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However, existing materials with robust performance over a broad temperature range are limited, especially if functional properties in addition to NZTE are sought. We report a data-driven materials design investigation and find that the zinc-blende structure is an excellent platform for obtaining NZTE and elucidating underlying crystal-chemical principles. Based on these, we introduced vacancy engineering and stuffed-atom incorporation, yielding a series of cubic quaternary chalcogenides AM3M\u2032X4, where linkage ion vibrations are systematically modulated. We found that NaAg3TiS4, NaAg3TiSe4, and RbAg3TiSe4 are promising NZTE candidates with coefficients of thermal expansion below 2 \u00d7 10\u20136 K\u20131 over extended temperature windows (300\u2013600 K). These are semiconducting materials distinct from low-thermal-expansion oxides. We explain the NZTE via the synergistic contributions of lattice softening, rigid-unit tilting, and linkage-ion transverse vibrations to the negative Gru\u0308neisen parameters. The stuffing of the zinc blende-based lattice provides a chemical way of tuning the linkage-ion transverse modes, thus controlling the thermal expansion in order to obtain NZTE.<\/jats:p>","DOI":"10.1021\/jacs.6c10467","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T11:41:28Z","timestamp":1788435688000},"page":"38913-38923","source":"Crossref","is-referenced-by-count":1,"title":["Wide-Temperature-Range\nNear-Zero Thermal Expansion\nvia Stuffing-Controlled Dynamics in Diamond-Like Materials"],"prefix":"10.1021","volume":"148","author":[{"given":"Yingjian","family":"Li","sequence":"first","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, Jilin, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianshu","family":"Li","sequence":"additional","affiliation":[{"name":"Imperial College London , , ,","place":["London, U.K., SW7 2AZ"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhao","family":"Fu","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7750-1485","authenticated-orcid":true,"given":"David J.","family":"Singh","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]},{"name":"University of Missouri , , , ,","place":["Columbia, Missouri, United States, 65211"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6438-5486","authenticated-orcid":true,"given":"Lijun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Jilin University , , , ,","place":["Changchun, Jilin, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,1]]},"reference":[{"key":"2026091609113013100_cit1","doi-asserted-by":"publisher","first-page":"8320","DOI":"10.1021\/jacs.6b02370","article-title":"New insights into the negative thermal\nexpansion: Direct experimental evidence for the \u201cguitar-string\u201d\neffect in cubic ScF3","volume":"138","author":"Hu","year":"2016","journal-title":"J. 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