{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:47:43Z","timestamp":1792784863391,"version":"4.5.0"},"reference-count":75,"publisher":"American Chemical Society (ACS)","issue":"40","license":[{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"name":"National Basic Research Program of China (973 Program)","award":["2024YFA1409800"],"award-info":[{"award-number":["2024YFA1409800"]}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["12504090"],"award-info":[{"award-number":["12504090"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["12688201"],"award-info":[{"award-number":["12688201"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"Xinjiang Tianchi Talents Program","award":["2025000061"],"award-info":[{"award-number":["2025000061"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Solid-state ultraviolet (UV) single-photon emitters (SPEs) are highly desirable for solar-blind free-space quantum communication, ion-compatible quantum networking, and label-free spectroscopy, yet robust and well-understood UV color centers remain scarce even in wide-gap hosts such as diamond. Here we show that the energy of zero-phonon lines (ZPLs) is not controlled by the bandgap alone, but is governed by the host bonding character (covalent versus ionic) through the bonding\u2013antibonding splitting of lattice divacancy-derived defect states. In covalent diamond, the divacancy yields only a 0.79 eV separation within the optical two-level manifold, so that most established centers exhibit ZPLs predominantly in the near-infrared or visible. By contrast, in ionic cubic boron nitride (c-BN), the corresponding divacancy splitting can reach 5.61 eV, naturally pushing the analogous transitions into the UV band. Building on this basic understanding, we establish a unified rule, combining impurity-associated atomic potential, lattice strain, and orbital hybridization, to predict ZPL trends of vacancy-impurity-vacancy (XV) centers in c-BN. Guided by this framework, we identify a chemically rich set of UV-emitting XV centers and reveal a roughly, though not strictly, monotonic redshift tendency of the ZPL for heavier impurities, with local deviations arising from competing strain, orbital hybridization, the Jahn\u2013Teller effect, and spin\u2013orbit coupling. These results provide a chemically transparent design rule for engineering UV SPEs in wide-gap hosts and help rationalize the scarcity of UV centers across materials, highlighting c-BN as a particularly fertile platform for solid-state quantum photonics.<\/jats:p>","DOI":"10.1021\/jacs.6c10140","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T04:02:16Z","timestamp":1790654536000},"page":"43103-43113","source":"Crossref","is-referenced-by-count":0,"title":["Chemical Design Rule\nfor Ultraviolet-Emitting Color\nCenters: The Role of Host Ionicity"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4389-6671","authenticated-orcid":true,"given":"Chen","family":"Qiu","sequence":"first","affiliation":[{"name":"Eastern Institute of Technology , , ,","place":["Ningbo, China, 315200"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao-Lan","family":"Yan","sequence":"additional","affiliation":[{"name":"Eastern Institute of Technology , , ,","place":["Ningbo, China, 315200"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2293-095X","authenticated-orcid":true,"given":"Cai-Xin","family":"Zhang","sequence":"additional","affiliation":[{"name":"Eastern Institute of Technology , , ,","place":["Ningbo, China, 315200"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9106-6333","authenticated-orcid":true,"given":"Yu","family":"Song","sequence":"additional","affiliation":[{"name":"Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences , , ,","place":["Urumqi, China, 830011"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1563-4738","authenticated-orcid":true,"given":"Su-Huai","family":"Wei","sequence":"additional","affiliation":[{"name":"Eastern Institute of Technology , , ,","place":["Ningbo, China, 315200"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,28]]},"reference":[{"key":"2026101414084128500_cit1","doi-asserted-by":"publisher","first-page":"326","DOI":"10.1038\/s42254-023-00583-2","article-title":"Applications\nof single photons to quantum communication and computing","volume":"5","author":"Couteau","year":"2023","journal-title":"Nat. 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B"},{"issue":"12","key":"2026101414084128500_cit30","doi-asserted-by":"publisher","first-page":"4864","DOI":"10.1021\/acsphotonics.8b01013","article-title":"Single-photon emitters\nin Lead-implanted single-crystal diamond","volume":"5","author":"Ditalia Tchernij","year":"2018","journal-title":"ACS\nPhotonics"},{"issue":"23","key":"2026101414084128500_cit31","doi-asserted-by":"publisher","first-page":"9227","DOI":"10.1021\/acs.nanolett.2c03743","article-title":"Quantum Emitters in\nHexagonal Boron\nNitride","volume":"22","author":"Aharonovich","year":"2022","journal-title":"Nano Lett."},{"issue":"4","key":"2026101414084128500_cit32","doi-asserted-by":"publisher","first-page":"843","DOI":"10.1364\/OME.386791","article-title":"Room-temperature\nsingle photon emitters in cubic boron nitride nanocrystals","volume":"10","author":"Lo\u0301pez-Morales","year":"2020","journal-title":"Opt. Mater. Express"},{"issue":"12","key":"2026101414084128500_cit33","doi-asserted-by":"publisher","first-page":"13454","DOI":"10.1021\/jacs.6c02983","article-title":"Chemical\nControl of Zero-Phonon Line\nWavelength in Diamond Color Centers for Telecom-Band Emission","volume":"148","author":"Qiu","year":"2026","journal-title":"J. Am. Chem. Soc."},{"issue":"2","key":"2026101414084128500_cit34","doi-asserted-by":"publisher","first-page":"021063","DOI":"10.1103\/PhysRevX.8.021063","article-title":"Ab Initio magneto-optical\nspectrum of group-IV vacancy color centers\nin diamond","volume":"8","author":"Thiering","year":"2018","journal-title":"Phys. Rev. X"},{"issue":"12","key":"2026101414084128500_cit35","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202409876","article-title":"Harsh Environment-Immune\nAll-Carbon\nVisible Light Photodetector: Sensitivity Improvement by Nitrogen-Vacancy\nCenter Density Enhancement Through Electron Irradiation","volume":"21","author":"Valappil","year":"2025","journal-title":"Small"},{"issue":"12","key":"2026101414084128500_cit36","doi-asserted-by":"publisher","first-page":"4818","DOI":"10.1021\/acs.nanolett.4c06343","article-title":"Intralevel Optical Transitions of\nXV (XV = BV, SiV, and NV) Centers in Fluorinated Diamane","volume":"25","author":"Yan","year":"2025","journal-title":"Nano Lett."},{"issue":"3","key":"2026101414084128500_cit37","doi-asserted-by":"publisher","first-page":"317","DOI":"10.1103\/RevModPhys.42.317","article-title":"Ionicity\nof the Chemical Bond in Crystals","volume":"42","author":"Phillips","year":"1970","journal-title":"Rev. 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