{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:46:08Z","timestamp":1792784768985,"version":"4.5.0"},"reference-count":55,"publisher":"American Chemical Society (ACS)","issue":"41","license":[{"start":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T00:00:00Z","timestamp":1791504000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T00:00:00Z","timestamp":1791504000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T00:00:00Z","timestamp":1791504000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100012152","name":"National Postdoctoral Program for Innovative Talents","doi-asserted-by":"publisher","award":["BX20230329"],"award-info":[{"award-number":["BX20230329"]}],"id":[{"id":"10.13039\/501100012152","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2024M752917"],"award-info":[{"award-number":["2024M752917"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["22401262"],"award-info":[{"award-number":["22401262"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["22471248"],"award-info":[{"award-number":["22471248"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["92356304"],"award-info":[{"award-number":["92356304"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]},{"name":"National Natural Science Foundation of China (NSFC)","award":["92461304"],"award-info":[{"award-number":["92461304"]}],"id":[{"id":"https:\/\/ror.org\/01h0zpd94","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Resolving how subangstrom changes in a metal core affect electronic structure and photophysical properties in high-nuclearity silver nanoclusters (NCs) remains challenging, as inner-core variations are often coupled with changes in outer metal shells, surface coordination, or crystal packing. Here, we report a structurally homologous series of Ag78 NCs (Ag78-1\u2013Ag78-4) sharing a common Ag6@Ag24@Ag48 metal architecture stabilized by an S2\u2013\/SO42\u2013 inorganic template framework. The inorganic template layer stabilizes the metal architecture and reduces structural perturbations from the outer coordination environment, allowing localized Ag6 contraction while largely retaining the overall metal\u2013inorganic architecture. Removal of the central Cl\u2013 template in Ag78-1 produces a distinct inward contraction of the Ag6 core in Ag78-2, and surface chloride substitution further accesses more contracted structural states (Ag78-3 and Ag78-4). These structural evolutions are established by single-crystal X-ray diffraction and supported by ESI-MS. Steady-state spectroscopy reveals progressive modulation of low-energy absorption and emission behavior across the series. Theoretical calculations show that central Cl\u2013 removal and accompanying Ag6 contraction reorganize low-energy electronic states, and femtosecond transient absorption across the series reveals corresponding changes in excited-state relaxation dynamics. This work establishes an inorganic-template-stabilized Ag78 platform for correlating atomically resolved inner-core structural evolution with electronic structures and excited-state properties in high-nuclearity silver NCs.<\/jats:p>","DOI":"10.1021\/jacs.6c11873","type":"journal-article","created":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T16:02:28Z","timestamp":1791561748000},"page":"44493-44504","source":"Crossref","is-referenced-by-count":0,"title":["Capturing Ag6 Inner-Core Contraction in\nInorganic-Template-Stabilized Ag78 Nanoclusters"],"prefix":"10.1021","volume":"148","author":[{"given":"Xin-Lan","family":"Peng","sequence":"first","affiliation":[{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]},{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian-Sheng","family":"Chai","sequence":"additional","affiliation":[{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]},{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Xie","sequence":"additional","affiliation":[{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]},{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai-Xin","family":"Sun","sequence":"additional","affiliation":[{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]},{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia-Chen","family":"Zhang","sequence":"additional","affiliation":[{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]},{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3593-5941","authenticated-orcid":true,"given":"Yubing","family":"Si","sequence":"additional","affiliation":[{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]},{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4999-9578","authenticated-orcid":true,"given":"Xi-Ming","family":"Luo","sequence":"additional","affiliation":[{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]},{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6728-0559","authenticated-orcid":true,"given":"Shuang-Quan","family":"Zang","sequence":"additional","affiliation":[{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. China, 450001"]},{"name":"Zhengzhou University , , ,","place":["Zhengzhou, P. R. 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Chem., Int.\nEd."},{"key":"2026102111083604700_cit26","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-67834-x","article-title":"Room-temperature photoluminescence\nin monocarboxylate-protected silver nanoclusters via steric hindrance-induced\ninterfacial structure locking","volume":"17","author":"Jiang","year":"2026","journal-title":"Nat. Commun."},{"key":"2026102111083604700_cit27","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202502782","article-title":"Dynamic ultralong\nphosphorescence and optical waveguiding switches in silver-organic\ncomplex via reversible single-crystal-to-single-crystal conversion","volume":"64","author":"Xing","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026102111083604700_cit28","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.70270","article-title":"Ligand-driven structural\nmodulation and enhanced photoluminescence in high-nuclearity Ag56 nanoclusters","volume":"7","author":"Akiyama","year":"2026","journal-title":"Aggregate"},{"key":"2026102111083604700_cit29","doi-asserted-by":"publisher","first-page":"8930","DOI":"10.1039\/C7NR00931C","article-title":"Chloride assisted supramolecular\nassembly of a luminescent gigantic cluster: [Ag216S56Cl7(CuCPh)98(H2O)12]\u2212 with pseudo-Th skeleton and five-shell arrangement","volume":"9","author":"Chen","year":"2017","journal-title":"Nanoscale"},{"key":"2026102111083604700_cit30","doi-asserted-by":"publisher","first-page":"25","DOI":"10.1016\/j.scib.2024.09.047","article-title":"Regulating self-assembly\nof concomitant isotropic Ag78 and anisotropic Ag110 nanoclusters","volume":"70","author":"Peng","year":"2025","journal-title":"Sci. Bull."},{"key":"2026102111083604700_cit31","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506971","article-title":"Solvent induced\ntransformation of homoleptic alkynyl-protected large silver nanoclusters","volume":"64","author":"Zheng","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026102111083604700_cit32","doi-asserted-by":"publisher","first-page":"19365","DOI":"10.1021\/jacs.2c07018","article-title":"Face-centered\ncubic silver nanoclusters consolidated\nwith tetradentate formamidinate","volume":"144","author":"Hu","year":"2022","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026102111083604700_cit33","doi-asserted-by":"publisher","first-page":"189","DOI":"10.1002\/anie.201809469","article-title":"Camouflaging structural diversity:\nco-crystallization of two different nanoparticles having different\ncores but the same shell","volume":"58","author":"Bodiuzzaman","year":"2019","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026102111083604700_cit34","doi-asserted-by":"publisher","first-page":"15582","DOI":"10.1021\/jacs.8b09162","article-title":"A unique pair: Ag40 and Ag46 nanoclusters\nwith the same surface but different cores for structure-property correlation","volume":"140","author":"Chai","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"2026102111083604700_cit35","doi-asserted-by":"publisher","first-page":"14759","DOI":"10.1021\/jacs.5c17347","article-title":"Sequential vertex-specific modulation\nof enantiopure metal nanoclusters","volume":"148","author":"Kong","year":"2026","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026102111083604700_cit36","doi-asserted-by":"publisher","first-page":"12439","DOI":"10.1021\/jacs.1c05568","article-title":"Symmetry breaking of atomically precise fullerene-like\nmetal nanoclusters","volume":"143","author":"Huang","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"2026102111083604700_cit37","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17198-1","article-title":"A keplerian\nAg90 nest of platonic and archimedean polyhedra in different\nsymmetry groups","volume":"11","author":"Su","year":"2020","journal-title":"Nat. Commun."},{"key":"2026102111083604700_cit38","doi-asserted-by":"publisher","first-page":"18305","DOI":"10.1021\/jacs.2c06093","article-title":"Sulfide boosting\nnear-unity photoluminescence quantum yield of silver nanocluster","volume":"144","author":"Zhang","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026102111083604700_cit39","doi-asserted-by":"publisher","first-page":"12659","DOI":"10.1002\/anie.202003143","article-title":"A sodalite-type silver\northophosphate cluster in a globular silver nanocluster","volume":"59","author":"Deng","year":"2020","journal-title":"Angew. Chem., Int. 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Soc."},{"key":"2026102111083604700_cit42","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202500700","article-title":"Enhancement of photoluminescence\nquantum yield of silver clusters by heavy atom effect","volume":"21","author":"Akiyama","year":"2025","journal-title":"Small"},{"key":"2026102111083604700_cit43","doi-asserted-by":"publisher","first-page":"15559","DOI":"10.1021\/ja506773d","article-title":"Crystal structure and\noptical properties of the [Ag62S12(SBut)32]2+ nanocluster with a complete\nface-centered cubic kernel","volume":"136","author":"Jin","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"2026102111083604700_cit44","doi-asserted-by":"publisher","first-page":"7905","DOI":"10.1021\/acs.chemmater.6b03472","article-title":"Two electron reduction:\nfrom quantum dots to metal nanoclusters","volume":"28","author":"Jin","year":"2016","journal-title":"Chem.\nMater."},{"key":"2026102111083604700_cit45","doi-asserted-by":"publisher","first-page":"23533","DOI":"10.1021\/jacs.3c07194","article-title":"Clarifying the electronic structure of anion-templated\nsilver nanoclusters by optical absorption spectroscopy and theoretical\ncalculation","volume":"145","author":"Horita","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"2026102111083604700_cit46","doi-asserted-by":"publisher","first-page":"37231","DOI":"10.1021\/jacs.5c10289","article-title":"Triggering\nphotoluminescence\nin high-nuclear silver nanoclusters via extra silver atom incorporation","volume":"147","author":"Akiyama","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026102111083604700_cit47","doi-asserted-by":"publisher","DOI":"10.1002\/anie.1815171","article-title":"One-end-truncated Au52 and Au70 quantum\nrods: high-quantum-yield NIR-II emitters with aspect-ratio-dominated\nphotophysics","volume":"0","author":"Luo","year":"2026","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026102111083604700_cit48","doi-asserted-by":"publisher","first-page":"1971","DOI":"10.1039\/D1NR07170J","article-title":"A chloride-doped silver-sulfide cluster\n[Ag148S26Cl30(CCBut)60]6+: hierarchical assembly, enhanced\nluminescence\nand cytotoxicity to cancer cells","volume":"14","author":"Jiang","year":"2022","journal-title":"Nanoscale"},{"key":"2026102111083604700_cit49","doi-asserted-by":"publisher","first-page":"689","DOI":"10.1038\/nchem.2718","article-title":"Hypersensitive\ndual-function luminescence\nswitching of a silver-chalcogenolate cluster-based metal-organic framework","volume":"9","author":"Huang","year":"2017","journal-title":"Nat. Chem."},{"key":"2026102111083604700_cit50","doi-asserted-by":"publisher","first-page":"2297","DOI":"10.1039\/D0CS01393E","article-title":"Shell\nengineering to achieve modification and assembly of atomically-precise\nsilver clusters","volume":"50","author":"Jin","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"2026102111083604700_cit51","doi-asserted-by":"publisher","first-page":"16095","DOI":"10.1021\/acsnano.1c04759","article-title":"Source of bright\nnear-infrared luminescence in gold nanoclusters","volume":"15","author":"Li","year":"2021","journal-title":"ACS Nano"},{"key":"2026102111083604700_cit52","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adm6928","article-title":"Arylgold nanoclusters: Phenyl-stabilized\nAu44 with thermal-controlled NIR single\/dual-channel phosphorescence","volume":"10","author":"Si","year":"2024","journal-title":"Sci. Adv."},{"key":"2026102111083604700_cit53","doi-asserted-by":"publisher","first-page":"8827","DOI":"10.1021\/acsnano.5c22362","article-title":"Au20Ag32 nanocluster\nemitting bright near-infrared-II photoluminescence with quantum yield\nof 30% in aerated solution","volume":"20","author":"Sardar","year":"2026","journal-title":"ACS Nano"},{"key":"2026102111083604700_cit54","doi-asserted-by":"publisher","first-page":"9092","DOI":"10.1039\/D5CS00383K","article-title":"Atom-precise coinage\nmetal nanoclusters for near-infrared emission: excited-state dynamics\nand mechanisms","volume":"54","author":"Liu","year":"2025","journal-title":"Chem. Soc. Rev."},{"key":"2026102111083604700_cit55","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202309073","article-title":"Visible to\nNIR-II photoluminescence of atomically precise\ngold nanoclusters","volume":"36","author":"Liu","year":"2024","journal-title":"Adv. Mater."}],"container-title":["Journal of the American\nChemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.6c11873","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/41\/44493\/68805306\/jacs.6c11873.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/148\/41\/44493\/68805306\/jacs.6c11873.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T15:31:29Z","timestamp":1792596689000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/148\/41\/44493\/5448169\/Capturing-Ag6-Inner-Core-Contraction-in-Inorganic"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,9]]},"references-count":55,"journal-issue":{"issue":"41","published-online":{"date-parts":[[2026,10,9]]},"published-print":{"date-parts":[[2026,10,21]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.6c11873","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,9]]}}}