{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T16:12:33Z","timestamp":1788970353088,"version":"build-2803163510"},"reference-count":54,"publisher":"American Chemical Society (ACS)","issue":"35","license":[{"start":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T00:00:00Z","timestamp":1787788800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T00:00:00Z","timestamp":1787788800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T00:00:00Z","timestamp":1787788800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22265006"],"award-info":[{"award-number":["22265006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22375066"],"award-info":[{"award-number":["22375066"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U23A20594"],"award-info":[{"award-number":["U23A20594"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Science and Technology Plan Projects of Guangxi Province","award":["2024GXNSFAA010360"],"award-info":[{"award-number":["2024GXNSFAA010360"]}]},{"DOI":"10.13039\/501100021171","name":"Guangdong Basic and Applied Basic Research Foundation","doi-asserted-by":"crossref","award":["2023B1515040003"],"award-info":[{"award-number":["2023B1515040003"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The precise identification and regulation of dynamic charge-transport pathways in multiaryl frameworks are pivotal for unlocking advanced optoelectronic functionalities and elucidating single-molecule transport phenomena. However, achieving reversible on\u2013off switching of through-space conjugation (TSC) and quantitatively correlating this process with single-molecule conductance remain formidable challenges. Herein, using tetraphenylethylene (TPE-2S) and tetraphenylethane (TPA-2S) as model systems, we demonstrate that external electric fields can reversibly gate dynamic TSC channels, enabling in situ and quantitative modulation of single-molecule conductance via the scanning tunneling microscopy break-junction (STM-BJ) technique. Systematic concentration- and bias-dependent STM-BJ control measurements, flicker-noise spectroscopy, and comprehensive DFT-NEGF transport calculations collectively validate that elevated applied bias drives reversible intramolecular torsional rearrangement and pairwise \u03c0\u2013\u03c0 dimerization of the flexible sp3-bridged TPA-2S, triggering a distinct conductance transition from weak monomeric through-bond tunneling to efficient intermolecular through-space charge transport. Comprehensive single-crystal and spectroscopic analyses reveal that the central C\u2550C bond in TPE-2S sustains efficient through-bond conjugation, whereas the sp3-hybridized C\u2013C bridge in TPA-2S disrupts covalent connectivity, confining electronic delocalization. Complementary transmission eigenchannel, local current density, and bias-dependent projected device density of states (PDDOS) calculations directly visualize charge delocalization across the phenyl\u2013phenyl stacking interface in TPA-2S dimers. BSSE-corrected intermolecular binding energies, field-amplified dipole polarization, and diabatic electronic coupling matrix elements further provide quantitative thermodynamic evidence that an external electric bias thermodynamically stabilizes the \u03c0-stacked dimer assembly. Flicker noise spectroscopy and theoretical transport calculations corroborate the reversible interconversion between single-channel monomer tunneling and multichannel dimer through-space conduction. This study establishes electric-field gating as a robust strategy for manipulating dynamic TSC and precisely tuning single-molecule conductance, positioning STM-BJ as a powerful platform to resolve transient single-junction transport behavior inaccessible via ensemble spectroscopy, and laying a foundational framework for designing stimuli-responsive single-molecule devices.<\/jats:p>","DOI":"10.1021\/jacs.6c10294","type":"journal-article","created":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T18:28:31Z","timestamp":1788287311000},"page":"38111-38123","source":"Crossref","is-referenced-by-count":0,"title":["Electric-Field Gating\nof Dynamic through-Space Conjugation\nin sp2\/sp3-Bridged Molecular Junctions"],"prefix":"10.1021","volume":"148","author":[{"given":"Jian","family":"Li","sequence":"first","affiliation":[{"name":"Guilin University of Technology , , ,","place":["Guilin, P. R. China, 541006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meijing","family":"Li","sequence":"additional","affiliation":[{"name":"Guilin University of Technology , , ,","place":["Guilin, P. R. China, 541006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiqi","family":"Guo","sequence":"additional","affiliation":[{"name":"Guilin University of Technology , , ,","place":["Guilin, P. R. China, 541006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xi","family":"Su","sequence":"additional","affiliation":[{"name":"Guilin University of Technology , , ,","place":["Guilin, P. R. China, 541006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangqi","family":"Wu","sequence":"additional","affiliation":[{"name":"Guilin University of Technology , , ,","place":["Guilin, P. R. China, 541006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0618-6024","authenticated-orcid":true,"given":"Zujin","family":"Zhao","sequence":"additional","affiliation":[{"name":"South China University of Technology , , ,","place":["Guangzhou, P.R.china, 510640"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6088-0930","authenticated-orcid":true,"given":"Shijie","family":"Zhen","sequence":"additional","affiliation":[{"name":"Guilin University of Technology , , ,","place":["Guilin, P. R. China, 541006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0293-964X","authenticated-orcid":true,"given":"Ben Zhong","family":"Tang","sequence":"additional","affiliation":[{"name":"The Chinese University of Hong Kong (Shenzhen) , , Longgang, , ,","place":["Shenzhen, Guangdong, China, 518172"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,27]]},"reference":[{"key":"2026090910091640200_cit1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202508708","article-title":"Distinct Charge\nTransport and Its Regulation in Single-Molecule and Monolayer Junctions","volume":"64","author":"Yang","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090910091640200_cit2","doi-asserted-by":"publisher","first-page":"16052","DOI":"10.1038\/natrevmats.2016.52","article-title":"Two-Dimensional Semiconductors for\nTransistors","volume":"1","author":"Chhowalla","year":"2016","journal-title":"Nat. Rev. Mater."},{"key":"2026090910091640200_cit3","doi-asserted-by":"publisher","first-page":"100115","DOI":"10.1016\/j.esci.2023.100115","article-title":"Modulating\nSingle-Molecule Charge Transport through External Stimulus","volume":"3","author":"Zou","year":"2023","journal-title":"eScience"},{"key":"2026090910091640200_cit4","doi-asserted-by":"publisher","first-page":"1450","DOI":"10.1038\/s41467-019-09120-1","article-title":"Side-Group\nChemical Gating via Reversible Optical and Electric Control\nin a Single Molecule Transistor","volume":"10","author":"Meng","year":"2019","journal-title":"Nat. Commun."},{"key":"2026090910091640200_cit5","doi-asserted-by":"publisher","first-page":"5569","DOI":"10.1021\/acs.nanolett.5b02188","article-title":"Electric-Field Control of Interfering Transport Pathways\nin a Single-Molecule Anthraquinone Transistor","volume":"15","author":"Koole","year":"2015","journal-title":"Nano Lett."},{"key":"2026090910091640200_cit6","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.70063","article-title":"Bridging the Gap Between Traditional and Nontraditional Luminogens\nwith Strong Non-Aromatic Through-Bond Conjugation and Through-Space\nConjugation","volume":"6","author":"Zhang","year":"2025","journal-title":"Aggregate"},{"key":"2026090910091640200_cit7","doi-asserted-by":"publisher","first-page":"131411","DOI":"10.1016\/j.matchemphys.2025.131411","article-title":"Donor-Acceptor Architecture and Charge Transfer Modulation\nin Olefin-Linked Triazine Frameworks","volume":"347","author":"Li","year":"2026","journal-title":"Mater.\nChem. Phys."},{"issue":"45","key":"2026090910091640200_cit8","doi-asserted-by":"publisher","first-page":"19200","DOI":"10.1039\/D1NR05487B","article-title":"Tuning the Current\nRectification Behavior of Rh2-Based\nMolecular Junctions by Varying Their Supramolecular Structures","volume":"13","author":"Bu","year":"2021","journal-title":"Nanoscale"},{"key":"2026090910091640200_cit9","doi-asserted-by":"publisher","first-page":"230","DOI":"10.1038\/s44160-025-00918-0","article-title":"Aromaticity and Through-Space\nElectronic Coupling in [2]Catenanes Comprising Two Intertwined Globally\nElectron-Delocalized Octaphyrinoid Rings","volume":"5","author":"Sui","year":"2026","journal-title":"Nat.\nSynth."},{"issue":"31","key":"2026090910091640200_cit10","doi-asserted-by":"publisher","first-page":"12101","DOI":"10.1021\/acs.nanolett.5c03693","article-title":"Single-Molecule\nConductance through Hybrid Radially and Linearly \u03c0-Conjugated\nMacromolecules Reveals an Unusual Intramolecular \u03c0-Interaction","volume":"25","author":"Shi","year":"2025","journal-title":"Nano Lett."},{"key":"2026090910091640200_cit11","doi-asserted-by":"publisher","first-page":"14515","DOI":"10.1039\/D3TC02035E","article-title":"Recent Progress\nin Tuning Charge Transport in Single-Molecule Junctions by Substituents","volume":"11","author":"Chen","year":"2023","journal-title":"J. Mater. Chem. C"},{"key":"2026090910091640200_cit12","doi-asserted-by":"publisher","first-page":"1","DOI":"10.31635\/ccschem.026.202507017","article-title":"Ultrastrong Through-Space Conjugation Enabled by Chiral Transfer-Driven\nHelical Structure","author":"Zhang","year":"2026","journal-title":"CCS Chem"},{"key":"2026090910091640200_cit13","doi-asserted-by":"publisher","first-page":"2493","DOI":"10.1039\/d3cs00996c","article-title":"Through-Space\nInteractions\nof Optoelectronic Materials","volume":"55","author":"Zhang","year":"2026","journal-title":"Chem. Soc. Rev."},{"key":"2026090910091640200_cit14","doi-asserted-by":"publisher","first-page":"1185","DOI":"10.1038\/s41566-024-01527-7","article-title":"Efficient\nOrganic Emitters Enabled by Ultrastrong Through-Space Conjugation","volume":"18","author":"Xu","year":"2024","journal-title":"Nat. Photonics"},{"issue":"92","key":"2026090910091640200_cit15","doi-asserted-by":"publisher","first-page":"18100","DOI":"10.1039\/d5cc04641f","article-title":"Through-Space Conjugation\nEngineering in Methylated\nTetraphenylethene Derivatives","volume":"61","author":"Gao","year":"2025","journal-title":"Chem. Commun."},{"key":"2026090910091640200_cit16","doi-asserted-by":"publisher","first-page":"2648","DOI":"10.1021\/acs.jpclett.9b01040","article-title":"Through-Space Conjugation:\nAn Effective\nStrategy for Stabilizing Intramolecular Charge-Transfer States","volume":"10","author":"Shen","year":"2019","journal-title":"J. Phys. Chem. Lett."},{"key":"2026090910091640200_cit17","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.70039","article-title":"Chiral Amplification\nand Regulation:\nDesign and Applications of Circularly Polarized Luminescence-Active\nMaterials Derived from Macrocyclic Compounds","volume":"6","author":"Zhang","year":"2025","journal-title":"Aggregate"},{"key":"2026090910091640200_cit18","doi-asserted-by":"publisher","first-page":"1790","DOI":"10.1021\/acs.macromol.6b02798","article-title":"Enhancement and Controlling\nthe Signal of Circularly Polarized Luminescence Based on a Planar\nChiral Tetrasubstituted [2.2]Paracyclophane Framework in Aggregation\nSystem","volume":"50","author":"Gon","year":"2017","journal-title":"Macromolecules"},{"key":"2026090910091640200_cit19","doi-asserted-by":"publisher","first-page":"1820","DOI":"10.1039\/D5CC07099F","article-title":"Through-Space Conjugation-Based Luminophores:\nToward Redder and More Efficient Emitters","volume":"62","author":"Wang","year":"2026","journal-title":"Chem.\nCommun."},{"key":"2026090910091640200_cit20","doi-asserted-by":"publisher","first-page":"9998","DOI":"10.1039\/D3NJ01074K","article-title":"Tuning Multichannel Conductance via\nThrough-Space Conjugated Naphthalene","volume":"47","author":"Li","year":"2023","journal-title":"New J.\nChem."},{"key":"2026090910091640200_cit21","doi-asserted-by":"publisher","first-page":"4588","DOI":"10.1039\/D5TC04260G","article-title":"Controllable Modulation of Through-Bond\nand Through-Space Coupling\nChannels in Indene-Derived Photoresponsive Molecules for Single-Molecule\nPhotoswitches","volume":"14","author":"Yu","year":"2026","journal-title":"J. Mater. Chem. C"},{"key":"2026090910091640200_cit22","doi-asserted-by":"publisher","first-page":"7160","DOI":"10.1039\/D1CC02111G","article-title":"Electric Field-Induced\nSwitching among Multiple Conductance Pathways in Single-Molecule Junctions","volume":"57","author":"Gao","year":"2021","journal-title":"Chem. Commun."},{"key":"2026090910091640200_cit23","doi-asserted-by":"publisher","first-page":"4200","DOI":"10.1021\/acs.nanolett.8b01082","article-title":"Remarkable\nMultichannel Conductance of Novel Single-Molecule Wires Built on Through-Space\nConjugated Hexaphenylbenzene","volume":"18","author":"Zhen","year":"2018","journal-title":"Nano Lett."},{"key":"2026090910091640200_cit24","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.70088","article-title":"Rapid Electrochemical Synthesis and\nSolvatochromic\nEmission Behavior of Single Crystals of a Heteronuclear Platinum(II)-Copper(I)\nComplex","volume":"6","author":"Liu","year":"2025","journal-title":"Aggregate"},{"key":"2026090910091640200_cit25","doi-asserted-by":"publisher","first-page":"13279","DOI":"10.1039\/D5NJ01996F","article-title":"External Electric Field-Induced Molecular Structural Evolution and\nElectronic Response of BITE-101: A Multiscale Investigation from Molecules\nto Crystals","volume":"49","author":"Gao","year":"2025","journal-title":"New J. Chem."},{"key":"2026090910091640200_cit26","doi-asserted-by":"publisher","first-page":"16180","DOI":"10.1039\/D5SC04835D","article-title":"Controlling\nMolecular Machines via Optimally Oriented External Electric Fields","volume":"16","author":"Severi","year":"2025","journal-title":"Chem. Sci."},{"key":"2026090910091640200_cit27","doi-asserted-by":"publisher","first-page":"2595","DOI":"10.1039\/D2CP04557E","article-title":"Impacts of External\nFields on Aromaticity and Acidity of Benzoic Acid: A Density Functional\nTheory, Conceptual Density Functional Theory and Information-Theoretic\nApproach Study","volume":"25","author":"Li","year":"2023","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"17","key":"2026090910091640200_cit28","doi-asserted-by":"publisher","first-page":"2105667","DOI":"10.1002\/advs.202105667","article-title":"Dual Modulation\nof Single Molecule\nConductance via Tuning Side Chains and Electric Field with Conjugated\nMolecules Entailing Intramolecular O\u2022\u2022\u2022S Interactions","volume":"9","author":"Zhang","year":"2022","journal-title":"Adv. Sci."},{"key":"2026090910091640200_cit29","doi-asserted-by":"publisher","first-page":"121410","DOI":"10.1016\/j.jlumin.2025.121410","article-title":"ESIPT Molecular\nProbe FET: Electric Field Effect on\nSpectral Properties","volume":"286","author":"Tomin","year":"2025","journal-title":"J. Lumin."},{"key":"2026090910091640200_cit30","doi-asserted-by":"publisher","first-page":"108404","DOI":"10.1016\/j.cclet.2023.108404","article-title":"Electric Field-Driven\nFolding of Single Molecules","volume":"35","author":"Yuan","year":"2024","journal-title":"Chin. Chem. Lett."},{"key":"2026090910091640200_cit31","doi-asserted-by":"publisher","first-page":"3397","DOI":"10.1038\/s41467-023-39206-w","article-title":"Local Cation-Tuned Reversible Single-Molecule\nSwitch in Electric Double Layer","volume":"14","author":"Tong","year":"2023","journal-title":"Nat. Commun."},{"key":"2026090910091640200_cit32","doi-asserted-by":"publisher","first-page":"101032","DOI":"10.1016\/j.coelec.2022.101032","article-title":"Electric Fields as Actuators in Unimolecular\nContacts","volume":"35","author":"Domke","year":"2022","journal-title":"Curr. Opin. Electrochem."},{"key":"2026090910091640200_cit33","doi-asserted-by":"publisher","first-page":"9094","DOI":"10.1021\/acs.jpclett.1c02578","article-title":"Electric Field Controlled\nSingle-Molecule Optical Switch by Through-Space Charge Transfer State","volume":"12","author":"Tian","year":"2021","journal-title":"J. Phys. Chem. Lett."},{"key":"2026090910091640200_cit34","doi-asserted-by":"publisher","first-page":"9565","DOI":"10.1021\/jacs.1c03882","article-title":"How to\nManipulate\nThrough-Space Conjugation and Clusteroluminescence of Simple AIEgens\nwith Isolated Phenyl Rings","volume":"143","author":"Zhang","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"2026090910091640200_cit35","doi-asserted-by":"publisher","first-page":"11456","DOI":"10.1039\/D3SC03892K","article-title":"Regulating the Orientation of a Single Coordinate Bond\nby the Synergistic Action of Mechanical Forces and Electric Field","volume":"14","author":"Zhang","year":"2023","journal-title":"Chem. Sci."},{"key":"2026090910091640200_cit36","doi-asserted-by":"publisher","first-page":"3941","DOI":"10.1021\/acsmaterialslett.4c01182","article-title":"Activating Electronic\nDelocalization: Through-Space Lone-Pair Interactions versus Hydrogen\nBonding","volume":"6","author":"Xiong","year":"2024","journal-title":"ACS Mater. Lett."},{"key":"2026090910091640200_cit37","doi-asserted-by":"publisher","first-page":"21","DOI":"10.1038\/s43586-024-00298-3","article-title":"Fluorescence Resonance Energy Transfer\nat the Single-Molecule Level","volume":"4","author":"Ha","year":"2024","journal-title":"Nat. Rev. Methods\nPrimers"},{"key":"2026090910091640200_cit38","doi-asserted-by":"publisher","first-page":"45","DOI":"10.1038\/s41566-017-0056-5","article-title":"Room-Temperature Ultrafast Nonlinear\nSpectroscopy of a Single Molecule","volume":"12","author":"Liebel","year":"2018","journal-title":"Nat. Photonics"},{"key":"2026090910091640200_cit39","doi-asserted-by":"publisher","first-page":"2107220","DOI":"10.1002\/smll.202107220","article-title":"The Evolution\nof the Charge Transport Mechanism in Single-Molecule Break Junctions\nRevealed by Flicker Noise Analysis","volume":"18","author":"Pan","year":"2022","journal-title":"Small"},{"key":"2026090910091640200_cit40","doi-asserted-by":"publisher","first-page":"4097","DOI":"10.1021\/acs.jpcc.4c07780","article-title":"Digging through\nthe (Statistical) Dirt: A Reproducible Method for Single-Molecule\nFlicker Noise Analysis","volume":"129","author":"Morris","year":"2025","journal-title":"J. Phys. Chem. C"},{"key":"2026090910091640200_cit41","doi-asserted-by":"publisher","first-page":"3476","DOI":"10.1021\/acsnano.1c11433","article-title":"Single-Molecule Junction: A Reliable Platform for Monitoring\nMolecular Physical and Chemical Processes","volume":"16","author":"Xie","year":"2022","journal-title":"ACS\nNano"},{"key":"2026090910091640200_cit42","doi-asserted-by":"publisher","first-page":"8378","DOI":"10.1002\/anie.201901228","article-title":"Unusual\nLength Dependence of the Conductance in Cumulene Molecular Wires","volume":"58","author":"Xu","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090910091640200_cit43","doi-asserted-by":"publisher","first-page":"16264","DOI":"10.1021\/jacs.7b08592","article-title":"Why Do Simple Molecules with \u201cIsolated\u201d\nPhenyl Rings Emit Visible Light?","volume":"139","author":"Zhang","year":"2017","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026090910091640200_cit44","doi-asserted-by":"publisher","first-page":"3885","DOI":"10.1039\/b003010o","article-title":"A Critical\nAccount on \u03c0\u2013\u03c0 Stacking in Metal Complexes with\nAromatic Nitrogen-Containing Ligands","author":"Janiak","year":"2000","journal-title":"J. Chem.\nSoc., Dalton Trans."},{"key":"2026090910091640200_cit45","doi-asserted-by":"publisher","first-page":"8487","DOI":"10.1021\/acs.chemrev.1c00648","article-title":"Dynamics\nof Excitons in Conjugated Molecules and Organic Semiconductor Systems","volume":"122","author":"Dimitriev","year":"2022","journal-title":"Chem. Rev."},{"key":"2026090910091640200_cit46","doi-asserted-by":"publisher","first-page":"699","DOI":"10.3762\/bjnano.2.76","article-title":"An MCBJ Case\nStudy: The Influence of \u03c0-Conjugation on the Single-Molecule\nConductance at a Solid\/Liquid Interface","volume":"2","author":"Hong","year":"2011","journal-title":"Beilstein\nJ. Nanotechnol."},{"key":"2026090910091640200_cit47","doi-asserted-by":"publisher","first-page":"223","DOI":"10.1021\/acs.chemrev.4c00327","article-title":"Utilization of Electric\nFields to Modulate Molecular Activities on the Nanoscale: From Physical\nProperties to Chemical Reactions","volume":"125","author":"Yang","year":"2025","journal-title":"Chem. Rev."},{"key":"2026090910091640200_cit48","doi-asserted-by":"publisher","first-page":"2500","DOI":"10.1038\/s41467-023-38078-4","article-title":"A Molecular Descriptor\nof Intramolecular Noncovalent Interaction for Regulating Optoelectronic\nProperties of Organic Semiconductors","volume":"14","author":"Liu","year":"2023","journal-title":"Nat. Commun."},{"key":"2026090910091640200_cit49","doi-asserted-by":"publisher","first-page":"1617","DOI":"10.1021\/jacs.2c09656","article-title":"Enhanced \u03c0\u2013\u03c0 Stacking\nbetween Dipole-Bearing Single\nMolecules Revealed by Conductance Measurement","volume":"145","author":"Zhang","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"2026090910091640200_cit50","doi-asserted-by":"publisher","first-page":"14607","DOI":"10.1039\/D4CP01277A","article-title":"Regulation\nof \u03c0\u2013\u03c0 Interactions between Single Aromatic Molecules\nby Bias Voltage","volume":"26","author":"Xu","year":"2024","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026090910091640200_cit51","doi-asserted-by":"publisher","first-page":"6230","DOI":"10.1039\/D2CS00006G","article-title":"Understanding\nMolecular and Electrochemical Charge Transfer: Theory and Computations","volume":"52","author":"Nazmutdinov","year":"2023","journal-title":"Chem. Soc. Rev."},{"key":"2026090910091640200_cit52","doi-asserted-by":"publisher","first-page":"10233","DOI":"10.1021\/acs.jpclett.3c02657","article-title":"Electric-Field Effects\non the Internal Charge Reorganization Energies of Crystalline Organic\nSemiconductors","volume":"14","author":"Wang","year":"2023","journal-title":"J. Phys. Chem. Lett."},{"key":"2026090910091640200_cit53","doi-asserted-by":"publisher","first-page":"15689","DOI":"10.1021\/jacs.2c05909","article-title":"Quantum Interference-Controlled Conductance Enhancement\nin Stacked Graphene-like Dimers","volume":"144","author":"Li","year":"2022","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026090910091640200_cit54","doi-asserted-by":"publisher","first-page":"8340","DOI":"10.1021\/acs.nanolett.1c02915","article-title":"Transition\nbetween Nonresonant and Resonant Charge Transport in Molecular Junctions","volume":"21","author":"Li","year":"2021","journal-title":"Nano Lett."}],"container-title":["Journal of the American\nChemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c10294","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/35\/38111\/67492915\/jacs.6c10294.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/35\/38111\/67492915\/jacs.6c10294.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T15:27:49Z","timestamp":1788967669000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/35\/38111\/5337611\/Electric-Field-Gating-of-Dynamic-through-Space"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,27]]},"references-count":54,"journal-issue":{"issue":"35","published-online":{"date-parts":[[2026,8,27]]},"published-print":{"date-parts":[[2026,9,9]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c10294","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,27]]}}}