{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,29]],"date-time":"2026-10-29T20:19:07Z","timestamp":1793305147464,"version":"4.5.0"},"reference-count":45,"publisher":"American Chemical Society (ACS)","issue":"31","license":[{"start":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T00:00:00Z","timestamp":1785369600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"name":"Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education","award":["NRF-2022R1I1A1A01071747"],"award-info":[{"award-number":["NRF-2022R1I1A1A01071747"]}]},{"name":"National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT)","award":["RS-2026-25469493 and RS-2024-00397807"],"award-info":[{"award-number":["RS-2026-25469493 and RS-2024-00397807"]}]},{"name":"Bio&Medical Technology Development Program of the National Research Foundation (NRF) funded by the Korean government (MSIT)","award":["RS-2023-00222838"],"award-info":[{"award-number":["RS-2023-00222838"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Surface-enhanced Raman scattering (SERS) is based on a highly localized electric field (E-field), i.e., hotspot, on plasmonic nanostructures and enables a wide variety of ultrasensitive molecular-fingerprint sensing applications. However, reliably forming and controlling hotspots, and positioning molecules within them to reproducibly obtain maximal and quantitative Raman signals, remains challenging. Here, we designed and synthesized gold nanocrevice-gap nanosnowman particles (AuNCNSs) that feature a superlocalized E-field inside the nanocrevice gap via surface-modified DNA-directed nanostructure growth chemistry. AuNCNSs facilitate a capacitive plasmon mode with an intense, broadly distributed near-field enhancement, yielding a 157-fold amplification (analytical SERS enhancement factor = \u223c3.1 \u00d7 1010). Remarkably, \u223c10% of Raman dyes confined within the nanocrevice gap contribute to \u223c90% of the total SERS intensity, effectively dividing SERS signal generation and target-sensing regions. Further, the Raman dyes adsorbed outside the nanocrevice gap region can be washed away with minimal signal loss, freeing the non-nanocrevice-gap nanoparticle surface for reliable and efficient functional ligand modification such as antibodies or DNA. The SERS tag-linked immunosorbent assay (SLISA) with antibody-modified AuNCNSs can detect as low as 10 fM viral targets, which is a 100-fold better sensitivity than conventional ELISA results for the same target, and the dynamic range is &amp;gt;5 orders of magnitude, ranging from 10 fM to &amp;gt;1 nM. Importantly, the specificity of the AuNCNS immunoassay is extraordinary, with almost undetectable SERS signals for nonspecific influenza targets, suggesting that AuNCNSs can be promising bioprobe platforms with high sensitivity and reliable target quantification capability by super-colocalizing Raman dyes and E-field inside the nanocrevice gap along with highly reliable and stable ligand modification on open non-NCG particle surfaces.<\/jats:p>","DOI":"10.1021\/jacs.6c10937","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:23:00Z","timestamp":1785849780000},"page":"33719-33726","source":"Crossref","is-referenced-by-count":1,"title":["Plasmonic\nNanocrevice-Gap Nanosnowman Particles Enabling\nColocalization of Raman Reporters with Super-Localized Electric Fields\nfor Highly Sensitive, Specific, and Quantitative Surface-Enhanced\nRaman Scattering Biosensing"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2401-9040","authenticated-orcid":true,"given":"Gyeong-Hwan","family":"Kim","sequence":"first","affiliation":[{"name":"Seoul National University , , Gwanak-ro 1 , , ,","place":["Gwanak-gu, Seoul, South Korea, 08826"]},{"name":"Seoul National University , , Gwanak-ro 1 , , ,","place":["Gwanak-gu, Seoul, South Korea, 08826"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yeong Seok","family":"Cha","sequence":"additional","affiliation":[{"name":"Seoul National University , , Gwanak-ro 1 , , ,","place":["Gwanak-gu, Seoul, South Korea, 08826"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoonhee","family":"Kim","sequence":"additional","affiliation":[{"name":"Seoul National University , , Gwanak-ro 1 , , ,","place":["Gwanak-gu, Seoul, South Korea, 08826"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3229-6427","authenticated-orcid":true,"given":"Jung-Hoon","family":"Lee","sequence":"additional","affiliation":[{"name":"Soonchunhyang University , , ,","place":["Asan, South Korea, 31538"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1606-0716","authenticated-orcid":true,"given":"Jeong-Wook","family":"Oh","sequence":"additional","affiliation":[{"name":"Hankuk University of Foreign Studies , , Oedae-ro 81 , Mohyeon-eup, Cheoin-gu, ,","place":["Yongin, South Korea, 17035"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7891-8482","authenticated-orcid":true,"given":"Jwa-Min","family":"Nam","sequence":"additional","affiliation":[{"name":"Seoul National University , , Gwanak-ro 1 , , ,","place":["Gwanak-gu, Seoul, South Korea, 08826"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,30]]},"reference":[{"issue":"8009","key":"2026081210090077500_cit1","doi-asserted-by":"publisher","first-page":"771","DOI":"10.1038\/s41586-024-07218-1","article-title":"Digital Colloid-Enhanced\nRaman Spectroscopy by Single-Molecule Counting","volume":"628","author":"Bi","year":"2024","journal-title":"Nature"},{"issue":"37","key":"2026081210090077500_cit2","doi-asserted-by":"publisher","first-page":"25359","DOI":"10.1021\/acsnano.4c09218","article-title":"Integrating,\nValidating, and Expanding Information Space in Single-Molecule Surface-Enhanced\nRaman Spectroscopy for Biomolecules","volume":"18","author":"Lee","year":"2024","journal-title":"ACS Nano"},{"issue":"38","key":"2026081210090077500_cit3","doi-asserted-by":"publisher","first-page":"25930","DOI":"10.1021\/acsnano.4c09483","article-title":"Single-Molecule\nSurface-Enhanced\nRaman Spectroscopy: Challenges, Opportunities, and Future Directions","volume":"18","author":"Schmidt","year":"2024","journal-title":"ACS Nano"},{"issue":"9","key":"2026081210090077500_cit4","doi-asserted-by":"publisher","first-page":"8381","DOI":"10.1021\/acsnano.4c15877","article-title":"Surface Enhanced Raman\nScattering for Biomolecular Sensing in Human Healthcare Monitoring","volume":"19","author":"Laing","year":"2025","journal-title":"ACS Nano"},{"issue":"47","key":"2026081210090077500_cit5","doi-asserted-by":"publisher","first-page":"32287","DOI":"10.1021\/acsnano.4c07037","article-title":"Shell-Isolated\nNanoparticle-Enhanced Raman Spectroscopy: Toward High Sensitivity\nand Broad Applicability","volume":"18","author":"Zhu","year":"2024","journal-title":"ACS Nano"},{"issue":"47","key":"2026081210090077500_cit6","doi-asserted-by":"publisher","first-page":"32315","DOI":"10.1021\/acsnano.4c12996","article-title":"Surface-Enhanced\nRaman Scattering-Based Multimodal Techniques: Advances and Perspectives","volume":"18","author":"Tan","year":"2024","journal-title":"ACS Nano"},{"issue":"3","key":"2026081210090077500_cit7","doi-asserted-by":"publisher","first-page":"1453","DOI":"10.1039\/D4CS00883A","article-title":"Surface-Enhanced Raman Spectroscopy:\nA Half-Century Historical Perspective","volume":"54","author":"Yi","year":"2025","journal-title":"Chem.\nSoc. Rev."},{"issue":"22","key":"2026081210090077500_cit8","doi-asserted-by":"publisher","first-page":"14000","DOI":"10.1021\/acsnano.4c02670","article-title":"Surface-Enhanced\nRaman Spectroscopy: Current Understanding, Challenges, and Opportunities","volume":"18","author":"Ma","year":"2024","journal-title":"ACS Nano"},{"issue":"5","key":"2026081210090077500_cit9","doi-asserted-by":"publisher","first-page":"253","DOI":"10.1038\/s42254-020-0171-y","article-title":"Fundamental\nUnderstanding and Applications of Plasmon-Enhanced Raman Spectroscopy","volume":"2","author":"Wang","year":"2020","journal-title":"Nat. Rev. Phys."},{"issue":"22","key":"2026081210090077500_cit10","doi-asserted-by":"publisher","first-page":"2303001","DOI":"10.1002\/adma.202303001","article-title":"Perspective on Tailored\nNanostructure-Dominated SPP Effects for SERS","volume":"36","author":"Hu","year":"2024","journal-title":"Adv. Mater."},{"issue":"1","key":"2026081210090077500_cit11","doi-asserted-by":"publisher","first-page":"11307","DOI":"10.1038\/s41467-025-66454-9","article-title":"Shell-Isolated\nNanoparticle-Enhanced Femtosecond Stimulated Raman Spectroscopy Reveals\nUltrafast Molecular Dynamics of Surface Reactions","volume":"16","author":"Sun","year":"2025","journal-title":"Nat. Commun."},{"issue":"1","key":"2026081210090077500_cit12","doi-asserted-by":"publisher","first-page":"28","DOI":"10.1021\/acsnano.9b04224","article-title":"Present\nand Future of Surface-Enhanced Raman Scattering","volume":"14","author":"Langer","year":"2020","journal-title":"ACS Nano"},{"issue":"28","key":"2026081210090077500_cit13","doi-asserted-by":"publisher","first-page":"2503562","DOI":"10.1002\/advs.202503562","article-title":"Helicobacter Pylori\nDetection Based on Synergistic Electromagnetic and Chemical Enhancement\nof Surface-Enhanced Raman Scattering in 3D Hotspot-Activated Gold\nNanorods\/Nano Mica Platelets\/ZnO Quantum Dots","volume":"12","author":"Lu","year":"2025","journal-title":"Adv. Sci."},{"issue":"14","key":"2026081210090077500_cit14","doi-asserted-by":"publisher","first-page":"13604","DOI":"10.1021\/acsanm.3c02258","article-title":"Triangular Silver\nNanoplates\/Graphene Oxide Nanohybrids\non Flexible Substrates for Detection of Bacteria via Surface-Enhanced\nRaman Spectroscopy","volume":"6","author":"Chen","year":"2023","journal-title":"ACS Appl. Nano Mater."},{"issue":"3","key":"2026081210090077500_cit15","doi-asserted-by":"publisher","first-page":"1073","DOI":"10.1021\/acsabm.1c01151","article-title":"Hydrophilic\u2013Hydrophobic\nNanohybrids of AuNP-Immobilized Two-Dimensional Nanomica Platelets\nas Flexible Substrates for High-Efficiency and High-Selectivity Surface-Enhanced\nRaman Scattering Microbe Detection","volume":"5","author":"Chen","year":"2022","journal-title":"ACS Appl.\nBio Mater."},{"issue":"11","key":"2026081210090077500_cit16","doi-asserted-by":"publisher","first-page":"12321","DOI":"10.1021\/jacs.6c02165","article-title":"Dynamic Electrochemical Reorientation at SERS Hotspots\nEnables Composition, Length, and Sequence Reading of DNA Oligonucleotides","volume":"148","author":"Tran","year":"2026","journal-title":"J. Am. Chem. Soc."},{"issue":"5887","key":"2026081210090077500_cit17","doi-asserted-by":"publisher","first-page":"388","DOI":"10.1126\/science.1159499","article-title":"Measurement of the Distribution of\nSite Enhancements in Surface-Enhanced Raman Scattering","volume":"321","author":"Fang","year":"2008","journal-title":"Science"},{"issue":"12","key":"2026081210090077500_cit18","doi-asserted-by":"publisher","first-page":"2180","DOI":"10.1002\/anie.200806139","article-title":"Isolating and Probing\nthe Hot Spot Formed between Two Silver Nanocubes","volume":"48","author":"Camargo","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"issue":"1","key":"2026081210090077500_cit19","doi-asserted-by":"publisher","first-page":"60","DOI":"10.1038\/nmat2596","article-title":"Nanogap-Engineerable\nRaman-Active Nanodumbbells for Single-Molecule Detection","volume":"9","author":"Lim","year":"2010","journal-title":"Nat. Mater."},{"issue":"7","key":"2026081210090077500_cit20","doi-asserted-by":"publisher","first-page":"452","DOI":"10.1038\/nnano.2011.79","article-title":"Highly Uniform and\nReproducible Surface-Enhanced\nRaman Scattering from DNA-Tailorable Nanoparticles with 1-Nm Interior\nGap","volume":"6","author":"Lim","year":"2011","journal-title":"Nat. Nanotechnol."},{"issue":"49","key":"2026081210090077500_cit21","doi-asserted-by":"publisher","first-page":"22337","DOI":"10.1021\/jacs.2c05950","article-title":"Toward Quantitative Surface-Enhanced Raman Scattering\nwith Plasmonic Nanoparticles: Multiscale View on Heterogeneities in\nParticle Morphology, Surface Modification, Interface, and Analytical\nProtocols","volume":"144","author":"Son","year":"2022","journal-title":"J. Am. Chem. Soc."},{"issue":"12","key":"2026081210090077500_cit22","doi-asserted-by":"publisher","first-page":"2746","DOI":"10.1021\/acs.accounts.6b00409","article-title":"Plasmonic\nNanogap-Enhanced\nRaman Scattering with Nanoparticles","volume":"49","author":"Nam","year":"2016","journal-title":"Acc. Chem.\nRes."},{"issue":"3","key":"2026081210090077500_cit23","doi-asserted-by":"publisher","first-page":"2992","DOI":"10.1021\/acsnano.4c14557","article-title":"Advances, Challenges, and Opportunities in Plasmonic\nNanogap-Enhanced Raman Scattering with Nanoparticles","volume":"19","author":"Kim","year":"2025","journal-title":"ACS Nano"},{"issue":"20","key":"2026081210090077500_cit24","doi-asserted-by":"publisher","first-page":"14012","DOI":"10.1021\/jacs.4c02099","article-title":"Open Cross-Gap\nGold Nanocubes with Strong, Large-Area, Symmetric Electromagnetic\nField Enhancement for On-Particle Molecular-Fingerprint Raman Bioassays","volume":"146","author":"Kim","year":"2024","journal-title":"J. Am. Chem. Soc."},{"issue":"20","key":"2026081210090077500_cit25","doi-asserted-by":"publisher","first-page":"6541","DOI":"10.1021\/acs.nanolett.5c06388","article-title":"Hybrid Plasmonic Nanostructures Using\n\u03c0-Conjugated Systems for Molecularly Imprinted Polymers","volume":"26","author":"Bleteau","year":"2026","journal-title":"Nano Lett."},{"issue":"50","key":"2026081210090077500_cit26","doi-asserted-by":"publisher","first-page":"16542","DOI":"10.1021\/jacs.6b10983","article-title":"DNA-Mediated Morphological\nControl\nof Pd\u2013Au Bimetallic Nanoparticles","volume":"138","author":"Satyavolu","year":"2016","journal-title":"J.\nAm. Chem. Soc."},{"issue":"5","key":"2026081210090077500_cit27","doi-asserted-by":"publisher","first-page":"1886","DOI":"10.1021\/nl100675p","article-title":"DNA-Mediated\nControl of Metal Nanoparticle Shape: One-Pot Synthesis and Cellular\nUptake of Highly Stable and Functional Gold Nanoflowers","volume":"10","author":"Wang","year":"2010","journal-title":"Nano Lett."},{"issue":"36","key":"2026081210090077500_cit28","doi-asserted-by":"publisher","first-page":"9078","DOI":"10.1002\/anie.201203716","article-title":"Discovery\nof the DNA \u201cGenetic Code\u201d for Abiological Gold Nanoparticle\nMorphologies","volume":"51","author":"Wang","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"issue":"45","key":"2026081210090077500_cit29","doi-asserted-by":"publisher","first-page":"14456","DOI":"10.1021\/jacs.5b09567","article-title":"Mechanistic\nInsight into DNA-Guided Control of Nanoparticle\nMorphologies","volume":"137","author":"Tan","year":"2015","journal-title":"J. Am. Chem. Soc."},{"issue":"1","key":"2026081210090077500_cit30","doi-asserted-by":"publisher","first-page":"3831","DOI":"10.1038\/s41467-022-31513-y","article-title":"Adenine Oligomer\nDirected Synthesis of Chiral Gold\nNanoparticles","volume":"13","author":"Cho","year":"2022","journal-title":"Nat. Commun."},{"issue":"11","key":"2026081210090077500_cit31","doi-asserted-by":"publisher","first-page":"6693","DOI":"10.1021\/nl503441v","article-title":"Shape-Controlled\nSynthesis\nof Gold Nanostructures Using DNA Origami Molds","volume":"14","author":"Helmi","year":"2014","journal-title":"Nano Lett."},{"issue":"1","key":"2026081210090077500_cit32","doi-asserted-by":"publisher","first-page":"12873","DOI":"10.1038\/ncomms12873","article-title":"Gold Nanocrystals\nwith DNA-Directed Morphologies","volume":"7","author":"Ma","year":"2016","journal-title":"Nat. Commun."},{"issue":"14","key":"2026081210090077500_cit33","doi-asserted-by":"publisher","first-page":"6311","DOI":"10.1021\/jacs.1c13116","article-title":"Single-Stranded DNA-Encoded Gold Nanoparticle Clusters\nas Programmable\nEnzyme Equivalents","volume":"144","author":"Chen","year":"2022","journal-title":"J. Am. Chem. Soc."},{"issue":"40","key":"2026081210090077500_cit34","doi-asserted-by":"publisher","first-page":"14052","DOI":"10.1021\/ja504270d","article-title":"Thiolated\nDNA-Based Chemistry and Control in the Structure and Optical Properties\nof Plasmonic Nanoparticles with Ultrasmall Interior Nanogap","volume":"136","author":"Oh","year":"2014","journal-title":"J. Am. Chem. Soc."},{"issue":"34","key":"2026081210090077500_cit35","doi-asserted-by":"publisher","first-page":"4726","DOI":"10.1002\/smll.201600289","article-title":"Synthesis, Optical Properties, and\nMultiplexed Raman Bio-Imaging of Surface Roughness-Controlled Nanobridged\nNanogap Particles","volume":"12","author":"Lee","year":"2016","journal-title":"Small"},{"issue":"11","key":"2026081210090077500_cit36","doi-asserted-by":"publisher","first-page":"4460","DOI":"10.1039\/C4SC01792G","article-title":"Gold Nanostructures\nEncoded by Non-Fluorescent Small Molecules in PolyA-Mediated Nanogaps\nas Universal SERS Nanotags for Recognizing Various Bioactive Molecules","volume":"5","author":"Zhao","year":"2014","journal-title":"Chem. Sci."},{"issue":"12","key":"2026081210090077500_cit37","doi-asserted-by":"publisher","first-page":"5456","DOI":"10.1021\/ja2121525","article-title":"Directional Synthesis and Assembly\nof Bimetallic Nanosnowmen with DNA","volume":"134","author":"Lee","year":"2012","journal-title":"J. Am. Chem.\nSoc."},{"issue":"11","key":"2026081210090077500_cit38","doi-asserted-by":"publisher","first-page":"6217","DOI":"10.1021\/nl502541u","article-title":"Plasmonic Nanosnowmen\nwith a Conductive Junction as Highly Tunable Nanoantenna Structures\nand Sensitive, Quantitative and Multiplexable Surface-Enhanced Raman\nScattering Probes","volume":"14","author":"Lee","year":"2014","journal-title":"Nano Lett."},{"issue":"12","key":"2026081210090077500_cit39","doi-asserted-by":"publisher","first-page":"19853","DOI":"10.1021\/acsnano.1c07319","article-title":"Polysorbate-\nAnd DNA-Mediated Synthesis and Strong, Stable, and Tunable Near-Infrared\nPhotoluminescence of Plasmonic Long-Body Nanosnowmen","volume":"15","author":"Kim","year":"2021","journal-title":"ACS Nano"},{"issue":"3","key":"2026081210090077500_cit40","doi-asserted-by":"publisher","first-page":"731","DOI":"10.1007\/s12274-014-0556-2","article-title":"Bimetallic Nano-Mushrooms with DNA-Mediated Interior Nanogaps for\nHigh-Efficiency SERS Signal Amplification","volume":"8","author":"Shen","year":"2015","journal-title":"Nano\nRes."},{"issue":"15","key":"2026081210090077500_cit41","doi-asserted-by":"publisher","first-page":"2208250","DOI":"10.1002\/adma.202208250","article-title":"Plasmonic Dual-Gap Nanodumbbells\nfor Label-Free On-Particle Raman DNA Assays","volume":"35","author":"Kim","year":"2023","journal-title":"Adv. Mater."},{"issue":"21","key":"2026081210090077500_cit42","doi-asserted-by":"publisher","first-page":"9988","DOI":"10.1364\/OE.14.009988","article-title":"Plasmons\nin Nearly Touching Metallic Nanoparticles: Singular Response in the\nLimit of Touching Dimers","volume":"14","author":"Romero","year":"2006","journal-title":"Opt. Express"},{"issue":"14","key":"2026081210090077500_cit43","doi-asserted-by":"publisher","first-page":"10974","DOI":"10.1021\/acsnano.5c19943","article-title":"Plasmon\nMode-Selective Gold Nanodimers\nwith a Metal\u2013Semiconductor Hybrid Junction","volume":"20","author":"Albert","year":"2026","journal-title":"ACS Nano"},{"issue":"24","key":"2026081210090077500_cit44","doi-asserted-by":"publisher","first-page":"8313","DOI":"10.1021\/ac0613582","article-title":"Maximizing DNA Loading on a Range\nof Gold Nanoparticle Sizes","volume":"78","author":"Hurst","year":"2006","journal-title":"Anal. Chem."},{"issue":"2","key":"2026081210090077500_cit45","doi-asserted-by":"publisher","first-page":"85","DOI":"10.1007\/s13233-023-00131-y","article-title":"Non-Specific Protein\nRemoval and Specific Protein Capture\nSimultaneously Using a Hydrodynamic Force Induced under Vortex Flow","volume":"31","author":"Liu","year":"2023","journal-title":"Macromol. Res."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c10937","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/31\/33719\/66342561\/jacs.6c10937.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/31\/33719\/66342561\/jacs.6c10937.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T14:24:13Z","timestamp":1786544653000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/31\/33719\/5237395\/Plasmonic-Nanocrevice-Gap-Nanosnowman-Particles"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,30]]},"references-count":45,"journal-issue":{"issue":"31","published-online":{"date-parts":[[2026,7,30]]},"published-print":{"date-parts":[[2026,8,12]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c10937","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,30]]}}}