{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T14:07:18Z","timestamp":1785506838836,"version":"3.56.0"},"reference-count":53,"publisher":"American Chemical Society (ACS)","issue":"29","license":[{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100006151","name":"Basic Energy Sciences","doi-asserted-by":"publisher","award":["DE-SC0012704"],"award-info":[{"award-number":["DE-SC0012704"]}],"id":[{"id":"10.13039\/100006151","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,29]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Manganese(I) carbonyl complexes are promising electrocatalysts for CO2 reduction, yet their application in homogeneous aqueous media remains limited by poor solubility and selectivity. Here, we report water-soluble Mn(I) and Re(I) complexes fac-[M(bpy2+)(CO)3X]2+ (X = I or Cl), featuring bipyridine ligands functionalized with \u2212Ph\u2212CH2\u2013(NMe3)+ cationic ammonium groups that integrate water solubility with secondary-sphere stabilization. In a bicarbonate buffer at pH 6.8, the Mn catalyst is completely selective for CO production at a low overpotential (\u03b7 = 0.3 V), operating by a protonation-first mechanism with observed rates of \u223c10 s\u20131. Pulse radiolysis reveals that the one-electron-reduced Mn species undergoes dimerization in the absence of CO2 but reacts competitively with CO2 through an initial pre-equilibrium followed by fast formation of a dinuclear CO2-bridged species (\u0394Go = \u221212.4 kcal mol\u20131). At a higher 0.6 V overpotential, a faster reduction-first pathway (\u223c100 s\u20131) is available upon reduction of the metallocarboxylic acid intermediate, Mn-CO2H2+; however, this regime is functionally limited by the formation of a resistive, noncatalytic film on the electrode surface. Comparison to the analogous water-soluble Re catalyst (kobs = 440 s\u20131, \u03b7 = 0.6 V) highlights the distinct mechanistic advantages of earth-abundant Mn in low-potential catalysis. These results demonstrate how cationic second-sphere design enables selective, homogeneous CO2 reduction in water while revealing competing radical and electrode-mediated processes that govern catalytic performance.<\/jats:p>","DOI":"10.1021\/jacs.6c09864","type":"journal-article","created":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T15:27:31Z","timestamp":1784561251000},"page":"31443-31451","source":"Crossref","is-referenced-by-count":0,"title":["Selective Reduction\nof Carbon Dioxide in Water Using\n[M(bpy2+)(CO)3(I)]2+ (M = Mn, Re)\nElectrocatalysts with Pendent Cations"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2283-7122","authenticated-orcid":true,"given":"Preshit C.","family":"Abhyankar","sequence":"first","affiliation":[{"name":"Brookhaven National Laboratory , , , ,","place":["Upton, New York, United States, 11973-5000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0824-2296","authenticated-orcid":true,"given":"Dmitry E.","family":"Polyansky","sequence":"additional","affiliation":[{"name":"Brookhaven National Laboratory , , , ,","place":["Upton, New York, United States, 11973-5000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6632-3895","authenticated-orcid":true,"given":"Gerald F.","family":"Manbeck","sequence":"additional","affiliation":[{"name":"Brookhaven National Laboratory , , , ,","place":["Upton, New York, United States, 11973-5000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,20]]},"reference":[{"key":"2026073109202910400_cit1","doi-asserted-by":"publisher","first-page":"120","DOI":"10.1016\/j.ccr.2018.01.014","article-title":"Electro and photoreduction of CO2 driven by manganese-carbonyl molecular catalysts","volume":"361","author":"Stanbury","year":"2018","journal-title":"Coord. Chem. Rev."},{"issue":"42","key":"2026073109202910400_cit2","doi-asserted-by":"publisher","first-page":"9903","DOI":"10.1002\/anie.201103616","article-title":"[Mn(bipyridyl)(CO)3Br]: An abundant metal\ncarbonyl complex as efficient electrocatalyst\nfor CO2 reduction","volume":"50","author":"Bourrez","year":"2011","journal-title":"Angew. Chem.,\nInt. Ed."},{"issue":"61","key":"2026073109202910400_cit3","doi-asserted-by":"publisher","first-page":"11465","DOI":"10.1039\/D5CC01007A","article-title":"Kinetics and thermodynamics of CO2 binding\nto a metal centre promotes CO2 reduction","volume":"61","author":"Huang","year":"2025","journal-title":"Chem. Commun."},{"issue":"6","key":"2026073109202910400_cit4","doi-asserted-by":"publisher","first-page":"2165","DOI":"10.1021\/acs.iecr.7b03514","article-title":"General techno-economic\nanalysis of CO2 electrolysis\nsystems","volume":"57","author":"Jouny","year":"2018","journal-title":"Ind. Eng. Chem. Res."},{"key":"2026073109202910400_cit5","doi-asserted-by":"publisher","first-page":"173","DOI":"10.1016\/j.ccr.2018.05.022","article-title":"Mechanistic\naspects of CO2 reduction catalysis with manganese-based\nmolecular catalysts","volume":"374","author":"Grills","year":"2018","journal-title":"Coord. Chem. Rev."},{"issue":"15","key":"2026073109202910400_cit6","doi-asserted-by":"publisher","first-page":"5563","DOI":"10.1021\/ja501051s","article-title":"Mechanism of the formation of a Mn-based\nCO2 reduction catalyst revealed by pulse radiolysis with\ntime-resolved infrared detection","volume":"136","author":"Grills","year":"2014","journal-title":"J. Am. Chem.\nSoc."},{"issue":"3","key":"2026073109202910400_cit7","doi-asserted-by":"publisher","first-page":"2281","DOI":"10.1039\/D5CP03590B","article-title":"Monomer and dimer pathways\nof earth-abundant manganese tricarbonyl pre-catalysts for CO2 reduction studied by time-resolved IR spectroscopy","volume":"28","author":"Tatarashvili","year":"2026","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"7","key":"2026073109202910400_cit8","doi-asserted-by":"publisher","first-page":"2604","DOI":"10.1021\/jacs.6b08776","article-title":"Turning on\nthe protonation-first\npathway for electrocatalytic CO2 reduction by manganese\nbipyridyl tricarbonyl complexes","volume":"139","author":"Ngo","year":"2017","journal-title":"J. Am. Chem.\nSoc."},{"issue":"2","key":"2026073109202910400_cit9","doi-asserted-by":"publisher","first-page":"900","DOI":"10.1021\/cs501687n","article-title":"Influence of Weak Br\u00f8nsted Acids on Electrocatalytic\nCO2 Reduction by Manganese and Rhenium Bipyridine Catalysts","volume":"5","author":"Riplinger","year":"2015","journal-title":"ACS Catal."},{"issue":"5","key":"2026073109202910400_cit10","doi-asserted-by":"publisher","first-page":"2484","DOI":"10.1021\/ic302391u","article-title":"Manganese as a substitute for rhenium in CO2 reduction catalysts: The importance of acids","volume":"52","author":"Smieja","year":"2013","journal-title":"Inorg. Chem."},{"key":"2026073109202910400_cit11","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2019.00397","article-title":"Secondary-sphere effects in molecular electrocatalytic\nCO2 reduction","volume":"7","author":"Nichols","year":"2019","journal-title":"Front. Chem."},{"issue":"5","key":"2026073109202910400_cit12","doi-asserted-by":"publisher","first-page":"616","DOI":"10.1021\/acs.accounts.1c00616","article-title":"Understanding\nthe role of inter- and intramolecular promoters in electro- and photochemical\nCO2 reduction using Mn, Re, and Ru catalysts","volume":"55","author":"Fujita","year":"2022","journal-title":"Acc. Chem. Res."},{"issue":"4","key":"2026073109202910400_cit13","doi-asserted-by":"publisher","first-page":"1386","DOI":"10.1021\/jacs.5b12215","article-title":"Manganese electrocatalysts\nwith bulky bipyridine ligands:\nUtilizing Lewis acids to promote carbon dioxide reduction at low overpotentials","volume":"138","author":"Sampson","year":"2016","journal-title":"J. Am. Chem. Soc."},{"issue":"11","key":"2026073109202910400_cit14","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202301388","article-title":"Structure activity\nrelationships for second-coordination sphere functional group dependent\nCO2 reduction by manganese bipyridyl electrocatalysts","volume":"16","author":"Blasczak","year":"2024","journal-title":"ChemCatChem"},{"issue":"24","key":"2026073109202910400_cit15","doi-asserted-by":"publisher","first-page":"9494","DOI":"10.1039\/D5DT00157A","article-title":"The impact\nof second coordination sphere functional group extension on product\nselectivity for manganese bipyridyl CO2 reduction electrocatalysts","volume":"54","author":"Suntrup","year":"2025","journal-title":"Dalton Trans."},{"issue":"40","key":"2026073109202910400_cit16","doi-asserted-by":"publisher","first-page":"15784","DOI":"10.1021\/acs.inorgchem.2c02586","article-title":"Steric and\nLewis basicity influence of the second coordination sphere on electrocatalytic\nCO2 reduction by manganese bipyridyl complexes","volume":"61","author":"Blasczak","year":"2022","journal-title":"Inorg. Chem."},{"issue":"2","key":"2026073109202910400_cit17","doi-asserted-by":"publisher","first-page":"662","DOI":"10.1002\/cssc.202001940","article-title":"Electro-\nand photochemical reduction\nof CO2 by molecular manganese catalysts: Exploring the\npositional effect of second-sphere hydrogen-bond donors","volume":"14","author":"Roy","year":"2021","journal-title":"ChemSusChem"},{"issue":"23","key":"2026073109202910400_cit18","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202304218","article-title":"Electrochemical CO2 reduction by urea hangman\nMn terpyridine species","volume":"30","author":"Li","year":"2024","journal-title":"Chem. - Eur. J."},{"issue":"16","key":"2026073109202910400_cit19","doi-asserted-by":"publisher","first-page":"6569","DOI":"10.1021\/jacs.8b13657","article-title":"Synergistic effects\nof imidazolium-functionalization on fac-Mn(CO)3 bipyridine catalyst platforms for electrocatalytic carbon\ndioxide reduction","volume":"141","author":"Sung","year":"2019","journal-title":"J. Am. Chem. Soc."},{"issue":"27","key":"2026073109202910400_cit20","doi-asserted-by":"publisher","first-page":"14940","DOI":"10.1039\/D1CP01576A","article-title":"Computational\nstudy on the reactivity of imidazolium-functionalized\nmanganese bipyridyl tricarbonyl electrocatalysts [Mn[bpyMe(Im-R)](CO)3Br]+ (R = Me, Me2 and Me4) for CO2-to-CO conversion over H2 formation","volume":"23","author":"Li","year":"2021","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"20","key":"2026073109202910400_cit21","doi-asserted-by":"publisher","first-page":"4782","DOI":"10.1002\/chem.201605546","article-title":"Local proton source\nin electrocatalytic CO2 reduction\nwith [Mn(bpy\u2013R)(CO)3Br] complexes","volume":"23","author":"Franco","year":"2017","journal-title":"Chem. - Eur. J."},{"issue":"6","key":"2026073109202910400_cit22","doi-asserted-by":"publisher","first-page":"1351","DOI":"10.1021\/acs.organomet.8b00588","article-title":"Electrochemical\nand photochemical reduction of CO2 catalyzed by Re(I) complexes\ncarrying local proton sources","volume":"38","author":"Rotundo","year":"2019","journal-title":"Organometallics"},{"issue":"46","key":"2026073109202910400_cit23","doi-asserted-by":"publisher","first-page":"4319","DOI":"10.1002\/ejic.202000738","article-title":"Manganese and rhenium tricarbonyl complexes equipped\nwith proton relays in the electrochemical CO2 reduction\nreaction","volume":"2020","author":"Mukherjee","year":"2020","journal-title":"Eur. J. Inorg. Chem."},{"issue":"9","key":"2026073109202910400_cit24","doi-asserted-by":"publisher","first-page":"4265","DOI":"10.1021\/jacs.9b11806","article-title":"Ligand-controlled product selectivity in electrochemical\ncarbon dioxide reduction using manganese bipyridine catalysts","volume":"142","author":"R\u00f8nne","year":"2020","journal-title":"J. Am. Chem. Soc."},{"issue":"1","key":"2026073109202910400_cit25","doi-asserted-by":"publisher","first-page":"26","DOI":"10.1021\/acsorginorgau.4c00046","article-title":"Metal-dependent mechanism of the\nelectrocatalytic reduction of CO2 by bipyridine complexes\nbearing pendant amines: A DFT study","volume":"5","author":"Luthra","year":"2025","journal-title":"ACS Org.\nInorg. Au"},{"issue":"48","key":"2026073109202910400_cit26","doi-asserted-by":"publisher","first-page":"20491","DOI":"10.1021\/jacs.1c10805","article-title":"Promoting\nselective generation of formic acid from CO2 using Mn(bpy)(CO)3Br as electrocatalyst and triethylamine\/isopropanol as additives","volume":"143","author":"Madsen","year":"2021","journal-title":"J. Am. Chem. Soc."},{"issue":"37","key":"2026073109202910400_cit27","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202104377","article-title":"Efficient electrochemical\nreduction of CO2 to formate\nin methanol solutions by Mn-functionalized electrodes in the presence\nof amines","volume":"28","author":"Stuardi","year":"2022","journal-title":"Chem. - Eur. J."},{"issue":"22","key":"2026073109202910400_cit28","doi-asserted-by":"publisher","first-page":"6882","DOI":"10.1073\/pnas.1507063112","article-title":"Efficient\nand selective\nmolecular catalyst for the CO2-to-CO electrochemical conversion\nin water","volume":"112","author":"Costentin","year":"2015","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"issue":"6","key":"2026073109202910400_cit29","doi-asserted-by":"publisher","first-page":"1224","DOI":"10.1021\/acs.organomet.8b00336","article-title":"Water-soluble manganese\ncomplex for selective electrocatalytic CO2 reduction to\nCO","volume":"38","author":"Walsh","year":"2019","journal-title":"Organometallics"},{"issue":"41","key":"2026073109202910400_cit30","doi-asserted-by":"publisher","first-page":"14425","DOI":"10.1021\/jacs.7b06269","article-title":"Tuning product selectivity\nfor aqueous CO2 reduction with a Mn(bipyridine)-pyrene\ncatalyst immobilized on a\ncarbon nanotube electrode","volume":"139","author":"Reuillard","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"2026073109202910400_cit31","doi-asserted-by":"publisher","first-page":"147","DOI":"10.1039\/C5FD00071H","article-title":"Improving the efficiency of electrochemical\nCO2 reduction using immobilized manganese complexes","volume":"183","author":"Walsh","year":"2015","journal-title":"Faraday Discuss."},{"issue":"9","key":"2026073109202910400_cit32","doi-asserted-by":"publisher","first-page":"7411","DOI":"10.1021\/jacs.4c15547","article-title":"Cambered bipyridyl ligand with extended aryl system\nenables electrochemical reduction of carbon dioxide and bicarbonate\nby Mn(bpy)(CO)3Br-type catalyst immobilized on carbon nanotubes","volume":"147","author":"Lee","year":"2025","journal-title":"J. Am. Chem. Soc."},{"issue":"5","key":"2026073109202910400_cit33","doi-asserted-by":"publisher","first-page":"4452","DOI":"10.1021\/acscatal.8b01068","article-title":"Low-energy\nelectrocatalytic CO2 reduction in water over Mn-complex\ncatalyst electrode aided by a nanocarbon support and K+ cations","volume":"8","author":"Sato","year":"2018","journal-title":"ACS Catal."},{"issue":"15","key":"2026073109202910400_cit34","doi-asserted-by":"publisher","first-page":"11297","DOI":"10.1021\/acsaem.5c01422","article-title":"Selective CO2 reduction in tap-water electrolyte catalyzed\nby impurity-resistant Mn-complex supported on carbon","volume":"8","author":"Nishi","year":"2025","journal-title":"ACS Appl. Energy Mater."},{"issue":"3","key":"2026073109202910400_cit35","doi-asserted-by":"publisher","first-page":"2071","DOI":"10.1021\/acscatal.3c05771","article-title":"Steric effects on CO2 reduction\nwith substituted\nMn(bpy)(CO)3X-type catalysts on multiwalled carbon nanotubes\nreveal critical mechanistic details","volume":"14","author":"DeLuca","year":"2024","journal-title":"ACS Catal."},{"issue":"84","key":"2026073109202910400_cit36","doi-asserted-by":"publisher","first-page":"12698","DOI":"10.1039\/C4CC06404F","article-title":"Electrocatalytic\nCO2 reduction with a membrane supported manganese catalyst\nin aqueous solution","volume":"50","author":"Walsh","year":"2014","journal-title":"Chem. Commun."},{"issue":"11","key":"2026073109202910400_cit37","doi-asserted-by":"publisher","first-page":"2990","DOI":"10.1039\/C9SE00450E","article-title":"Metal\u2013organic\nconjugated microporous polymer containing a carbon dioxide reduction\nelectrocatalyst","volume":"3","author":"Smith","year":"2019","journal-title":"Sustainable Energy Fuels"},{"issue":"21","key":"2026073109202910400_cit38","doi-asserted-by":"publisher","first-page":"18804","DOI":"10.1021\/acscatal.5c03678","article-title":"Electrodeposited\nfilms of manganese\u2013bipyridine complexes for aqueous electrochemical\nCO2 reduction","volume":"15","author":"Silva","year":"2025","journal-title":"ACS Catal."},{"issue":"12","key":"2026073109202910400_cit39","doi-asserted-by":"publisher","first-page":"7210","DOI":"10.1021\/acscatal.1c00314","article-title":"Mechanically\nconstrained catalytic Mn(CO)3Br single sites in a two-dimensional\ncovalent organic framework for CO2 electroreduction in\nH2O","volume":"11","author":"Dubed Bandomo","year":"2021","journal-title":"ACS Catal."},{"issue":"2","key":"2026073109202910400_cit40","doi-asserted-by":"publisher","first-page":"1142","DOI":"10.1039\/D4TA02807D","article-title":"Post-synthetic modification of covalent\norganic frameworks with active manganese centers for electrocatalytic\nCO2 reduction in water","volume":"13","author":"Gala","year":"2025","journal-title":"J. Mater.\nChem. A"},{"issue":"36","key":"2026073109202910400_cit41","doi-asserted-by":"publisher","first-page":"24742","DOI":"10.1021\/jacs.4c08084","article-title":"Fast catalysis\nat low overpotential:\nDesigning efficient dicationic Re(bpy2+)(CO)3I electrocatalysts for CO2 reduction","volume":"146","author":"Rotundo","year":"2024","journal-title":"J. Am. Chem. Soc."},{"issue":"20","key":"2026073109202910400_cit42","doi-asserted-by":"publisher","first-page":"7877","DOI":"10.1021\/acs.inorgchem.3c00624","article-title":"A dicationic fac-Re(bpy)(CO)3Cl for CO2 electroreduction\nat\na reduced overpotential","volume":"62","author":"Rotundo","year":"2023","journal-title":"Inorg. Chem."},{"issue":"14","key":"2026073109202910400_cit43","doi-asserted-by":"publisher","first-page":"4701","DOI":"10.1021\/ja511890h","article-title":"Pd-Catalyzed\nelectrohydrogenation of carbon dioxide\nto formate: High mass activity at low overpotential and identification\nof the deactivation pathway","volume":"137","author":"Min","year":"2015","journal-title":"J. Am. Chem. Soc."},{"issue":"3","key":"2026073109202910400_cit44","doi-asserted-by":"publisher","first-page":"162","DOI":"10.1021\/acsmeasuresciau.2c00070","article-title":"Electrochemical\nimpedance spectroscopy\u2013A Tutorial","volume":"3","author":"Lazanas","year":"2023","journal-title":"ACS\nMeas. Sci. Au"},{"issue":"1","key":"2026073109202910400_cit45","doi-asserted-by":"publisher","first-page":"240","DOI":"10.1002\/anie.201306750","article-title":"Pulsed-EPR evidence of a manganese(II)\nhydroxycarbonyl intermediate in the electrocatalytic reduction of\ncarbon dioxide by a manganese bipyridyl derivative","volume":"53","author":"Bourrez","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"issue":"22","key":"2026073109202910400_cit46","doi-asserted-by":"publisher","first-page":"4359","DOI":"10.1002\/cssc.201701559","article-title":"Application of pulse radiolysis to\nmechanistic investigations of catalysis relevant to Artificial Photosynthesis","volume":"10","author":"Grills","year":"2017","journal-title":"ChemSusChem"},{"key":"2026073109202910400_cit47","unstructured":"Hinsberg, W.; Houle, F.\n          Kinetiscope: A stochastic kinetics\nsimulator."},{"issue":"22","key":"2026073109202910400_cit48","doi-asserted-by":"publisher","first-page":"18796","DOI":"10.1021\/jacs.5c02523","article-title":"Efficient Self-Sensitized Photochemical\nCO2 Reduction Using Re(bpy2+)(CO)3(I)2+ and Re(bpy2+)(CO)3(CH3CN)3+ Photocatalysts with Pendent Ammonium Cations","volume":"147","author":"Wang","year":"2025","journal-title":"J. Am. Chem. Soc."},{"issue":"39","key":"2026073109202910400_cit49","doi-asserted-by":"publisher","first-page":"11976","DOI":"10.1021\/ja035960a","article-title":"Involvement of a binuclear\nspecies with the Re\u2013C(O)O\u2013Re moiety in CO2 reduction\ncatalyzed by tricarbonyl rhenium(I) complexes with diimine ligands:\nstrikingly slow formation of the Re\u2013Re and Re\u2013C(O)O\u2013Re\nspecies from Re(dmb)(CO)3S (dmb = 4,4\u2032-dimethyl-2,2\u2032-bipyridine,\nS = solvent)","volume":"125","author":"Hayashi","year":"2003","journal-title":"J. Am. Chem. Soc."},{"issue":"6","key":"2026073109202910400_cit50","doi-asserted-by":"publisher","first-page":"2074","DOI":"10.1039\/D3SC06059D","article-title":"Overall reaction\nmechanism of photocatalytic\nCO2 reduction on a Re(I)-complex catalyst unit of a Ru(II)\u2013Re(I)\nsupramolecular photocatalyst","volume":"15","author":"Kamogawa","year":"2024","journal-title":"Chem. Sci."},{"issue":"7","key":"2026073109202910400_cit51","doi-asserted-by":"publisher","first-page":"1226","DOI":"10.1002\/celc.201300263","article-title":"Multielectron,\nmultistep molecular catalysis of electrochemical\nreactions: Benchmarking of homogeneous catalysts","volume":"1","author":"Costentin","year":"2014","journal-title":"ChemElectroChem"},{"issue":"1","key":"2026073109202910400_cit52","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1063\/1.555839","article-title":"Standard\nelectrode potentials and temperature coefficients in water at 298.15\nK","volume":"18","author":"Bratsch","year":"1989","journal-title":"J. Phys. Chem. Ref. Data"},{"issue":"27","key":"2026073109202910400_cit53","doi-asserted-by":"publisher","first-page":"11235","DOI":"10.1021\/ja303560c","article-title":"Turnover\nnumbers, turnover frequencies, and overpotential in molecular catalysis\nof electrochemical reactions. Cyclic voltammetry and preparative-scale\nelectrolysis","volume":"134","author":"Costentin","year":"2012","journal-title":"J. Am. Chem. Soc."}],"container-title":["Journal of the American\nChemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c09864","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/29\/31443\/66343785\/jacs.6c09864.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/29\/31443\/66343785\/jacs.6c09864.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T13:20:32Z","timestamp":1785504032000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/29\/31443\/5237453\/Selective-Reduction-of-Carbon-Dioxide-in-Water"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,20]]},"references-count":53,"journal-issue":{"issue":"29","published-online":{"date-parts":[[2026,7,20]]},"published-print":{"date-parts":[[2026,7,29]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c09864","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,20]]}}}