{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T09:18:31Z","timestamp":1788254311746,"version":"build-2803163510"},"reference-count":34,"publisher":"American Chemical Society (ACS)","issue":"33","license":[{"start":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T00:00:00Z","timestamp":1786924800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/na","name":"Horizon 2020 European Commission","doi-asserted-by":"publisher","award":["101055472"],"award-info":[{"award-number":["101055472"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"German Research Council","doi-asserted-by":"publisher","award":["AB 1234\/1-1"],"award-info":[{"award-number":["AB 1234\/1-1"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"German Research Council","doi-asserted-by":"publisher","award":["EXC 2033-390677874-325 RESOLV"],"award-info":[{"award-number":["EXC 2033-390677874-325 RESOLV"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"National Institutes of Health","doi-asserted-by":"publisher","award":["R01AB123456"],"award-info":[{"award-number":["R01AB123456"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,8,26]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Both olefins and arenes are abundant and versatile feedstock chemicals. Although the electrophilic alkylation of arenes constitutes an advanced technology, the corresponding alkylation of olefins is rather undeveloped. Here, we report an asymmetric catalytic benzylation and allylation of unactivated olefins with acetates as electrophiles. The reaction is catalyzed by a single imidodiphosphorimidate organocatalyst operating as a silylium Lewis acid. Mechanistic experiments support an enantioconvergent SN1 mechanism featuring stereoablative ion pair formation, resulting in a dynamic kinetic resolution. The enantioenriched hydrocarbon products are readily derivatized to odorants and nonsteroidal anti-inflammatory drugs in one or two steps. The developed method provides a metal-free alternative to cornerstone Tsuji\u2013Trost-type allylations proceeding though \u03c0-allyl metal complexes.<\/jats:p>","DOI":"10.1021\/jacs.6c12914","type":"journal-article","created":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T20:01:52Z","timestamp":1786996912000},"page":"35270-35277","source":"Crossref","is-referenced-by-count":0,"title":["The Catalytic Asymmetric\nAlkylation of Olefins with\nAlcohol Derivatives"],"prefix":"10.1021","volume":"148","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-0097-8016","authenticated-orcid":true,"given":"Luc M.","family":"Debie","sequence":"first","affiliation":[{"name":"Max-Planck-Institut fu\u0308r Kohlenforschung , ,","place":["Mu\u0308lheim an der Ruhr, Germany, D-45470"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thibault","family":"Gotta","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut fu\u0308r Kohlenforschung , ,","place":["Mu\u0308lheim an der Ruhr, Germany, D-45470"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mathias","family":"Turberg","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut fu\u0308r Kohlenforschung , ,","place":["Mu\u0308lheim an der Ruhr, Germany, D-45470"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9709-8187","authenticated-orcid":true,"given":"Nils","family":"No\u0308thling","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut fu\u0308r Kohlenforschung , ,","place":["Mu\u0308lheim an der Ruhr, Germany, D-45470"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9804-599X","authenticated-orcid":true,"given":"Benjamin","family":"List","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut fu\u0308r Kohlenforschung , ,","place":["Mu\u0308lheim an der Ruhr, Germany, D-45470"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,17]]},"reference":[{"issue":"14","key":"2026090104500540400_cit1","doi-asserted-by":"publisher","first-page":"3339","DOI":"10.1046\/j.1432-1033.2002.03014.x","article-title":"Structure, Mechanism and Function\nof Prenyltransferases","volume":"269","author":"Liang","year":"2002","journal-title":"Eur. 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