013I2 batteries with four-electron I\u2013\/I0\/I+ conversion","volume":"147","author":"Zhang","year":"2025","journal-title":"J.\nAm. Chem. Soc."},{"issue":"38","key":"2026081910225423600_cit34","doi-asserted-by":"publisher","first-page":"2501460","DOI":"10.1002\/aenm.202501460","article-title":"Enhanced redox\nkinetics of aqueous I\u2013\/I2\/I+ conversion chemistry in hydrated eutectic electrolyte over a wide\ntemperature range","volume":"15","author":"Liu","year":"2025","journal-title":"Adv. Energy Mater."},{"issue":"2","key":"2026081910225423600_cit35","doi-asserted-by":"publisher","first-page":"51","DOI":"10.1007\/s12039-021-01912-7","article-title":"Formation and structure of iodine:\nwater (H2O-I2) charge-transfer complex","volume":"133","author":"Shrikanth","year":"2021","journal-title":"J.\nChem. Sci."},{"issue":"18","key":"2026081910225423600_cit36","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202422163","article-title":"Solvent chemistry\nmanipulated iodine redox thermodynamics for durable\niodine batteries","volume":"64","author":"Liu","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"issue":"1","key":"2026081910225423600_cit37","doi-asserted-by":"publisher","first-page":"5508","DOI":"10.1038\/s41467-023-41071-6","article-title":"A twelve-electron conversion\niodine cathode enabled by interhalogen\nchemistry in aqueous solution","volume":"14","author":"Ma","year":"2023","journal-title":"Nat. Commun."},{"key":"2026081910225423600_cit38","doi-asserted-by":"publisher","first-page":"271","DOI":"10.1021\/ar4001444","article-title":"Breaking bonds with\nelectrons and protons. Models and examples","volume":"47","author":"Costentin","year":"2014","journal-title":"Acc. Chem. Res."},{"issue":"123","key":"2026081910225423600_cit39","doi-asserted-by":"publisher","first-page":"109422","DOI":"10.1016\/j.nanoen.2024.109422","article-title":"Revealing the voltage decay of LiMn0. 7Fe0.\u00a03PO4 cathodes over cycling","volume":"123","author":"Hu","year":"2024","journal-title":"Nano Energy"},{"key":"2026081910225423600_cit40","doi-asserted-by":"publisher","first-page":"10550","DOI":"10.1039\/D5TA00706B","article-title":"Enhanced cycling\nstability and suppressed voltage decay of LiMn0.8 Fe0.2PO4\/C by Zn-gradient doping","volume":"13","author":"Huang","year":"2025","journal-title":"J. Mater. Chem. A"},{"issue":"39","key":"2026081910225423600_cit41","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404784","article-title":"Bidentate Coordination Structure Facilitates High-Voltage and High-Utilization\nAqueous Zn\u2013I 2 Batteries","volume":"63","author":"Wang","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026081910225423600_cit42","doi-asserted-by":"publisher","first-page":"26889","DOI":"10.1021\/jacs.5c08469","article-title":"Deciphering\nSN2-type nucleophilic substitution via halogen-free intermediates\nfor high-energy zinc-iodine batteries","volume":"147","author":"Yi","year":"2025","journal-title":"J. Am.\nChem. Soc."},{"key":"2026081910225423600_cit43","doi-asserted-by":"publisher","first-page":"2898","DOI":"10.1007\/s40843-024-2972-7","article-title":"Modulating\nthe interfacial microenvironment via zwitterionic additive for long-cycling\naqueous Zn-ion batteries","volume":"67","author":"Xie","year":"2024","journal-title":"Sci. China Mater."},{"key":"2026081910225423600_cit44","doi-asserted-by":"publisher","first-page":"5552","DOI":"10.1039\/D4EE02096K","article-title":"Fully exploited\nimidazolium bromide\nfor simultaneous resolution of cathode and anode challenges in zinc\u2013bromine\nbatteries","volume":"17","author":"Hu","year":"2024","journal-title":"Energy Environ. Sci."},{"issue":"1","key":"2026081910225423600_cit45","doi-asserted-by":"publisher","first-page":"4463","DOI":"10.1038\/s41467-020-18284-0","article-title":"Modulating electrolyte\nstructure for ultralow temperature aqueous\nzinc batteries","volume":"11","author":"Zhang","year":"2020","journal-title":"Nat. Commun."},{"key":"2026081910225423600_cit46","doi-asserted-by":"publisher","first-page":"2714","DOI":"10.1021\/jacs.4c15132","article-title":"A self-phase\nseparated electrolyte toward durable and rollover-stable zinc metal\nbatteries","volume":"147","author":"Zhao","year":"2025","journal-title":"J. Am. Chem. Soc."},{"issue":"6","key":"2026081910225423600_cit47","doi-asserted-by":"publisher","first-page":"2103345","DOI":"10.1002\/smll.202103345","article-title":"Ultrastable zinc anode by simultaneously manipulating\nsolvation sheath\nand inducing oriented deposition with PEG stability promoter","volume":"18","author":"Cao","year":"2022","journal-title":"Small"},{"issue":"33","key":"2026081910225423600_cit48","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202505924","article-title":"Zwitterion-modified\nNiFe OER catalyst\nachieving ultra-stable anion exchange membrane water electrolysis\nvia dynamic alkaline microenvironment engineering","volume":"137","author":"Li","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"issue":"31","key":"2026081910225423600_cit49","doi-asserted-by":"publisher","first-page":"2201599","DOI":"10.1002\/aenm.202201599","article-title":"Triggering\nZn2+ unsaturated hydration structure via hydrated salt\nelectrolyte for high voltage and cycling stable rechargeable aqueous\nZn battery","volume":"12","author":"Yan","year":"2022","journal-title":"Adv. Energy Mater."},{"key":"2026081910225423600_cit50","doi-asserted-by":"publisher","first-page":"153050","DOI":"10.1016\/j.jnucmat.2021.153050","article-title":"Iodine local environment in high pressure borosilicate glasses: An\nX-ray photoelectron spectroscopy and X-ray absorption spectroscopy\ninvestigation","volume":"553","author":"Morizet","year":"2021","journal-title":"J. Nucl. Mater."},{"key":"2026081910225423600_cit51","doi-asserted-by":"publisher","first-page":"451","DOI":"10.1016\/j.jenvrad.2008.06.003","article-title":"Inorganic iodine incorporation\ninto soil organic matter: evidence from iodine K-edge X-ray absorption\nnear-edge structure","volume":"101","author":"Yamaguchi","year":"2010","journal-title":"J. Environ. Radioact."},{"key":"2026081910225423600_cit52","doi-asserted-by":"publisher","first-page":"104837","DOI":"10.1016\/j.ensm.2025.104837","article-title":"Competitive\ncoordination enables aqueous four-electron zinc-iodine batteries over\n60,000 cycles","volume":"84","author":"Yan","year":"2026","journal-title":"Energy Storage Mater."},{"issue":"1","key":"2026081910225423600_cit53","doi-asserted-by":"publisher","first-page":"33","DOI":"10.1038\/s42004-021-00465-7","article-title":"A solvent-free\nsolid\ncatalyst for the selective and color-indicating ambient-air removal\nof sulfur mustard","volume":"4","author":"Collins-Wildman","year":"2021","journal-title":"Commun. Chem."},{"key":"2026081910225423600_cit54","doi-asserted-by":"publisher","first-page":"015501","DOI":"10.1103\/PhysRevLett.99.015501","article-title":"New phase transition of solid bromine\nunder high pressure","volume":"99","author":"San-Miguel","year":"2007","journal-title":"Phys. Rev. Lett."},{"key":"2026081910225423600_cit55","doi-asserted-by":"publisher","first-page":"2024","DOI":"10.1021\/acsenergylett.2c00912","article-title":"Operando Br K-edge\ndispersive X-ray absorption fine structure analysis for Br\u2013\/Br3\u2013 redox mediator for Li\u2013Air\nbatteries","volume":"7","author":"Ito","year":"2022","journal-title":"ACS Energy Lett."},{"key":"2026081910225423600_cit56","doi-asserted-by":"publisher","first-page":"28820","DOI":"10.1021\/jacs.5c05786","article-title":"Balanced iodophilicity\nand solvophilicity unlocks fast\niodine conversion chemistry","volume":"147","author":"Xiao","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026081910225423600_cit57","doi-asserted-by":"publisher","first-page":"101932","DOI":"10.1016\/j.matt.2024.11.026","article-title":"\u03c0-d conjugated coordination\nmediated catalysis for four-electron-transfer fast-charging aqueous\nzinc-iodine batteries","volume":"8","author":"Guan","year":"2025","journal-title":"Matter"},{"issue":"23","key":"2026081910225423600_cit58","doi-asserted-by":"publisher","first-page":"2309371","DOI":"10.1002\/smll.202309371","article-title":"In situ Raman\nstudy of surface reconstruction\nof FeOOH\/Ni3S2 oxygen evolution reaction electrocatalysts","volume":"20","author":"Chen","year":"2024","journal-title":"Small"},{"key":"2026081910225423600_cit59","doi-asserted-by":"publisher","first-page":"24468","DOI":"10.1039\/D4TA03881A","article-title":"Regulating\nthe electrolyte network to accelerate reversible I\u2013\/I2Br\u2013 conversion and suppress zinc\ndendrite formation in advanced zinc\u2013iodine flow batteries","volume":"12","author":"Zhao","year":"2024","journal-title":"J. Mater. Chem. A"}],"container-title":["Journal of the American\nChemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c08547","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/32\/34472\/66426886\/jacs.6c08547.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/32\/34472\/66426886\/jacs.6c08547.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T14:23:00Z","timestamp":1787149380000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/32\/34472\/5247104\/Electron-Push-Pull-Effect-Drives-Reversible-Six"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,5]]},"references-count":59,"journal-issue":{"issue":"32","published-online":{"date-parts":[[2026,8,5]]},"published-print":{"date-parts":[[2026,8,19]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c08547","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,5]]}}}