{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T02:40:57Z","timestamp":1790217657194,"version":"4.1.0"},"reference-count":51,"publisher":"American Chemical Society (ACS)","issue":"34","license":[{"start":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T00:00:00Z","timestamp":1787529600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T00:00:00Z","timestamp":1787529600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T00:00:00Z","timestamp":1787529600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/na","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22176036"],"award-info":[{"award-number":["22176036"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22376028"],"award-info":[{"award-number":["22376028"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22494680"],"award-info":[{"award-number":["22494680"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22494684"],"award-info":[{"award-number":["22494684"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22576036"],"award-info":[{"award-number":["22576036"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Ice is ubiquitous in natural environments, yet the interstitial liquid trapped within polycrystalline grain boundaries remains difficult to access, limiting mechanistic understanding of accelerated reactions in ice. Here, we combine cryogenic stimulated Raman scattering microscopy with multivariate curve resolution to visualize and spectroscopically resolve internal constituents of frozen microdroplets. We identify pronounced structural heterogeneity: the entrapped interstitial liquid displays more strongly hydrogen-bonded water signatures than bulk supercooled water, whereas the ice\u2013water interface shows diminished orientational ordering, whereby water hydrogen atoms are less preferentially aligned toward solutes, consistent with frustrated solvation and partial desolvation. Using sulfur dioxide autoxidation as a model reaction, we find that frozen microdroplets exhibit an approximately 20-fold faster apparent oxidation rate than supercooled liquid microdroplets under otherwise comparable conditions. Kinetic analysis and simulations suggest that interfacial frustrated solvation, together with grain boundary acidification, lowers the effective barrier for electron transfer and radical initiation and the associated enhancement of sulfate formation. These findings provide a microscopic link between buried ice\u2013water interfacial structure and low-temperature reaction kinetics, with implications for atmospheric chemistry in cold and mixed-phase environments.<\/jats:p>","DOI":"10.1021\/jacs.6c11450","type":"journal-article","created":{"date-parts":[[2026,8,30]],"date-time":"2026-08-30T12:42:26Z","timestamp":1788093746000},"page":"37134-37143","source":"Crossref","is-referenced-by-count":1,"title":["Frustrated\nInterfacial Solvation Enhances Reaction\nRates at Acidified Ice Grain Boundaries in Frozen Microdroplets"],"prefix":"10.1021","volume":"148","author":[{"given":"Runbo","family":"Wang","sequence":"first","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]},{"name":"Central South University , , ,","place":["Changsha, People\u2019s Republic of China, 410083"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-2661-1577","authenticated-orcid":true,"given":"Kuan","family":"Luo","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9137-5243","authenticated-orcid":true,"given":"Tao","family":"Wang","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]},{"name":"Shanghai Institute of Pollution Control and Ecological Security , ,","place":["Shanghai, People\u2019s Republic of China, 200092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9409-8656","authenticated-orcid":true,"given":"Yu","family":"Wei","sequence":"additional","affiliation":[{"name":"Nanjing University , , ,","place":["Nanjing, People\u2019s Republic of China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jilun","family":"Wang","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Le","family":"Yang","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenbo","family":"You","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiuyue","family":"Ge","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5118-4901","authenticated-orcid":true,"given":"Yangyang","family":"Liu","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minglu","family":"Ma","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kejian","family":"Li","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9746-4466","authenticated-orcid":true,"given":"Yuting","family":"Lyu","sequence":"additional","affiliation":[{"name":"Universite Claude Bernard Lyon 1, CNRS, IRCELYON , UMR 5256 , ,","place":["Villeurbanne, France, F-69100"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laurentiu-Gabriel","family":"Movila","sequence":"additional","affiliation":[{"name":"Universite Claude Bernard Lyon 1, CNRS, IRCELYON , UMR 5256 , ,","place":["Villeurbanne, France, F-69100"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7693-1125","authenticated-orcid":true,"given":"Xiang","family":"Sun","sequence":"additional","affiliation":[{"name":"Nanjing University , , ,","place":["Nanjing, People\u2019s Republic of China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1979-4395","authenticated-orcid":true,"given":"Huiming","family":"Bao","sequence":"additional","affiliation":[{"name":"Nanjing University , , ,","place":["Nanjing, People\u2019s Republic of China, 210023"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5859-3070","authenticated-orcid":true,"given":"Jianmin","family":"Chen","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1578-7056","authenticated-orcid":true,"given":"Christian","family":"George","sequence":"additional","affiliation":[{"name":"Universite Claude Bernard Lyon 1, CNRS, IRCELYON , UMR 5256 , ,","place":["Villeurbanne, France, F-69100"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Norimichi","family":"Takenaka","sequence":"additional","affiliation":[{"name":"Osaka Metropolitan University , , 1\u22121 Gakuen\u2212cho, Naka\u2212ku , , ,","place":["Sakai\u2212shi, Osaka, Japan, 599\u22128531"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3464-7825","authenticated-orcid":true,"given":"Markku","family":"Kulmala","sequence":"additional","affiliation":[{"name":"University of Helsinki , , ,","place":["Helsinki, Finland, FIN-00014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minbiao","family":"Ji","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0765-8660","authenticated-orcid":true,"given":"Liwu","family":"Zhang","sequence":"additional","affiliation":[{"name":"Fudan University , , ,","place":["Shanghai, People\u2019s Republic of China, 200433"]},{"name":"Shanghai Institute of Pollution Control and Ecological Security , ,","place":["Shanghai, People\u2019s Republic of China, 200092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6600-2055","authenticated-orcid":true,"given":"Zhang","family":"Lin","sequence":"additional","affiliation":[{"name":"Central South University , , ,","place":["Changsha, People\u2019s Republic of China, 410083"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,24]]},"reference":[{"issue":"7974","key":"2026090312073774800_cit1","doi-asserted-by":"publisher","first-page":"557","DOI":"10.1038\/s41586-023-06283-2","article-title":"Microstructure and\ncrystal order during freezing of supercooled water drops","volume":"620","author":"Kalita","year":"2023","journal-title":"Nature"},{"issue":"3","key":"2026090312073774800_cit2","doi-asserted-by":"publisher","first-page":"197","DOI":"10.1038\/nchem.540","article-title":"Formation\nof mixed-phase particles during the freezing of polar stratospheric\nice clouds","volume":"2","author":"Bogdan","year":"2010","journal-title":"Nat. Chem."},{"issue":"8","key":"2026090312073774800_cit3","doi-asserted-by":"publisher","first-page":"579","DOI":"10.1038\/s41570-022-00407-4","article-title":"Chemical approaches\nto cryopreservation","volume":"6","author":"Murray","year":"2022","journal-title":"Nat. Rev. Chem."},{"issue":"1","key":"2026090312073774800_cit4","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2015.3","article-title":"Design of\nanti-icing surfaces: smooth, textured or slippery?","volume":"1","author":"Kreder","year":"2016","journal-title":"Nat. Rev. Mater."},{"issue":"3","key":"2026090312073774800_cit5","doi-asserted-by":"publisher","first-page":"1587","DOI":"10.5194\/acp-14-1587-2014","article-title":"A review of air-ice\nchemical and physical interactions (AICI): liquids, quasi-liquids,\nand solids in snow","volume":"14","author":"Bartels-Rausch","year":"2014","journal-title":"Atmos. Chem. Phys."},{"issue":"6807","key":"2026090312073774800_cit6","doi-asserted-by":"publisher","first-page":"212","DOI":"10.1126\/science.aee9519","article-title":"A single freeze cycle redirects iron\nmineral transformation","volume":"393","author":"Luo","year":"2026","journal-title":"Science"},{"issue":"6730","key":"2026090312073774800_cit7","doi-asserted-by":"publisher","first-page":"182","DOI":"10.1126\/science.adp7708","article-title":"Linear-viscous\nflow of temperate ice","volume":"387","author":"Schohn","year":"2025","journal-title":"Science"},{"issue":"10","key":"2026090312073774800_cit8","doi-asserted-by":"publisher","first-page":"1533","DOI":"10.1038\/s41563-025-02332-5","article-title":"Streaming\nflexoelectricity in saline ice","volume":"24","author":"Wen","year":"2025","journal-title":"Nat. Mater."},{"issue":"2","key":"2026090312073774800_cit9","doi-asserted-by":"publisher","first-page":"386","DOI":"10.1039\/D4AN01200C","article-title":"Witnessing a discrete microdroplet\nfreezing event via real-time electrochemical monitoring of solution\ntemperature","volume":"150","author":"Kauffmann","year":"2025","journal-title":"Analyst"},{"issue":"4","key":"2026090312073774800_cit10","doi-asserted-by":"publisher","first-page":"503","DOI":"10.1163\/156856192X00827","article-title":"Surface\ntension parameters of ice obtained from contact angle data and from\npositive and negative particle adhesion to advancing freezing fronts","volume":"6","author":"Vanoss","year":"1992","journal-title":"Adhes. Sci. Technol."},{"issue":"21","key":"2026090312073774800_cit11","doi-asserted-by":"publisher","first-page":"3199","DOI":"10.1021\/jz301411q","article-title":"Characterizing charge\ntransfer at water ice interfaces","volume":"3","author":"Lee","year":"2012","journal-title":"J. Phys. Chem.\nLett."},{"issue":"21","key":"2026090312073774800_cit12","doi-asserted-by":"publisher","DOI":"10.1063\/5.0048817","article-title":"Structure\nof the electrical double layer at the ice-water interface","volume":"154","author":"Daigle","year":"2021","journal-title":"J. Chem. Phys."},{"issue":"35","key":"2026090312073774800_cit13","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2507588122","article-title":"Ice as a kinetic\nand mechanistic driver of oxalate- promoted iron oxyhydroxide dissolution","volume":"122","author":"Sebaaly","year":"2025","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"issue":"14","key":"2026090312073774800_cit14","doi-asserted-by":"publisher","first-page":"11124","DOI":"10.1021\/acs.est.6c02314","article-title":"Spatial Ice Confinement Enabled Chemical\nReaction Acceleration for Water Purification","volume":"60","author":"Shi","year":"2026","journal-title":"Environ. Sci. Technol."},{"issue":"41","key":"2026090312073774800_cit15","doi-asserted-by":"publisher","first-page":"37290","DOI":"10.1021\/jacs.5c10587","article-title":"Inhibiting Isomerization\nvia Confinement in Ice-Water Interfaces\nEnhances Stereoselectivity in [2 + 2] Cycloaddition","volume":"147","author":"Wan","year":"2025","journal-title":"J. Am. Chem. Soc."},{"issue":"23","key":"2026090312073774800_cit16","doi-asserted-by":"publisher","first-page":"4804","DOI":"10.1021\/acs.jpclett.5b02277","article-title":"Frustrated\nsolvation structures can enhance electron transfer rates","volume":"6","author":"Remsing","year":"2015","journal-title":"J. Phys. Chem. Lett."},{"issue":"36","key":"2026090312073774800_cit17","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.ado4373","article-title":"Enhanced aqueous\nformation and neutralization of fine atmospheric\nparticles driven by extreme cold","volume":"10","author":"Campbell","year":"2024","journal-title":"Sci. Adv."},{"issue":"1","key":"2026090312073774800_cit18","doi-asserted-by":"publisher","first-page":"64","DOI":"10.1016\/j.scib.2025.06.023","article-title":"Northeast China: an\nemerging hotspot of atmospheric sciences","volume":"71","author":"Cheng","year":"2026","journal-title":"Sci.\nBull."},{"issue":"1","key":"2026090312073774800_cit19","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-63028-7","article-title":"Climate impacts and future trends\nof hailstorms in China based on\nmillennial records","volume":"16","author":"Zhang","year":"2025","journal-title":"Nat. Commun."},{"issue":"1","key":"2026090312073774800_cit20","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-48793-1","article-title":"Hydrogen peroxide\nserves as pivotal fountainhead for aerosol aqueous sulfate formation\nfrom a global perspective","volume":"15","author":"Gao","year":"2024","journal-title":"Nat. Commun."},{"key":"2026090312073774800_cit21","doi-asserted-by":"publisher","first-page":"1997","DOI":"10.5194\/acp-4-1997-2004","article-title":"Laboratory evidence for volume-dominated nucleation\nof ice in supercooled water microdroplets","volume":"4","author":"Duft","year":"2004","journal-title":"Atmos.\nChem. Phys."},{"issue":"2","key":"2026090312073774800_cit22","doi-asserted-by":"publisher","first-page":"195","DOI":"10.1111\/j.1365-2818.1974.tb03979.x","article-title":"Caveat on the use of the Delesse principle of areal\nanalysis for estimating component volume densities","volume":"102","author":"Mayhew","year":"1974","journal-title":"J. Microsc."},{"issue":"12","key":"2026090312073774800_cit23","doi-asserted-by":"publisher","first-page":"5722","DOI":"10.1021\/jacs.9b13454","article-title":"Heightened cold-denaturation\nof proteins at the ice-water interface","volume":"142","author":"Arsiccio","year":"2020","journal-title":"J. Am.\nChem. Soc."},{"issue":"11","key":"2026090312073774800_cit24","doi-asserted-by":"publisher","first-page":"2609","DOI":"10.1021\/acs.jpcb.2c09068","article-title":"Imaging low-temperature phases of ice with polarization-resolved\nhyperspectral stimulated Raman scattering microscopy","volume":"127","author":"Chen","year":"2023","journal-title":"J. Phys. Chem. B"},{"issue":"43","key":"2026090312073774800_cit25","doi-asserted-by":"publisher","first-page":"11006","DOI":"10.1021\/jp074551o","article-title":"Spectroscopic\nprobes of the quasi-liquid\nlayer on ice","volume":"111","author":"Kahan","year":"2007","journal-title":"J. Phys. Chem. A"},{"issue":"8057","key":"2026090312073774800_cit26","doi-asserted-by":"publisher","first-page":"87","DOI":"10.1038\/s41586-025-08702-y","article-title":"Water structure and\nelectric fields at the interface of oil droplets","volume":"640","author":"Shi","year":"2025","journal-title":"Nature"},{"issue":"3","key":"2026090312073774800_cit27","doi-asserted-by":"publisher","first-page":"172","DOI":"10.1038\/s41570-019-0080-8","article-title":"Surface premelting of water ice","volume":"3","author":"Slater","year":"2019","journal-title":"Nat. Rev. Chem."},{"issue":"28","key":"2026090312073774800_cit28","doi-asserted-by":"publisher","first-page":"425","DOI":"10.1007\/BF01476465","article-title":"U\u0308ber\nden Schmelzvorgang bei nichtpolaren Kristallen","volume":"30","author":"Stranski","year":"1942","journal-title":"Naturwissenschaften"},{"issue":"6399","key":"2026090312073774800_cit29","doi-asserted-by":"publisher","first-page":"278","DOI":"10.1126\/science.aao4839","article-title":"Atmospheric new particle\nformation\nfrom sulfuric acid and amines in a Chinese megacity","volume":"361","author":"Yao","year":"2018","journal-title":"Science"},{"issue":"6316","key":"2026090312073774800_cit30","doi-asserted-by":"publisher","first-page":"1119","DOI":"10.1126\/science.aaf2649","article-title":"Global atmospheric particle formation\nfrom CERN CLOUD measurements","volume":"354","author":"Dunne","year":"2016","journal-title":"Science"},{"issue":"8","key":"2026090312073774800_cit31","doi-asserted-by":"publisher","first-page":"1707","DOI":"10.1175\/JAMC-D-15-0248.1","article-title":"The measured relationship between\nice water content and cloud radar reflectivity in tropical convective\nclouds","volume":"55","author":"Protat","year":"2016","journal-title":"J. Appl. Meteorol. Clim."},{"issue":"2","key":"2026090312073774800_cit32","doi-asserted-by":"publisher","first-page":"163","DOI":"10.1175\/JTECH-D-21-0077.1","article-title":"Accurate absolute\nmeasurements of liquid water content (LWC) and ice water content (IWC)\nof clouds and precipitation with spectrometric water Raman lidar","volume":"39","author":"Reichardt","year":"2022","journal-title":"J. Atmos. Ocean. Technol."},{"issue":"41","key":"2026090312073774800_cit33","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2512544122","article-title":"Freezing enhances\nCO2 mineralization in Ca2+-containing solutions","volume":"122","author":"Sun","year":"2025","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"issue":"40","key":"2026090312073774800_cit34","doi-asserted-by":"publisher","first-page":"17948","DOI":"10.1021\/acs.est.4c07493","article-title":"Simultaneous oxidation\nof bromide and dissolution of\nmanganese oxide induced by freezing","volume":"58","author":"Wu","year":"2024","journal-title":"Environ.\nSci. Technol."},{"issue":"43","key":"2026090312073774800_cit35","doi-asserted-by":"publisher","first-page":"11226","DOI":"10.1021\/jp020449","article-title":"NMR investigation\nof the quasi-brine layer in ice\/brine mixtures","volume":"106","author":"Cho","year":"2002","journal-title":"J. Phys. Chem. B"},{"issue":"36","key":"2026090312073774800_cit36","doi-asserted-by":"publisher","first-page":"8780","DOI":"10.1021\/jp0738356","article-title":"Chemical kinetics of reactions in the unfrozen solution\nof ice","volume":"111","author":"Takenaka","year":"2007","journal-title":"J. Phys. Chem. A"},{"issue":"16","key":"2026090312073774800_cit37","doi-asserted-by":"publisher","first-page":"4855","DOI":"10.5194\/acp-8-4855-2008","article-title":"Multiphase\nmodeling of nitrate photochemistry in the\nquasi-liquid layer (QLL): implications for NOx release from the Arctic\nand coastal Antarctic snowpack","volume":"8","author":"Boxe","year":"2008","journal-title":"Atmos. Chem.\nPhys."},{"issue":"12","key":"2026090312073774800_cit38","doi-asserted-by":"publisher","first-page":"7637","DOI":"10.1021\/acs.est.2c00112","article-title":"Rapid sulfate formation via uncatalyzed autoxidation of sulfur dioxide\nin aerosol microdroplets","volume":"56","author":"Chen","year":"2022","journal-title":"Environ. Sci. Technol."},{"issue":"23","key":"2026090312073774800_cit39","doi-asserted-by":"publisher","first-page":"13768","DOI":"10.1021\/acs.est.5b01658","article-title":"Oxidation of gas-phase SO2 on the surfaces\nof acidic microdroplets: Implications for sulfate and sulfate radical\nanion formation in the atmospheric liquid phase","volume":"49","author":"Hung","year":"2015","journal-title":"Environ. Sci. Technol."},{"issue":"1\u20133","key":"2026090312073774800_cit40","doi-asserted-by":"publisher","first-page":"241","DOI":"10.1016\/0004-6981(78)90204-4","article-title":"Oxidation of sulfur\ndioxide in aqueous systems with\nparticular reference to the atmosphere","volume":"12","author":"Hegg","year":"1978","journal-title":"Atmos.\nEnviron."},{"issue":"1","key":"2026090312073774800_cit41","doi-asserted-by":"publisher","first-page":"129","DOI":"10.1016\/0022-0248(91)90918-U","article-title":"Freezing potentials arising on solidification\nof dilute\naqueous solutions of electrolytes","volume":"112","author":"Bronshteyn","year":"1991","journal-title":"J. Cryst.\nGrowth"},{"issue":"3","key":"2026090312073774800_cit42","doi-asserted-by":"publisher","first-page":"1354","DOI":"10.1073\/pnas.1916401117","article-title":"Fast oxidation of sulfur dioxide\nby hydrogen peroxide in deliquesced aerosol particles","volume":"117","author":"Liu","year":"2020","journal-title":"Proc. Natl. Acad. Sci. U.S.A."},{"issue":"9","key":"2026090312073774800_cit43","doi-asserted-by":"publisher","first-page":"1925","DOI":"10.1021\/acs.jpclett.7b00458","article-title":"Confinement effects on an electron\ntransfer reaction in nanoporous carbon electrodes","volume":"8","author":"Li","year":"2017","journal-title":"J. Phys. Chem. Lett."},{"issue":"6","key":"2026090312073774800_cit44","doi-asserted-by":"publisher","first-page":"948","DOI":"10.1287\/opre.43.6.948","article-title":"Global\nsensitivity analysis","volume":"43","author":"Wagner","year":"1995","journal-title":"Oper. Res."},{"issue":"1","key":"2026090312073774800_cit45","doi-asserted-by":"publisher","DOI":"10.1038\/s41612-018-0041-9","article-title":"Tropospheric OH and\nstratospheric OH and Cl concentrations\ndetermined from CH4, CH3Cl, and SF6 measurements","volume":"1","author":"Li","year":"2018","journal-title":"npj Clim. Atmos. Sci."},{"key":"2026090312073774800_cit46","volume-title":"Atmospheric Chemistry\nand Physics: From Air Pollution to Climate Change","author":"Seinfeld","year":"2016"},{"issue":"8","key":"2026090312073774800_cit47","doi-asserted-by":"publisher","first-page":"1619","DOI":"10.1351\/PAC-REP-10-01-01","article-title":"Defining the hydrogen\nbond: An account (IUPAC Technical\nReport)","volume":"83","author":"Arunan","year":"2011","journal-title":"Pure Appl. Chem."},{"issue":"47","key":"2026090312073774800_cit48","doi-asserted-by":"publisher","first-page":"16065","DOI":"10.1021\/ja805471a","article-title":"Cuaq+\/Cuaq2+ redox reaction exhibits\nstrong nonlinear solvent response due to change in coordination number","volume":"130","author":"Blumberger","year":"2008","journal-title":"J. Am. Chem. Soc."},{"issue":"5897","key":"2026090312073774800_cit49","doi-asserted-by":"publisher","first-page":"1817","DOI":"10.1126\/science.1161511","article-title":"Linear\nresponse breakdown in solvation\ndynamics induced by atomic electron-transfer reactions","volume":"321","author":"Bragg","year":"2008","journal-title":"Science"},{"issue":"1","key":"2026090312073774800_cit50","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-63899-w","article-title":"Probing catalyst-free hydroxyl radical\ngeneration at microbubble\ninterfaces","volume":"16","author":"Yang","year":"2025","journal-title":"Nat. Commun."},{"issue":"5","key":"2026090312073774800_cit51","doi-asserted-by":"publisher","first-page":"1954","DOI":"10.1021\/jp909219k","article-title":"Instantaneous liquid\ninterfaces","volume":"114","author":"Willard","year":"2010","journal-title":"J. Phys. Chem. B"}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c11450","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/34\/37134\/67322261\/jacs.6c11450.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/34\/37134\/67322261\/jacs.6c11450.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T16:19:31Z","timestamp":1788452371000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/34\/37134\/5321175\/Frustrated-Interfacial-Solvation-Enhances-Reaction"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,24]]},"references-count":51,"journal-issue":{"issue":"34","published-online":{"date-parts":[[2026,8,24]]},"published-print":{"date-parts":[[2026,9,2]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c11450","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,24]]}}}