{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T20:35:43Z","timestamp":1792182943784,"version":"4.4.0"},"reference-count":29,"publisher":"American Chemical Society (ACS)","issue":"46","license":[{"start":{"date-parts":[[2018,12,19]],"date-time":"2018-12-19T00:00:00Z","timestamp":1545177600000},"content-version":"vor","delay-in-days":37,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_ccby_termsofuse.html"}],"funder":[{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["742041"],"award-info":[{"award-number":["742041"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","award":["EP\/I011870"],"award-info":[{"award-number":["EP\/I011870"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000770","name":"University of Manchester","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100000770","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2018,11,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>We report a record-high SO2 adsorption capacity of 12.3 mmol g\u20131 in a robust porous material, MFM-601, at 298 K and 1.0 bar. SO2 adsorption in MFM-601 is fully reversible and highly selective over CO2 and N2. The binding domains for adsorbed SO2 and CO2 molecules in MFM-601 have been determined by in situ synchrotron X-ray diffraction experiments, giving insights at the molecular level to the basis of the observed high selectivity.<\/jats:p>","DOI":"10.1021\/jacs.8b08433","type":"journal-article","created":{"date-parts":[[2018,11,12]],"date-time":"2018-11-12T14:16:43Z","timestamp":1542032203000},"page":"15564-15567","source":"Crossref","is-referenced-by-count":208,"title":["Exceptional\nAdsorption and Binding of Sulfur Dioxide\nin a Robust Zirconium-Based Metal\u2013Organic Framework"],"prefix":"10.1021","volume":"140","author":[{"given":"Joseph H.","family":"Carter","sequence":"first","affiliation":[{"name":"University of Manchester , , ,","place":["Manchester, United Kingdom, M13 9PL"]},{"name":"Harwell Science Campus , , ,","place":["Oxfordshire, United Kingdom, OX11 0DE"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xue","family":"Han","sequence":"additional","affiliation":[{"name":"University of Manchester , , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Florian Y.","family":"Moreau","sequence":"additional","affiliation":[{"name":"University of Manchester , , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ivan","family":"da Silva","sequence":"additional","affiliation":[{"name":"STFC Rutherford Appleton Laboratory , , ,","place":["Oxfordshire, United Kingdom, OX11 0QX"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Adam","family":"Nevin","sequence":"additional","affiliation":[{"name":"University of Manchester , , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Harry G. W.","family":"Godfrey","sequence":"additional","affiliation":[{"name":"University of Manchester , , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chiu C.","family":"Tang","sequence":"additional","affiliation":[{"name":"Harwell Science Campus , , ,","place":["Oxfordshire, United Kingdom, OX11 0DE"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1111-9272","authenticated-orcid":true,"given":"Sihai","family":"Yang","sequence":"additional","affiliation":[{"name":"University of Manchester , , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6992-0700","authenticated-orcid":true,"given":"Martin","family":"Schro\u0308der","sequence":"additional","affiliation":[{"name":"University of Manchester , , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2018,11,12]]},"reference":[{"key":"2026090313444517700_cit1","volume-title":"International Energy Outlook 2017","author":"U.S. Energy Information Administration.","year":"2017"},{"key":"2026090313444517700_cit2","doi-asserted-by":"crossref","DOI":"10.1201\/9780824745172","volume-title":"Petroleum Refining\nTechnology and Economics","author":"Gary","year":"2001","edition":"4"},{"key":"2026090313444517700_cit3a","article-title":"Committee\non Acute Exposure Guideline Levels, Committee\non Toxicology","volume-title":"Board on Environmental Studies\nand Toxicology. Acute Exposure Guideline Levels for Selected Airborne\nChemicals","year":"2010"},{"key":"2026090313444517700_cit3b","article-title":"World Health Organisation\nreport","volume-title":"WHO Air Quality Guidelines for Particulate\nMatter, Ozone, Nitrogen Dioxide and Sulfur Dioxide","year":"2005"},{"key":"2026090313444517700_cit3c","doi-asserted-by":"publisher","first-page":"267","DOI":"10.1080\/00207239208710766","volume":"41","author":"Huang","year":"1992","journal-title":"Int. J. Environ. Stud."},{"key":"2026090313444517700_cit4","doi-asserted-by":"publisher","first-page":"725","DOI":"10.3155\/1047-3289.59.6.725","volume":"59","author":"Lee","year":"2009","journal-title":"J. Air Waste Manage.\nAssoc."},{"key":"2026090313444517700_cit5a","doi-asserted-by":"publisher","first-page":"77","DOI":"10.1016\/j.cej.2012.02.026","volume":"188","author":"Deng","year":"2012","journal-title":"Chem. Eng. J."},{"key":"2026090313444517700_cit5b","doi-asserted-by":"publisher","first-page":"19884","DOI":"10.1039\/C4CP00109E","volume":"16","author":"Matito-Martos","year":"2014","journal-title":"Phys. Chem. Chem.\nPhys."},{"key":"2026090313444517700_cit6","doi-asserted-by":"publisher","first-page":"2142","DOI":"10.1021\/ie801165u","volume":"48","author":"Zhang","year":"2009","journal-title":"Ind. Eng. Chem. Res."},{"key":"2026090313444517700_cit7","doi-asserted-by":"publisher","first-page":"1704292","DOI":"10.1002\/adfm.201704292","volume":"28","author":"Xia","year":"2018","journal-title":"Adv.\nFunct. Mater."},{"key":"2026090313444517700_cit8","doi-asserted-by":"publisher","first-page":"1556","DOI":"10.1021\/je4011135","volume":"59","author":"Yi","year":"2014","journal-title":"J. Chem. Eng. Data"},{"key":"2026090313444517700_cit9","doi-asserted-by":"publisher","first-page":"705","DOI":"10.1038\/nature01650","volume":"423","author":"Yaghi","year":"2003","journal-title":"Nature"},{"key":"2026090313444517700_cit10","doi-asserted-by":"publisher","first-page":"673","DOI":"10.1021\/cr300014x","volume":"112","author":"Zhou","year":"2012","journal-title":"Chem. Rev."},{"key":"2026090313444517700_cit11a","doi-asserted-by":"publisher","first-page":"869","DOI":"10.1021\/cr200190s","volume":"112","author":"Li","year":"2012","journal-title":"Chem. Rev."},{"key":"2026090313444517700_cit11b","doi-asserted-by":"publisher","first-page":"108","DOI":"10.1016\/j.mattod.2017.07.006","volume":"21","author":"Li","year":"2018","journal-title":"Mater. Today"},{"key":"2026090313444517700_cit11c","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.09.027","author":"Lin","year":"2017","journal-title":"Coord.\nChem. Rev."},{"key":"2026090313444517700_cit12","doi-asserted-by":"publisher","first-page":"13850","DOI":"10.1021\/ja8057953","volume":"130","author":"Cavka","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"2026090313444517700_cit13","doi-asserted-by":"publisher","first-page":"3716","DOI":"10.1021\/jz501899j","volume":"5","author":"Planas","year":"2014","journal-title":"J. Phys. Chem. Lett."},{"key":"2026090313444517700_cit14","doi-asserted-by":"publisher","first-page":"10286","DOI":"10.1021\/acsami.7b00918","volume":"9","author":"Wang","year":"2017","journal-title":"ACS\nAppl. Mater. Interfaces"},{"key":"2026090313444517700_cit15","doi-asserted-by":"publisher","first-page":"149","DOI":"10.1038\/nprot.2016.001","volume":"11","author":"Wang","year":"2016","journal-title":"Nat. Protoc."},{"key":"2026090313444517700_cit16","doi-asserted-by":"publisher","first-page":"30","DOI":"10.1016\/j.micromeso.2015.01.032","volume":"208","author":"Piscopo","year":"2015","journal-title":"Microporous Mesoporous\nMater."},{"key":"2026090313444517700_cit17","doi-asserted-by":"publisher","first-page":"4954","DOI":"10.1021\/ja401061m","volume":"135","author":"Yang","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"2026090313444517700_cit18","doi-asserted-by":"publisher","first-page":"4653","DOI":"10.1021\/cm401270b","volume":"25","author":"Tan","year":"2013","journal-title":"Chem. Mater."},{"key":"2026090313444517700_cit19","doi-asserted-by":"publisher","first-page":"17045","DOI":"10.1038\/natrevmats.2017.45","volume":"2","author":"Trickett","year":"2017","journal-title":"Nat. Rev. Mater."},{"key":"2026090313444517700_cit20a","doi-asserted-by":"publisher","first-page":"1606929","DOI":"10.1002\/adma.201606929","volume":"29","author":"Cui","year":"2017","journal-title":"Adv. Mater."},{"key":"2026090313444517700_cit20b","doi-asserted-by":"publisher","first-page":"8705","DOI":"10.1002\/adma.201602338","volume":"28","author":"Savage","year":"2016","journal-title":"Adv. Mater."},{"key":"2026090313444517700_cit21a","doi-asserted-by":"publisher","first-page":"10525","DOI":"10.1021\/ja404514r","volume":"135","author":"Wu","year":"2013","journal-title":"J.\nAm. Chem. Soc."},{"key":"2026090313444517700_cit21b","doi-asserted-by":"publisher","first-page":"6980","DOI":"10.1021\/jp512501k","volume":"119","author":"Chevreau","year":"2015","journal-title":"J. Phys. Chem. C"},{"key":"2026090313444517700_cit22","doi-asserted-by":"publisher","first-page":"372","DOI":"10.1107\/S0365110X5200109X","volume":"5","author":"Post","year":"1952","journal-title":"Acta Crystallogr."}],"container-title":["Journal of the American Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/jacs.8b08433","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/140\/46\/15564\/67310340\/jacs.8b08433.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/jacsat\/article-pdf\/140\/46\/15564\/67310340\/jacs.8b08433.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T17:44:53Z","timestamp":1788457493000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/jacsat\/article\/140\/46\/15564\/758082\/Exceptional-Adsorption-and-Binding-of-Sulfur"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,11,12]]},"references-count":29,"journal-issue":{"issue":"46","published-online":{"date-parts":[[2018,11,12]]},"published-print":{"date-parts":[[2018,11,21]]}},"URL":"https:\/\/doi.org\/10.1021\/jacs.8b08433","relation":{},"ISSN":["0002-7863","1520-5126"],"issn-type":[{"value":"0002-7863","type":"print"},{"value":"1520-5126","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,11,12]]}}}