{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T04:00:40Z","timestamp":1792814440528,"version":"4.5.0"},"reference-count":120,"publisher":"American Chemical Society (ACS)","issue":"26","license":[{"start":{"date-parts":[[2026,6,24]],"date-time":"2026-06-24T00:00:00Z","timestamp":1782259200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,6,24]],"date-time":"2026-06-24T00:00:00Z","timestamp":1782259200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,6,24]],"date-time":"2026-06-24T00:00:00Z","timestamp":1782259200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000928","name":"Welch Foundation","doi-asserted-by":"publisher","award":["F-0038"],"award-info":[{"award-number":["F-0038"]}],"id":[{"id":"10.13039\/100000928","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation (NSF)","doi-asserted-by":"crossref","award":["CHE-2246428"],"award-info":[{"award-number":["CHE-2246428"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J. Am. Chem. Soc."],"published-print":{"date-parts":[[2026,7,8]]},"DOI":"10.1021\/jacs.6c09865","type":"journal-article","created":{"date-parts":[[2026,6,24]],"date-time":"2026-06-24T19:23:37Z","timestamp":1782329017000},"page":"27925-27933","source":"Crossref","is-referenced-by-count":1,"title":["Quaternary\n                    <i>N<\/i>\n                    -Heterobenzylic Carbon Centers via Allene-Mediated C\u2013H Functionalization of Azines\/Azoles: Ruthenium-Catalyzed Dearomative Addition-Hydrogen Auto-Transfer"],"prefix":"10.1021","volume":"148","author":[{"given":"Nicholas K.","family":"Bowers","sequence":"first","affiliation":[{"name":"Department of Chemistry","place":["Austin, United States"]},{"name":"University of Texas at Austin","place":["Austin, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-9923-3725","authenticated-orcid":true,"given":"Brandon I.","family":"Gonzalez","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Austin, United States"]},{"name":"University of Texas at Austin","place":["Austin, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Niclas","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Austin, United States"]},{"name":"University of Texas at Austin","place":["Austin, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vincent","family":"Ngo","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Austin, United States"]},{"name":"University of Texas at Austin","place":["Austin, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-6687-2466","authenticated-orcid":true,"given":"Yhin Sarah","family":"Teoh","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Austin, United States"]},{"name":"University of Texas at Austin","place":["Austin, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tate A.","family":"Claggett","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Austin, United States"]},{"name":"University of Texas at Austin","place":["Austin, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8418-9709","authenticated-orcid":true,"given":"Michael J.","family":"Krische","sequence":"additional","affiliation":[{"name":"Department of Chemistry","place":["Austin, United States"]},{"name":"University of Texas at Austin","place":["Austin, United States"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,6,24]]},"reference":[{"key":"ref1\/cit1","doi-asserted-by":"publisher","DOI":"10.1038\/366529a0"},{"key":"ref2\/cit2a","doi-asserted-by":"publisher","DOI":"10.1007\/3-540-68525-1_3"},{"key":"ref2\/cit2b","doi-asserted-by":"publisher","DOI":"10.1021\/cr0104330"},{"key":"ref2\/cit2c","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2010.09.030"},{"key":"ref2\/cit2d","doi-asserted-by":"publisher","DOI":"10.1021\/cr300153j"},{"key":"ref2\/cit2e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00495"},{"key":"ref2\/cit2f","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00359J"},{"key":"ref2\/cit2g","doi-asserted-by":"publisher","DOI":"10.1016\/bs.adomc.2023.01.002"},{"key":"ref3\/cit3a","doi-asserted-by":"publisher","DOI":"10.1246\/cl.150913"},{"key":"ref3\/cit3b","doi-asserted-by":"publisher","DOI":"10.1055\/s-0040-1720406"},{"key":"ref4\/cit4a","doi-asserted-by":"publisher","DOI":"10.1039\/a902240f"},{"key":"ref4\/cit4b","doi-asserted-by":"publisher","DOI":"10.1021\/jo901350j"},{"key":"ref4\/cit4c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201001470"},{"key":"ref4\/cit4d","doi-asserted-by":"publisher","DOI":"10.1021\/ja108809u"},{"key":"ref4\/cit4e","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201207958"},{"key":"ref4\/cit4f","doi-asserted-by":"publisher","DOI":"10.1021\/ja505776m"},{"key":"ref5\/cit5a","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC02790A"},{"key":"ref5\/cit5b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202502569"},{"key":"ref6\/cit6a","doi-asserted-by":"publisher","DOI":"10.1021\/ja710766j"},{"key":"ref6\/cit6b","doi-asserted-by":"publisher","DOI":"10.1021\/ja907214t"},{"key":"ref6\/cit6c","doi-asserted-by":"publisher","DOI":"10.1021\/ja106514b"},{"key":"ref6\/cit6d","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b04199"},{"key":"ref6\/cit6e","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c04043"},{"key":"ref6\/cit6f","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c09306"},{"key":"ref6\/cit6g","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2021.132339"},{"key":"ref6\/cit6h","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c01098"},{"key":"ref6\/cit6i","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c14600"},{"key":"ref7\/cit7","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702409"},{"key":"ref8\/cit8a","doi-asserted-by":"publisher","DOI":"10.1021\/ja057654y"},{"key":"ref8\/cit8b","doi-asserted-by":"publisher","DOI":"10.1021\/ja060999b"},{"key":"ref8\/cit8c","doi-asserted-by":"publisher","DOI":"10.1021\/ol800395m"},{"key":"ref8\/cit8d","doi-asserted-by":"publisher","DOI":"10.1055\/s-0029-1216826"},{"key":"ref9\/cit9","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c13377"},{"key":"ref10\/cit10a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902996"},{"key":"ref10\/cit10b","doi-asserted-by":"publisher","DOI":"10.1039\/c1md00134e"},{"key":"ref10\/cit10c","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201300922"},{"key":"ref10\/cit10d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00567"},{"key":"ref10\/cit10e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00021"},{"key":"ref10\/cit10f","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900977"},{"key":"ref11\/cit11a","doi-asserted-by":"publisher","DOI":"10.1021\/cr00022a005"},{"key":"ref11\/cit11b","doi-asserted-by":"publisher","DOI":"10.1039\/B615042J"},{"key":"ref11\/cit11c","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc05222a"},{"key":"ref11\/cit11d","doi-asserted-by":"publisher","DOI":"10.1038\/nature14007"},{"key":"ref11\/cit11e","doi-asserted-by":"publisher","DOI":"10.1021\/ja410424g"},{"key":"ref11\/cit11f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00385"},{"key":"ref11\/cit11g","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903188"},{"key":"ref12\/cit12a","doi-asserted-by":"publisher","DOI":"10.1039\/jr9630002039"},{"key":"ref12\/cit12b","volume-title":"Thermochemistry of Organic and Organometallic Compounds","author":"Cox J. D.","year":"1970"},{"key":"ref12\/cit12c","doi-asserted-by":"publisher","DOI":"10.1021\/cr990327m"},{"key":"ref12\/cit12d","doi-asserted-by":"crossref","first-page":"1657","DOI":"10.1016\/S0040-4020(03)00137-6","volume":"59","author":"Cyra\u0144ski M. K.","year":"2003","journal-title":"Tetrahedron"},{"key":"ref12\/cit12e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.4c01925"},{"key":"ref14\/cit14a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b02568"},{"key":"ref14\/cit14b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c02864"},{"key":"ref14\/cit14c","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.1c02346"},{"key":"ref15\/cit15a","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201208666"},{"key":"ref15\/cit15b","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201300991"},{"key":"ref16\/cit16a","doi-asserted-by":"publisher","DOI":"10.1021\/cr200251d"},{"key":"ref16\/cit16b","doi-asserted-by":"publisher","DOI":"10.1039\/C4OB00371C"},{"key":"ref16\/cit16c","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2016.11.005"},{"key":"ref16\/cit16d","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c01651"},{"key":"ref16\/cit16e","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC04638E"},{"key":"ref16\/cit16f","doi-asserted-by":"publisher","DOI":"10.1055\/a-1577-7638"},{"key":"ref16\/cit16g","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00625"},{"key":"ref17\/cit17a","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah5133"},{"key":"ref17\/cit17b","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c01109"},{"key":"ref17\/cit17c","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c01857"},{"key":"ref17\/cit17d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00858"},{"key":"ref18\/cit18a","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c15157"},{"key":"ref18\/cit18b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c15097"},{"key":"ref19\/cit19a","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC01968H"},{"key":"ref19\/cit19b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00213"},{"key":"ref19\/cit19c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202007251"},{"key":"ref19\/cit19d","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00803"},{"key":"ref19\/cit19e","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202101890"},{"key":"ref20\/cit20","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201704248"},{"key":"ref21\/cit21a","doi-asserted-by":"publisher","DOI":"10.1021\/ol901759t"},{"key":"ref21\/cit21b","doi-asserted-by":"publisher","DOI":"10.1021\/ja303790s"},{"key":"ref21\/cit21c","doi-asserted-by":"publisher","DOI":"10.1021\/ja311956k"},{"key":"ref21\/cit21d","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709087"},{"key":"ref21\/cit21e","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b00207"},{"key":"ref22\/cit22a","first-page":"513","volume":"10","author":"Ginzburg Y. I.","year":"1940","journal-title":"J. Gen. Chem."},{"key":"ref22\/cit22b","doi-asserted-by":"publisher","DOI":"10.1021\/ja01174a017"},{"key":"ref23\/cit23a","doi-asserted-by":"publisher","DOI":"10.1039\/DT9850000873"},{"key":"ref23\/cit23b","doi-asserted-by":"publisher","DOI":"10.1039\/a704157h"},{"key":"ref23\/cit23c","doi-asserted-by":"publisher","DOI":"10.1021\/om049646g"},{"key":"ref24\/cit24a","doi-asserted-by":"publisher","DOI":"10.1021\/ja902437k"},{"key":"ref24\/cit24b","doi-asserted-by":"publisher","DOI":"10.1021\/ol9018562"},{"key":"ref25\/cit25","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c06734"},{"key":"ref26\/cit26a","doi-asserted-by":"publisher","DOI":"10.1021\/ja806677w"},{"key":"ref26\/cit26b","doi-asserted-by":"publisher","DOI":"10.1021\/ja1104156"},{"key":"ref27\/cit27a","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(03)01807-0"},{"key":"ref27\/cit27b","doi-asserted-by":"publisher","DOI":"10.1021\/ja051930r"},{"key":"ref27\/cit27c","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2005.504"},{"key":"ref28\/cit28a","doi-asserted-by":"publisher","DOI":"10.1021\/jm501100b"},{"key":"ref28\/cit28b","doi-asserted-by":"publisher","DOI":"10.1021\/jm4017625"},{"key":"ref28\/cit28c","doi-asserted-by":"publisher","DOI":"10.1111\/cbdd.12260"},{"key":"ref28\/cit28d","doi-asserted-by":"publisher","DOI":"10.1016\/bs.aihch.2016.11.002"},{"key":"ref28\/cit28e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.2c00473"},{"key":"ref28\/cit28f","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.4c01122"},{"key":"ref29\/cit29a","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00628G"},{"key":"ref29\/cit29b","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00022"},{"key":"ref29\/cit29c","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0021-z"},{"key":"ref29\/cit29d","doi-asserted-by":"publisher","DOI":"10.1139\/cjc-2018-0357"},{"key":"ref29\/cit29e","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00881"},{"key":"ref30\/cit30a","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2004.09.014"},{"key":"ref30\/cit30b","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c05629"},{"key":"ref31\/cit31","doi-asserted-by":"publisher","DOI":"10.1016\/s0040-4039(00)99497-8"},{"key":"ref32\/cit32a","doi-asserted-by":"publisher","DOI":"10.1021\/om00006a057"},{"key":"ref32\/cit32b","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC05609G"},{"key":"ref33\/cit33","doi-asserted-by":"publisher","DOI":"10.1007\/s00706-020-02713-3"},{"key":"ref34\/cit34","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2015.01.050"},{"key":"ref35\/cit35","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.9b02369"},{"key":"ref36\/cit36a","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201000037"},{"key":"ref36\/cit36b","doi-asserted-by":"publisher","DOI":"10.1055\/s-0036-1588540"},{"key":"ref37\/cit37","doi-asserted-by":"publisher","DOI":"10.1021\/cr60307a002"},{"key":"ref38\/cit38a","first-page":"C71","volume":"18","author":"Dewar M. J. S.","year":"1951","journal-title":"Bull. Soc. Chim. Fr."},{"key":"ref38\/cit38b","doi-asserted-by":"publisher","DOI":"10.1039\/jr9530002939"},{"key":"ref38\/cit38c","doi-asserted-by":"publisher","DOI":"10.1021\/ja00498a001"},{"key":"ref39\/cit39a","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)80238-6"},{"key":"ref39\/cit39b","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(99)00184-8"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c09865","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c09865","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T13:43:30Z","timestamp":1783518210000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.6c09865"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,6,24]]},"references-count":120,"journal-issue":{"issue":"26","published-print":{"date-parts":[[2026,7,8]]}},"alternative-id":["10.1021\/jacs.6c09865"],"URL":"https:\/\/doi.org\/10.1021\/jacs.6c09865","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,6,24]]}}}