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Isoelectronic to carbon isosteres such as diamond, graphite, and carbon nanotubes (CNTs), (BN)n polymorphs exhibit remarkably different properties owing to the highly polar B\u2013N bonds. The high temperature synthesis of (BN)n materials preclude the isolation and study of molecular BN. Herein, we report the synthesis of EtCAAC\u2013B\u2261N\u2013B(C6F5)3, a donor\u2013acceptor stabilized molecular boron nitride. Single-crystal X-ray diffraction as well as nuclear magnetic resonance, infrared, and Raman spectroscopic studies coupled with density functional theory calculations support the notion that the central B\u2261N unit exhibits triple bond character. Preliminary reactivity indicates that this compound does not react analogously to structurally similar iminoboranes as evidenced by the thermal extrusion of the central boron and nitrogen atoms.<\/jats:p>","DOI":"10.1021\/jacs.6c14427","type":"journal-article","created":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T17:01:40Z","timestamp":1787158900000},"page":"37535-37544","source":"Crossref","is-referenced-by-count":1,"title":["Taming Molecular Boron\nNitride through a Tandem Donor\u2013Acceptor\nStabilization\/Arene Release Strategy"],"prefix":"10.1021","volume":"148","author":[{"given":"Junyi","family":"Wang","sequence":"first","affiliation":[{"name":"Baylor University , , , ,","place":["Waco, Texas, United States, 76798"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9260-2986","authenticated-orcid":true,"given":"Todd W.","family":"Hudnall","sequence":"additional","affiliation":[{"name":"Baylor University , , , ,","place":["Waco, Texas, United States, 76798"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,19]]},"reference":[{"issue":"138","key":"2026090312100026000_cit1","doi-asserted-by":"publisher","first-page":"270","DOI":"10.1080\/14786444208621545","article-title":"XLVI. 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