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However, for olefins with similar electron densities, achieving selective cross-coupling remains a challenge due to competing side reactions, such as homocoupling. The approach taken to alter or regulate the similar redox potentials between two coupling reactants is crucial for achieving high cross-selectivity. To address this, we propose a strategy that leverages the difference in Lewis acid interactions with different substrates to achieve varying degrees of LUMO modification, thereby enhancing the reduction potential difference (\u0394Ered) between the substrates and improving cross-coupling selectivity. A selective reductive cross-coupling of electron-deficient olefins that possess similar electrochemical properties was achieved with the assistance of catalytic amounts of Lewis acids. This mild protocol offers tunable reduction potentials, amplification of subtle electrochemical differences between substrates, broad substrate scope, and compatibility with the late-stage functionalization of natural products and drug derivatives.<\/jats:p>","DOI":"10.1021\/jacs.6c08696","type":"journal-article","created":{"date-parts":[[2026,8,10]],"date-time":"2026-08-10T16:01:56Z","timestamp":1786377716000},"page":"34512-34522","source":"Crossref","is-referenced-by-count":0,"title":["Electrochemical Cross-Coupling\nof Electron-Deficient\nOlefins"],"prefix":"10.1021","volume":"148","author":[{"given":"Chengyi","family":"Peng","sequence":"first","affiliation":[{"name":"Nankai University , , 94 Weijin Road , ,","place":["Tianjin, China, 300071"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weimei","family":"Zeng","sequence":"additional","affiliation":[{"name":"Nankai University , , 94 Weijin Road , ,","place":["Tianjin, China, 300071"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuxuan","family":"Li","sequence":"additional","affiliation":[{"name":"Nankai University , , 94 Weijin Road , ,","place":["Tianjin, China, 300071"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5859-6754","authenticated-orcid":true,"given":"Youai","family":"Qiu","sequence":"additional","affiliation":[{"name":"Nankai University , , 94 Weijin Road , ,","place":["Tianjin, China, 300071"]},{"name":"Guangxi Normal University , , ,","place":["Guilin, People\u2019s Republic of China, 541004"]},{"name":"Nanjing University , , ,","place":["Nanjing, China, 210093"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,10]]},"reference":[{"key":"2026081910212375200_cit1a","doi-asserted-by":"publisher","first-page":"1350","DOI":"10.1126\/science.adl5890","article-title":"Alcohol-alcohol cross-coupling enabled by SH2 radical\nsorting","volume":"383","author":"Chen","year":"2024","journal-title":"Science"},{"key":"2026081910212375200_cit1b","doi-asserted-by":"publisher","DOI":"10.1002\/ijch.202300089","article-title":"Recent Advances in Electrochemical,\nNi-Catalyzed C\u2013C Bond Formation","volume":"64","author":"Franke","year":"2024","journal-title":"Isr.\nJ. 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